Thermal and odd–even behaviour in a homologous series of lithium n-alkanoates

► Odd-even alteration, in a homologous series of lithium n-alkanoates, is explained. ► Odd chain length compounds are higher in density and melting point. ► This results from a more favourable interaction between methyl groups from opposite chains in a lamellar bi-layer. Thermotropic phase transitio...

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Veröffentlicht in:	The Journal of chemical thermodynamics 2011-04, Vol.43 (4), p.584-590
Hauptverfasser:	White, Nicole A.S., Ellis, Henry A., Nelson, Peter N., Maragh, Paul T.
Format:	Artikel
Sprache:	eng
Schlagworte:	13C NMR spectroscopy Alternations Chains Chemical thermodynamics Chemistry Density Differential scanning calorimetry Elements, mineral and organic compounds Entropy Exact sciences and technology General and physical chemistry Lithium Lithium n-alkanoates Melting temperature Melts Molecular conformation Phase transformations Polarizing light microscopy Thermodynamic properties Thermodynamics
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