High-quality poly (N-phenyl-2-naphthylamine) films: Electrosynthesis and fluorescent properties
A novel conducting poly (N-phenyl-2-naphthylamine) (PPBNA) film was successfully electropolymerized by direct anodic oxidation of its monomer N-phenyl-2-naphthylamine in boron trifluoride diethyl etherate. The prepared PPBNA films showed good redox activity and structural stability even in concentra...
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Veröffentlicht in: | Materials letters 2010-10, Vol.64 (20), p.2211-2214 |
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creator | Lei, Wu Xie, Xingen Hao, Qingli Xia, Mingzhu Wang, Fengyun |
description | A novel conducting poly (N-phenyl-2-naphthylamine) (PPBNA) film was successfully electropolymerized by direct anodic oxidation of its monomer N-phenyl-2-naphthylamine in boron trifluoride diethyl etherate. The prepared PPBNA films showed good redox activity and structural stability even in concentrated sulfuric acid. The impedance spectra of PPBNA films demonstrated that the electron transfer resistance was around 80
Ω. The fluorescent results indicated that the emission band of PPBNA was red-shifted about 30
nm in comparison with that of the monomer. The fluorescent spectra exhibited that the monomer and PPBNA films were excellent blue-light-emitting and blue-green-light-emitting material, respectively. |
doi_str_mv | 10.1016/j.matlet.2010.07.045 |
format | Article |
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Ω. The fluorescent results indicated that the emission band of PPBNA was red-shifted about 30
nm in comparison with that of the monomer. The fluorescent spectra exhibited that the monomer and PPBNA films were excellent blue-light-emitting and blue-green-light-emitting material, respectively.</description><identifier>ISSN: 0167-577X</identifier><identifier>EISSN: 1873-4979</identifier><identifier>DOI: 10.1016/j.matlet.2010.07.045</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Anodizing ; Boron ; Characterization methods ; Conducting polymer ; Conduction ; Electron transfer ; Electronic materials ; Electropolymerization ; Emission ; Fluorescence property ; Impedance ; Monomers ; N-phenyl-2-naphthylamine ; Spectra ; Structural stability</subject><ispartof>Materials letters, 2010-10, Vol.64 (20), p.2211-2214</ispartof><rights>2010 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c339t-e0febc21d0b99643040ec16a9fbdee2f900ba7a96a320f86c4dce74602dc67893</citedby><cites>FETCH-LOGICAL-c339t-e0febc21d0b99643040ec16a9fbdee2f900ba7a96a320f86c4dce74602dc67893</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.matlet.2010.07.045$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27922,27923,45993</link.rule.ids></links><search><creatorcontrib>Lei, Wu</creatorcontrib><creatorcontrib>Xie, Xingen</creatorcontrib><creatorcontrib>Hao, Qingli</creatorcontrib><creatorcontrib>Xia, Mingzhu</creatorcontrib><creatorcontrib>Wang, Fengyun</creatorcontrib><title>High-quality poly (N-phenyl-2-naphthylamine) films: Electrosynthesis and fluorescent properties</title><title>Materials letters</title><description>A novel conducting poly (N-phenyl-2-naphthylamine) (PPBNA) film was successfully electropolymerized by direct anodic oxidation of its monomer N-phenyl-2-naphthylamine in boron trifluoride diethyl etherate. The prepared PPBNA films showed good redox activity and structural stability even in concentrated sulfuric acid. The impedance spectra of PPBNA films demonstrated that the electron transfer resistance was around 80
Ω. The fluorescent results indicated that the emission band of PPBNA was red-shifted about 30
