Construction of right-handed-, left-handed-, and racemic helical coordination polymers. Enantioselective recognition using chiral helical crystals

Infinite square-tubular helices, [CuCl2(L)(S)] (L = bis(4-pyridyl)methylvinylsilane; S = Me2SO, HCONMe2), were constructed. This helical system affords three kinds of P, M crystals in Me2SO, and racemic crystals in HCONMe2. The cyclic voltammogram (CV) technique using the M-crystals is an effective...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (38), p.4000-4002
Hauptverfasser:	Park, Kyung Hwan, Noh, Tae Hwan, Shim, Yoon-Bo, Jung, Ok-Sang
Format:	Artikel
Sprache:	eng
Schlagworte:	Construction Coordination polymers Copper - chemistry Crystallization Crystallography, X-Ray Crystals Dimethyl Sulfoxide - chemistry Dimethylformamide - chemistry Helical Helices Models, Molecular Polymers - chemistry Proline Proline - chemistry Recognition Silanes - chemistry Stereoisomerism
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