The synthesis, characterization and third-order nonlinear optical character of poly(2,5-dipropargyloxybenzoate) containing a polar aromatic diacetylene
The glass transition temperature of the novel compound, poly( 2, 5-dipropargyloxybenzoate) containing a polar aromatic diacetylene was 105 °C and differential scanning calorimetry showed two exothermic peaks due to the opening of the hexa-2,4-diynylene-1,6-dioxy group and the aromatic diacetylene gr...
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| Veröffentlicht in: | Dyes and pigments 2011-02, Vol.88 (2), p.129-134 |
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| creator | Castañon, Sandra L. Beristain, Miriam F. Ortega, Alejandra Gómez-Sosa, Gustavo Muñoz, Eduardo Perez-Martínez, Ana Laura Ogawa, Takeshi Halim, M. Faisal Smith, Francis Walser, Ardie Dorsinville, Roger |
| description | The glass transition temperature of the novel compound, poly(
2,
5-dipropargyloxybenzoate) containing a polar aromatic diacetylene was 105 °C and differential scanning calorimetry showed two exothermic peaks due to the opening of the hexa-2,4-diynylene-1,6-dioxy group and the aromatic diacetylene group. Two types of free radical were detected in the electron spin resonance spectra of the heated polymer, one formed by cross-linking of the main chain hexa-2,4-diynylene-1,6-dioxy group and another arising from the aromatic chromophore diacetylene. The third-order nonlinear optical susceptibility,
χ
(3), of the polymer film determined using the Z-scan technique was −4.5 ± 1 × 10
−10 esu. When the films were irradiated by UV light at 140 °C, they formed micro-cracks due to intense cross-linking. |
| doi_str_mv | 10.1016/j.dyepig.2010.05.012 |
| format | Article |
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2,
5-dipropargyloxybenzoate) containing a polar aromatic diacetylene was 105 °C and differential scanning calorimetry showed two exothermic peaks due to the opening of the hexa-2,4-diynylene-1,6-dioxy group and the aromatic diacetylene group. Two types of free radical were detected in the electron spin resonance spectra of the heated polymer, one formed by cross-linking of the main chain hexa-2,4-diynylene-1,6-dioxy group and another arising from the aromatic chromophore diacetylene. The third-order nonlinear optical susceptibility,
χ
(3), of the polymer film determined using the Z-scan technique was −4.5 ± 1 × 10
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2,
5-dipropargyloxybenzoate) containing a polar aromatic diacetylene was 105 °C and differential scanning calorimetry showed two exothermic peaks due to the opening of the hexa-2,4-diynylene-1,6-dioxy group and the aromatic diacetylene group. Two types of free radical were detected in the electron spin resonance spectra of the heated polymer, one formed by cross-linking of the main chain hexa-2,4-diynylene-1,6-dioxy group and another arising from the aromatic chromophore diacetylene. The third-order nonlinear optical susceptibility,
χ
(3), of the polymer film determined using the Z-scan technique was −4.5 ± 1 × 10
−10 esu. When the films were irradiated by UV light at 140 °C, they formed micro-cracks due to intense cross-linking.</description><subject>Aromatic compounds</subject><subject>Cross-linking</subject><subject>Crosslinking</subject><subject>Differential scanning calorimetry</subject><subject>Electron spin resonance</subject><subject>Free radicals</subject><subject>Microcracks</subject><subject>Nonlinear optics</subject><subject>Nonlinearity</subject><subject>Polar aromatic diacetylene</subject><subject>Spectra</subject><subject>Z-Scan</subject><issn>0143-7208</issn><issn>1873-3743</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kcuKFDEUhoMo2I6-gYssR5hqc-1UbQQZxgsMuBnXIXVyqjtNdVImGbHmRXxd07TgzlUO4f__c_kIecvZljO-e3_c-hWXsN8K1r6Y3jIunpEN743spFHyOdkwrmRnBOtfklelHBljvRR8Q34_HJCWNdYDllBuKBxcdlAxhydXQ4rURU_rIWTfpewx05jiHCK6TNNSA7j5n4WmiS5pXq_Fje58WHJaXN6vc_q1jhifkqv4jkKK1YUY4p66s7oFuZxOrRlQHxxgXWeM-Jq8mNxc8M3f94p8_3T3cPulu__2-evtx_sOpBxqp5BrVEyNOII3YhjHwZhBSjn1oECq3uuxV5oNKPRopsH3YtdKJkcwwPQkr8j1JbdN--MRS7WnUADn2UVMj8XyneFCt0P2TaouUsiplIyTXXI4ubxazuyZgz3aCwd75mCZto1Ds3242LCt8TNgtgUCRkAfMkK1PoX_B_wBb3CW9g</recordid><startdate>20110201</startdate><enddate>20110201</enddate><creator>Castañon, Sandra L.