Synthesis of low bandgap polymer based on 3,6-dithien-2-yl-2,5-dialkylpyrrolo[3,4-c]pyrrole-1,4-dione for photovoltaic applications

A new 3,6-dithien-2-yl-2,5-dialkylpyrrolo[3,4-c]pyrrole-1,4-dione (DTDPP) based polymer, poly{thieno[3,2-b]thiophene-alt-3,6-dithien-2-yl-2,5-di(2-octyldodecyl)-pyrrolo[3,4-c]pyrrole-1,4-dione} (PTT-DTDPP) was synthesized by the Stille coupling reaction. The polymer shows a broad absorption in visib...

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Veröffentlicht in:Solar energy materials and solar cells 2011-04, Vol.95 (4), p.1168-1173
Hauptverfasser: Zhang, Guobing, Fu, Yingying, Xie, Zhiyuan, Zhang, Qing
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container_end_page 1173
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container_title Solar energy materials and solar cells
container_volume 95
creator Zhang, Guobing
Fu, Yingying
Xie, Zhiyuan
Zhang, Qing
description A new 3,6-dithien-2-yl-2,5-dialkylpyrrolo[3,4-c]pyrrole-1,4-dione (DTDPP) based polymer, poly{thieno[3,2-b]thiophene-alt-3,6-dithien-2-yl-2,5-di(2-octyldodecyl)-pyrrolo[3,4-c]pyrrole-1,4-dione} (PTT-DTDPP) was synthesized by the Stille coupling reaction. The polymer shows a broad absorption in visible and near infrared region and displays suitable HOMO/LUMO energy levels for marching with those of PCBM acceptor. The photovoltaic properties of the polymer were studied by bulk heterojunction solar cell devices using PTT-DTDPP as donor and PC 71BM as acceptor. The power conversion efficiency of device achieved 1.60% under the illumination of AM1.5 G, 100 mW/cm 2.
doi_str_mv 10.1016/j.solmat.2010.12.049
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subjects Conjugated polymer
Conversion
Devices
Displays
DTDPP
Illumination
Infrared
Low bandgap
Photovoltaic cells
Polymer solar cells
Solar cells
Solar energy
Solar power generation
title Synthesis of low bandgap polymer based on 3,6-dithien-2-yl-2,5-dialkylpyrrolo[3,4-c]pyrrole-1,4-dione for photovoltaic applications
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