nm in comparison with that of the monomer. The fluorescent spectra exhibited that the monomer and PPBNA films were excellent blue-light-emitting and blue-green-light-emitting material, respectively.</description><subject>Anodizing</subject><subject>Boron</subject><subject>Characterization methods</subject><subject>Conducting polymer</subject><subject>Conduction</subject><subject>Electron transfer</subject><subject>Electronic materials</subject><subject>Electropolymerization</subject><subject>Emission</subject><subject>Fluorescence property</subject><subject>Impedance</subject><subject>Monomers</subject><subject>N-phenyl-2-naphthylamine</subject><subject>Spectra</subject><subject>Structural stability</subject><issn>0167-577X</issn><issn>1873-4979</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp9kE9LAzEQxYMoWKvfwMMe6yHr7G66aTwIUqoVil4UvIU0O-umZP80SYX99qbUs6eB4b03836E3GaQZpCV97u0VcFiSHOIK-ApsPkZmWQLXlAmuDgnkyjjdM751yW58n4HAEwAmxC5Nt8N3R-UNWFMht6OyeyNDg12o6U57dTQhGa0qjUd3iW1sa1_SFYWdXC9H7vQoDc-UV2V1PbQO_Qau5AMrh_QBYP-mlzUynq8-ZtT8vm8-liu6eb95XX5tKG6KESgCDVudZ5VsBWiZAUwQJ2VStTbCjGvBcBWcSVKVeRQL0rNKo2clZBXuuQLUUzJ7JQbT-8P6INsTfzFWtVhf_Ay1s9yUcw5RCk7SXWs4B3WcnCmVW6UGcgjT7mTJ57yyFMCl5FntD2ebBhr_Bh00muDncbKuIhDVr35P-AXgquCiQ</recordid><startdate>20101031</startdate><enddate>20101031</enddate><creator>Lei, Wu</creator><creator>Xie, Xingen</creator><creator>Hao, Qingli</creator><creator>Xia, Mingzhu</creator><creator>Wang, Fengyun</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20101031</creationdate><title>High-quality poly (N-phenyl-2-naphthylamine) films: Electrosynthesis and fluorescent properties</title><author>Lei, Wu ; Xie, Xingen ; Hao, Qingli ; Xia, Mingzhu ; Wang, Fengyun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c339t-e0febc21d0b99643040ec16a9fbdee2f900ba7a96a320f86c4dce74602dc67893</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Anodizing</topic><topic>Boron</topic><topic>Characterization methods</topic><topic>Conducting polymer</topic><topic>Conduction</topic><topic>Electron transfer</topic><topic>Electronic materials</topic><topic>Electropolymerization</topic><topic>Emission</topic><topic>Fluorescence property</topic><topic>Impedance</topic><topic>Monomers</topic><topic>N-phenyl-2-naphthylamine</topic><topic>Spectra</topic><topic>Structural stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lei, Wu</creatorcontrib><creatorcontrib>Xie, Xingen</creatorcontrib><creatorcontrib>Hao, Qingli</creatorcontrib><creatorcontrib>Xia, Mingzhu</creatorcontrib><creatorcontrib>Wang, Fengyun</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Materials letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lei, Wu</au><au>Xie, Xingen</au><au>Hao, Qingli</au><au>Xia, Mingzhu</au><au>Wang, Fengyun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High-quality poly (N-phenyl-2-naphthylamine) films: Electrosynthesis and fluorescent properties</atitle><jtitle>Materials letters</jtitle><date>2010-10-31</date><risdate>2010</risdate><volume>64</volume><issue>20</issue><spage>2211</spage><epage>2214</epage><pages>2211-2214</pages><issn>0167-577X</issn><eissn>1873-4979</eissn><abstract>A novel conducting poly (N-phenyl-2-naphthylamine) (PPBNA) film was successfully electropolymerized by direct anodic oxidation of its monomer N-phenyl-2-naphthylamine in boron trifluoride diethyl etherate. The prepared PPBNA films showed good redox activity and structural stability even in concentrated sulfuric acid. The impedance spectra of PPBNA films demonstrated that the electron transfer resistance was around 80
Ω. The fluorescent results indicated that the emission band of PPBNA was red-shifted about 30
nm in comparison with that of the monomer. The fluorescent spectra exhibited that the monomer and PPBNA films were excellent blue-light-emitting and blue-green-light-emitting material, respectively.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.matlet.2010.07.045</doi><tpages>4</tpages></addata></record> |
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source | ScienceDirect Journals (5 years ago - present) |
subjects | Anodizing Boron Characterization methods Conducting polymer Conduction Electron transfer Electronic materials Electropolymerization Emission Fluorescence property Impedance Monomers N-phenyl-2-naphthylamine Spectra Structural stability |
title | High-quality poly (N-phenyl-2-naphthylamine) films: Electrosynthesis and fluorescent properties |
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