Push–pull chromophores comprising benzothiazolium acceptor and thiophene auxiliary donor moieties: Synthesis, structure, linear and quadratic non-linear optical properties

Novel, push–pull chromophores combining a cationic benzothiazolium acceptor moiety and either one or two thiophene rings as a part of the conjugated π-system between the donor and the acceptor moieties have been synthesized and characterized. The chromophores displayed pronounced quadratic NLO activ...

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Veröffentlicht in:Dyes and pigments 2009-06, Vol.81 (3), p.203-210
Hauptverfasser: Quist, Florence, Vande Velde, Christophe M.L., Didier, Delphine, Teshome, Ayele, Asselberghs, Inge, Clays, Koen, Sergeyev, Sergey
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container_end_page 210
container_issue 3
container_start_page 203
container_title Dyes and pigments
container_volume 81
creator Quist, Florence
Vande Velde, Christophe M.L.
Didier, Delphine
Teshome, Ayele
Asselberghs, Inge
Clays, Koen
Sergeyev, Sergey
description Novel, push–pull chromophores combining a cationic benzothiazolium acceptor moiety and either one or two thiophene rings as a part of the conjugated π-system between the donor and the acceptor moieties have been synthesized and characterized. The chromophores displayed pronounced quadratic NLO activity with their first molecular hyper polarizabilities in agreement with their linear spectral properties.
doi_str_mv 10.1016/j.dyepig.2008.10.004
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source Elsevier ScienceDirect Journals Complete
subjects Benzothiazolium
Cationic
Chromophores
Dyes
Non-linear optics
Nonlinearity
Optical properties
Push–pull chromophores
Second harmonic generation
Spectral lines
Synthesis
Thiophene
Thiophenes
title Push–pull chromophores comprising benzothiazolium acceptor and thiophene auxiliary donor moieties: Synthesis, structure, linear and quadratic non-linear optical properties
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