Push–pull chromophores comprising benzothiazolium acceptor and thiophene auxiliary donor moieties: Synthesis, structure, linear and quadratic non-linear optical properties
Novel, push–pull chromophores combining a cationic benzothiazolium acceptor moiety and either one or two thiophene rings as a part of the conjugated π-system between the donor and the acceptor moieties have been synthesized and characterized. The chromophores displayed pronounced quadratic NLO activ...
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Veröffentlicht in: | Dyes and pigments 2009-06, Vol.81 (3), p.203-210 |
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container_title | Dyes and pigments |
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creator | Quist, Florence Vande Velde, Christophe M.L. Didier, Delphine Teshome, Ayele Asselberghs, Inge Clays, Koen Sergeyev, Sergey |
description | Novel, push–pull chromophores combining a cationic benzothiazolium acceptor moiety and either one or two thiophene rings as a part of the conjugated π-system between the donor and the acceptor moieties have been synthesized and characterized. The chromophores displayed pronounced quadratic NLO activity with their first molecular hyper polarizabilities in agreement with their linear spectral properties. |
doi_str_mv | 10.1016/j.dyepig.2008.10.004 |
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language | eng |
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source | Elsevier ScienceDirect Journals Complete |
subjects | Benzothiazolium Cationic Chromophores Dyes Non-linear optics Nonlinearity Optical properties Push–pull chromophores Second harmonic generation Spectral lines Synthesis Thiophene Thiophenes |
title | Push–pull chromophores comprising benzothiazolium acceptor and thiophene auxiliary donor moieties: Synthesis, structure, linear and quadratic non-linear optical properties |
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