Effect of doping precursors on the optical properties of Ce-doped ZnO nanorods

We have investigated the use of different cerium precursors for fabrication of Ce doped ZnO nanorods by electrodeposition. ZnO nanorods fabricated with different Ce precursors had similar morphology, but very different optical properties. The influence of annealing in oxygen at different temperature...

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Veröffentlicht in:Thin solid films 2011-11, Vol.520 (3), p.1125-1130
Hauptverfasser: Chen, X.Y., Fang, F., Ng, A.M.C., Djurišić, A.B., Chan, W.K., Lui, H.F., Fong, P.W.K., Surya, C., Cheah, K.W.
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container_end_page 1130
container_issue 3
container_start_page 1125
container_title Thin solid films
container_volume 520
creator Chen, X.Y.
Fang, F.
Ng, A.M.C.
Djurišić, A.B.
Chan, W.K.
Lui, H.F.
Fong, P.W.K.
Surya, C.
Cheah, K.W.
description We have investigated the use of different cerium precursors for fabrication of Ce doped ZnO nanorods by electrodeposition. ZnO nanorods fabricated with different Ce precursors had similar morphology, but very different optical properties. The influence of annealing in oxygen at different temperatures on the optical properties of Ce doped ZnO nanorods was also studied. The as-grown samples exhibited very different ratios of ultraviolet to visible (defect) emission. The relative contributions of green and orange–red emissions in the emission spectra of annealed samples were also dependent on the precursor used, indicating that the types and concentrations of native defects were dependent on the precursor used. To explore the possibility of applications of these nanorods in ZnO-based devices, nanorods were also grown on p-GaN substrates. Two different Ce precursors in this case resulted in different current–voltage curves, as well as different electroluminescence and photoluminescence spectra of the devices. Obtained results are discussed.
doi_str_mv 10.1016/j.tsf.2011.08.022
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subjects Annealing
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Cross-disciplinary physics: materials science
rheology
Defect annealing
Devices
Electrodeposition, electroplating
Exact sciences and technology
Light-emitting diodes
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Nanorods
Nanoscale materials and structures: fabrication and characterization
Nanotubes
Optical properties
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Optical properties of specific thin films
Other topics in nanoscale materials and structures
Oxides
Physics
Precursors
Ultraviolet
Zinc oxide
title Effect of doping precursors on the optical properties of Ce-doped ZnO nanorods
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