Effect of SiC Nanowires on the Mechanical and Oxidation Protective Ability of SiC Coating for C/C Composites

To protect carbon/carbon (C/C) composites against oxidation, a SiC nanowire‐toughened SiC coating with homogeneously dispersed nanowires within the coating was successfully prepared on C/C composites by a simple and low cost two‐step technique of chemical vapor deposition and pack cementation. The S...

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Veröffentlicht in:Journal of the American Ceramic Society 2012-02, Vol.95 (2), p.739-745
Hauptverfasser: Yanhui, Chu, Qiangang, Fu, Hejun, Li, Xiaohong, Shi, Kezhi, Li, Xue, Wen, Gunan, Shang
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container_end_page 745
container_issue 2
container_start_page 739
container_title Journal of the American Ceramic Society
container_volume 95
creator Yanhui, Chu
Qiangang, Fu
Hejun, Li
Xiaohong, Shi
Kezhi, Li
Xue, Wen
Gunan, Shang
description To protect carbon/carbon (C/C) composites against oxidation, a SiC nanowire‐toughened SiC coating with homogeneously dispersed nanowires within the coating was successfully prepared on C/C composites by a simple and low cost two‐step technique of chemical vapor deposition and pack cementation. The SiC nanowires effectively increased the mechanical properties of the coating, decreased the size of the defects in the coating, and improved the oxidation protection effectiveness of the coating. The results showed that, after introducing the SiC nanowires, the hardness, elastic modulus, and fracture toughness of the SiC coating were increased by 5%, 19%, and 48%, respectively. The mass loss of the coated C/C samples was reduced from 8.10% to 5.21% after thermogravimetric analysis in air from 873 to 1773 K. Moreover, the mass loss of the SiC nanowire‐toughened SiC coated sample was only 14.33% and 2.68% after isothermal oxidation at 1173 K for 39 h and 1773 K for 44 h in air, whereas the mass loss of the pure SiC coated sample was up to 16.12% and 7.00% after isothermal oxidation at 1173 K for 15 h and 1773 K for 20 h in air.
doi_str_mv 10.1111/j.1551-2916.2011.04979.x
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The SiC nanowires effectively increased the mechanical properties of the coating, decreased the size of the defects in the coating, and improved the oxidation protection effectiveness of the coating. The results showed that, after introducing the SiC nanowires, the hardness, elastic modulus, and fracture toughness of the SiC coating were increased by 5%, 19%, and 48%, respectively. The mass loss of the coated C/C samples was reduced from 8.10% to 5.21% after thermogravimetric analysis in air from 873 to 1773 K. 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source Wiley Online Library Journals Frontfile Complete
subjects Carbon
Carbon-carbon composites
Coating
Composite materials
Mechanical properties
Nanomaterials
Nanostructure
Nanowires
Oxidation
Protective coatings
Silicon carbide
Thermogravimetric analysis
title Effect of SiC Nanowires on the Mechanical and Oxidation Protective Ability of SiC Coating for C/C Composites
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