Surface modification of an epoxy resin with polyamines via cyanuric chloride coupling
The presence of polyamine groups on the surface of dielectric resins potentially improves the adhesion with electrochemically deposited metals. In this article, first cyanuric chloride is covalently bound to the surface hydroxyl groups of the epoxy resin. The remaining reactive sites on the coupled...
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| Veröffentlicht in: | Applied surface science 2010-08, Vol.256 (21), p.6269-6278 |
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| container_issue | 21 |
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| container_title | Applied surface science |
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| creator | Schaubroeck, David De Baets, Johan Desmet, Tim Dubruel, Peter Schacht, Etienne Van Vaeck, Luc Van Calster, André |
| description | The presence of polyamine groups on the surface of dielectric resins potentially improves the adhesion with electrochemically deposited metals. In this article, first cyanuric chloride is covalently bound to the surface hydroxyl groups of the epoxy resin. The remaining reactive sites on the coupled cyanuric chloride molecule are then used to anchor polyamines. New data on the triazine coupling is presented. The surface reactions are monitored and characterized by means of ATR-IR, SEM-EDS, XPS and ToF-S-SIMS. |
| doi_str_mv | 10.1016/j.apsusc.2010.04.003 |
| format | Article |
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In this article, first cyanuric chloride is covalently bound to the surface hydroxyl groups of the epoxy resin. The remaining reactive sites on the coupled cyanuric chloride molecule are then used to anchor polyamines. New data on the triazine coupling is presented. 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In this article, first cyanuric chloride is covalently bound to the surface hydroxyl groups of the epoxy resin. The remaining reactive sites on the coupled cyanuric chloride molecule are then used to anchor polyamines. New data on the triazine coupling is presented. 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| fulltext | fulltext |
| identifier | ISSN: 0169-4332 |
| ispartof | Applied surface science, 2010-08, Vol.256 (21), p.6269-6278 |
| issn | 0169-4332 1873-5584 |
| language | eng |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Adhesion Chlorides Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Coupling (molecular) Covalence Cross-disciplinary physics: materials science rheology Cyanuric chloride Deposition Electroless copper deposition Epoxy resins Exact sciences and technology Physics Polyamines Polyethylenimine Surface characterization Surface reactions X-ray photoelectron spectroscopy |
| title | Surface modification of an epoxy resin with polyamines via cyanuric chloride coupling |
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