Intracavity laser absorption spectroscopy of sooting acetylene/air flames

Intracavity laser absorption spectroscopy (ICLAS) is used to measure the absolute concentration profiles of HCO and C 2 in low-pressure acetylene/oxygen/nitrogen flames with equivalence ratios ϕ=0.8, 1.0, 1.5, 2.0 and 2.5. The flames with ϕ=2.0 and 2.5 are soot-producing, with light extinction reach...

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Veröffentlicht in:Applied physics. B, Lasers and optics Lasers and optics, 2008-08, Vol.92 (2), p.281-286
Hauptverfasser: Goldman, A., Cheskis, S.
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description Intracavity laser absorption spectroscopy (ICLAS) is used to measure the absolute concentration profiles of HCO and C 2 in low-pressure acetylene/oxygen/nitrogen flames with equivalence ratios ϕ=0.8, 1.0, 1.5, 2.0 and 2.5. The flames with ϕ=2.0 and 2.5 are soot-producing, with light extinction reaching 0.1% per pass in the flame with ϕ=2.5. This strong broadband extinction does not affect the sensitivity of ICLAS, however. The temperature profiles of the flames were measured using laser-induced fluorescence of the OH radicals. For C 2 concentration measurements, the (0–2) vibronic transition of the Swan band is used. The lines of this transition are located close to the HCO lines, making it possible to measure the two radical concentrations simultaneously. The C 2 concentration is highest in the ϕ=1.5 flame, and lower in the lean and heavily sooted ϕ=2.5 flames.
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source SpringerNature Journals
subjects Absorption spectroscopy
Acetylene
Atomic and molecular physics
Biological and medical applications
Broadband
Engineering
Exact sciences and technology
Extinction
Fluorescence
Fundamental areas of phenomenology (including applications)
Laser spectroscopy
Lasers
Molecular properties and interactions with photons
Molecular spectra
Optical Devices
Optics
Photonics
Physical Chemistry
Physics
Physics and Astronomy
Quantum Optics
Radicals
Temperature profiles
Visible spectra
title Intracavity laser absorption spectroscopy of sooting acetylene/air flames
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