Graphite as a highly efficient and stable catalyst for the production of lactones
The carbon materials carbon nanotubes (CNTs), graphite, and activated carbon were tested as metal-free catalysts. They showed excellent activity and selectivity in the Baeyer–Villiger (B–V) oxidation of cyclohexanone at room temperature using dioxygen (O2) as oxidant and benzaldehyde as sacrificial...
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| Veröffentlicht in: | Carbon (New York) 2013-04, Vol.55, p.269-275 |
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| container_title | Carbon (New York) |
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| creator | Li, Yue-Fang Guo, Ming-Qi Yin, Shuang-Feng Chen, Lang Zhou, Yong-Bo Qiu, Ren-Hua Au, Chak-Tong |
| description | The carbon materials carbon nanotubes (CNTs), graphite, and activated carbon were tested as metal-free catalysts. They showed excellent activity and selectivity in the Baeyer–Villiger (B–V) oxidation of cyclohexanone at room temperature using dioxygen (O2) as oxidant and benzaldehyde as sacrificial agent. Among them graphite was found to be the most suitable for the formation of lactones from cyclic ketones, showing good recyclability and reusability. The use of the metal-free catalysts enables a green process for the production of lactones from ketones under mild reactions. |
| doi_str_mv | 10.1016/j.carbon.2012.12.036 |
| format | Article |
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Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Yue-Fang</creatorcontrib><creatorcontrib>Guo, Ming-Qi</creatorcontrib><creatorcontrib>Yin, Shuang-Feng</creatorcontrib><creatorcontrib>Chen, Lang</creatorcontrib><creatorcontrib>Zhou, Yong-Bo</creatorcontrib><creatorcontrib>Qiu, Ren-Hua</creatorcontrib><creatorcontrib>Au, Chak-Tong</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Carbon (New York)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Yue-Fang</au><au>Guo, Ming-Qi</au><au>Yin, Shuang-Feng</au><au>Chen, Lang</au><au>Zhou, Yong-Bo</au><au>Qiu, Ren-Hua</au><au>Au, Chak-Tong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Graphite as a highly efficient and stable catalyst for the production of lactones</atitle><jtitle>Carbon (New York)</jtitle><date>2013-04-01</date><risdate>2013</risdate><volume>55</volume><spage>269</spage><epage>275</epage><pages>269-275</pages><issn>0008-6223</issn><eissn>1873-3891</eissn><coden>CRBNAH</coden><abstract>The carbon materials carbon nanotubes (CNTs), graphite, and activated carbon were tested as metal-free catalysts. 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| fulltext | fulltext |
| identifier | ISSN: 0008-6223 |
| ispartof | Carbon (New York), 2013-04, Vol.55, p.269-275 |
| issn | 0008-6223 1873-3891 |
| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Benzaldehyde Carbon Catalysis Catalysts Chemistry Cyclohexanone Exact sciences and technology General and physical chemistry Graphite Ketones Lactones Recyclability Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | Graphite as a highly efficient and stable catalyst for the production of lactones |
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