Unsymmetrical bifunctional trithiocarbonate as unexpected by-product in the synthesis of a dithioester RAFT agent

The trithiocarbonate 2-(benzylsulfanylthiocarbonylsulfanyl) propanoic acid is formed as minor by-product in the synthesis of the dithioester 2-((2-phenylthioacetyl)sulfanyl) propanoic acid via the Grignard route. The mechanism for this side reaction is not clear. The isolated trithiocarbonate may ac...

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Veröffentlicht in:	Colloid and polymer science 2007-05, Vol.285 (8), p.947-952
Hauptverfasser:	LASCHEWSKY, André, POUND, Gwenaelle, SKRABANIA, Katja, HOLDT, Hans-Jürgen, TELLER, Joachim
Format:	Artikel
Sprache:	eng
Schlagworte:	Acrylamide Applied sciences Byproducts Colloids Exact sciences and technology Free radical polymerization Free radicals Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts Propanoic acid Propionic acid Rafts Synthesis
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