Deposited dielectrics on metal thin films using silicon and glass substrates for hot electron-induced electrochemiluminescence

Electrochemiluminescence by tunnel emission of hot electrons into aqueous solution is a sensitive method for detection of luminophores e.g. rare-earth chelates, which may be used as labels in bioassays. Electrons are injected into solution from an insulating film-coated working electrode, working ag...

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Veröffentlicht in:Thin solid films 2010-10, Vol.519 (1), p.430-433
Hauptverfasser: Niskanen, Antti J., Ylinen-Hinkka, Tiina, Pusa, Matti, Kulmala, Sakari, Franssila, Sami
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container_end_page 433
container_issue 1
container_start_page 430
container_title Thin solid films
container_volume 519
creator Niskanen, Antti J.
Ylinen-Hinkka, Tiina
Pusa, Matti
Kulmala, Sakari
Franssila, Sami
description Electrochemiluminescence by tunnel emission of hot electrons into aqueous solution is a sensitive method for detection of luminophores e.g. rare-earth chelates, which may be used as labels in bioassays. Electrons are injected into solution from an insulating film-coated working electrode, working against a platinum counter electrode. Conductive silicon electrodes with various tunnel dielectric materials e.g. thermal oxide have been used in previous work. In this paper we explore the use of metal thin film electrodes on silicon and glass substrates, using tunneling dielectrics of aluminum oxide and silicon dioxide made by the low-temperature processes of atomic layer deposition or plasma-enhanced chemical vapor deposition.
doi_str_mv 10.1016/j.tsf.2010.07.027
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subjects Aluminum oxide
Atomic layer deposition
Chemical vapor deposition
Chemical vapor deposition (including plasma-enhanced cvd, mocvd, etc.)
Chemiluminescence
Chemistry
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Cross-disciplinary physics: materials science
rheology
Deposition
Dielectric, piezoelectric, ferroelectric and antiferroelectric materials
Dielectrics
Dielectrics, piezoelectrics, and ferroelectrics and their properties
Electrochemiluminescence
Electrochemistry
Electrodes
Electrodes: preparations and properties
Exact sciences and technology
Film-coated electrodes
General and physical chemistry
Glass
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Physics
Rare earth metals
Silicon substrates
Thin films
Thin insulating
Vapor phase epitaxy
growth from vapor phase
title Deposited dielectrics on metal thin films using silicon and glass substrates for hot electron-induced electrochemiluminescence
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