Nanostructure and strain analysis of CeO2/YSZ strained superlattice

The nanostructure and the strain fields in the superlattice [CeO2/YSZ]5 fabricated on a SiO2/Si(001) substrate were investigated macroscopically and nanoscopically using XRD and HRTEM with geometric phase analysis (GPA) and related methods. The XRD analyses elucidated that the out-of-plane lattice p...

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Veröffentlicht in:Materials science & engineering. B, Solid-state materials for advanced technology Solid-state materials for advanced technology, 2010-10, Vol.173 (1-3), p.220-228
Hauptverfasser: Kiguchi, Takanori, Konno, Toyohiko J., Wakiya, Naoki, Morioka, Hitoshi, Saito, Keisuke, Shinozaki, Kazuo
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container_issue 1-3
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container_title Materials science & engineering. B, Solid-state materials for advanced technology
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creator Kiguchi, Takanori
Konno, Toyohiko J.
Wakiya, Naoki
Morioka, Hitoshi
Saito, Keisuke
Shinozaki, Kazuo
description The nanostructure and the strain fields in the superlattice [CeO2/YSZ]5 fabricated on a SiO2/Si(001) substrate were investigated macroscopically and nanoscopically using XRD and HRTEM with geometric phase analysis (GPA) and related methods. The XRD analyses elucidated that the out-of-plane lattice parameter of CeO2 and YSZ layers was relaxed. However, the in-plane lattice parameter was almost identical. Results of HRTEM and related analyses revealed that CeO2 and YSZ layers formed a superlattice structure. Results showed that the superlattice has some defects, such as misorientation, varied thickness of CeO2 and YSZ layers, varied artificial periodicity, and interface roughness. However, the out-of-plane lattice parameter had periodicity corresponding to the superlattice structure. The in-plane lattice parameter was also equal to the local deviation. Therefore, the strain effect in the superlattice persisted to some degree.
doi_str_mv 10.1016/j.mseb.2010.02.013
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subjects Deviation
Lattice parameters
Materials science
Nanocomposites
Nanomaterials
Nanostructure
Strain
Superlattice structures
Superlattices
Yttria stabilized zirconia
title Nanostructure and strain analysis of CeO2/YSZ strained superlattice
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