</creator><creator>Beristain, Miriam F.</creator><creator>Ortega, Alejandra</creator><creator>Gómez-Sosa, Gustavo</creator><creator>Muñoz, Eduardo</creator><creator>Perez-Martínez, Ana Laura</creator><creator>Ogawa, Takeshi</creator><creator>Halim, M. Faisal</creator><creator>Smith, Francis</creator><creator>Walser, Ardie</creator><creator>Dorsinville, Roger</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20110201</creationdate><title>The synthesis, characterization and third-order nonlinear optical character of poly(2,5-dipropargyloxybenzoate) containing a polar aromatic diacetylene</title><author>Castañon, Sandra L. ; Beristain, Miriam F. ; Ortega, Alejandra ; Gómez-Sosa, Gustavo ; Muñoz, Eduardo ; Perez-Martínez, Ana Laura ; Ogawa, Takeshi ; Halim, M. Faisal ; Smith, Francis ; Walser, Ardie ; Dorsinville, Roger</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c339t-4e15e404bebcd729bb9779333f8c4c348d5b84509e25b7f9d826e2503bc7c05f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Aromatic compounds</topic><topic>Cross-linking</topic><topic>Crosslinking</topic><topic>Differential scanning calorimetry</topic><topic>Electron spin resonance</topic><topic>Free radicals</topic><topic>Microcracks</topic><topic>Nonlinear optics</topic><topic>Nonlinearity</topic><topic>Polar aromatic diacetylene</topic><topic>Spectra</topic><topic>Z-Scan</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Castañon, Sandra L.</creatorcontrib><creatorcontrib>Beristain, Miriam F.</creatorcontrib><creatorcontrib>Ortega, Alejandra</creatorcontrib><creatorcontrib>Gómez-Sosa, Gustavo</creatorcontrib><creatorcontrib>Muñoz, Eduardo</creatorcontrib><creatorcontrib>Perez-Martínez, Ana Laura</creatorcontrib><creatorcontrib>Ogawa, Takeshi</creatorcontrib><creatorcontrib>Halim, M. Faisal</creatorcontrib><creatorcontrib>Smith, Francis</creatorcontrib><creatorcontrib>Walser, Ardie</creatorcontrib><creatorcontrib>Dorsinville, Roger</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Dyes and pigments</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Castañon, Sandra L.</au><au>Beristain, Miriam F.</au><au>Ortega, Alejandra</au><au>Gómez-Sosa, Gustavo</au><au>Muñoz, Eduardo</au><au>Perez-Martínez, Ana Laura</au><au>Ogawa, Takeshi</au><au>Halim, M. Faisal</au><au>Smith, Francis</au><au>Walser, Ardie</au><au>Dorsinville, Roger</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The synthesis, characterization and third-order nonlinear optical character of poly(2,5-dipropargyloxybenzoate) containing a polar aromatic diacetylene</atitle><jtitle>Dyes and pigments</jtitle><date>2011-02-01</date><risdate>2011</risdate><volume>88</volume><issue>2</issue><spage>129</spage><epage>134</epage><pages>129-134</pages><issn>0143-7208</issn><eissn>1873-3743</eissn><abstract>The glass transition temperature of the novel compound, poly(
2,
5-dipropargyloxybenzoate) containing a polar aromatic diacetylene was 105 °C and differential scanning calorimetry showed two exothermic peaks due to the opening of the hexa-2,4-diynylene-1,6-dioxy group and the aromatic diacetylene group. Two types of free radical were detected in the electron spin resonance spectra of the heated polymer, one formed by cross-linking of the main chain hexa-2,4-diynylene-1,6-dioxy group and another arising from the aromatic chromophore diacetylene. The third-order nonlinear optical susceptibility,
χ
(3), of the polymer film determined using the Z-scan technique was −4.5 ± 1 × 10
−10 esu. When the films were irradiated by UV light at 140 °C, they formed micro-cracks due to intense cross-linking.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.dyepig.2010.05.012</doi><tpages>6</tpages></addata></record> |
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| subjects | Aromatic compounds Cross-linking Crosslinking Differential scanning calorimetry Electron spin resonance Free radicals Microcracks Nonlinear optics Nonlinearity Polar aromatic diacetylene Spectra Z-Scan |
| title | The synthesis, characterization and third-order nonlinear optical character of poly(2,5-dipropargyloxybenzoate) containing a polar aromatic diacetylene |
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