Phosphite-driven, [CpRh(bpy)(H2O)]2+-catalyzed reduction of nicotinamide and flavin cofactors: characterization and application to promote chemoenzymatic reduction reactions

The organometallic compound [Cp*Rh(bpy)(H2O)]2+ is a versatile catalyst for the in situ regeneration of reduced nicotinamides and flavins by catalyzing the electron transfer between the cathode or formate to the oxidized cofactors and prosthetic groups. In the present contribution we demonstrate the...

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Veröffentlicht in:	Applied organometallic chemistry 2010-05, Vol.24 (5), p.380-385
Hauptverfasser:	Grau, Maria Mifsud, Poizat, Maël, Arends, Isabel W. C. E., Hollmann, Frank
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts chemoenzymatic reduction reactions cofactor regeneration Equivalence Formates Nicotinamide phosphite Prosthetics Reduction Regeneration
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