The effect of temperature on the exciton absorption of copper chloride and copper bromide nanocrystals in potassium-aluminum-borate glass
The absorption spectra of nanosized crystals of copper (I) halides distributed in the potassium-aluminum borate glass system were investigated in the region of the exciton absorption band in the temperature range from 20 to 300°C. The temperature dependences of the exciton absorption band of CuHal (...
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Veröffentlicht in: | Glass physics and chemistry 2015, Vol.41 (1), p.81-88 |
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creator | Babkina, A. N. Nikonorov, N. V. Tsekhomskii, V. A. Shirshnev, P. S. |
description | The absorption spectra of nanosized crystals of copper (I) halides distributed in the potassium-aluminum borate glass system were investigated in the region of the exciton absorption band in the temperature range from 20 to 300°C. The temperature dependences of the exciton absorption band of CuHal (Hal = Cl, Br) nanocrystals, which were obtained upon the heating and cooling of the sample, have a form of hysteresis. The melting (140–240°C) and crystallization (35–105°C) temperatures of copper (I) halide nanocrystals contained in the potassium-aluminum borate glass were determined by the optical spectroscopy method. |
doi_str_mv | 10.1134/S1087659615010046 |
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The melting (140–240°C) and crystallization (35–105°C) temperatures of copper (I) halide nanocrystals contained in the potassium-aluminum borate glass were determined by the optical spectroscopy method.</description><identifier>ISSN: 1087-6596</identifier><identifier>EISSN: 1608-313X</identifier><identifier>DOI: 10.1134/S1087659615010046</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>ABSORPTION ; Absorption spectra ; Borates ; BROMIDES ; Ceramics ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Composites ; Copper ; COPPER BROMIDE ; CRYSTAL STRUCTURE ; Excitation ; Glass ; GLASSES ; Halides ; Materials Science ; MICROSTRUCTURES ; Nanocrystals ; Nanostructure ; Natural Materials ; Physical Chemistry ; SPECTRA</subject><ispartof>Glass physics and chemistry, 2015, Vol.41 (1), p.81-88</ispartof><rights>Pleiades Publishing, Ltd. 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c349t-83016e06ac28abad4bf5984c5887482588200103522cc5d1c391f8fd1924a833</citedby><cites>FETCH-LOGICAL-c349t-83016e06ac28abad4bf5984c5887482588200103522cc5d1c391f8fd1924a833</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1087659615010046$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1087659615010046$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Babkina, A. 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The melting (140–240°C) and crystallization (35–105°C) temperatures of copper (I) halide nanocrystals contained in the potassium-aluminum borate glass were determined by the optical spectroscopy method.</description><subject>ABSORPTION</subject><subject>Absorption spectra</subject><subject>Borates</subject><subject>BROMIDES</subject><subject>Ceramics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Copper</subject><subject>COPPER BROMIDE</subject><subject>CRYSTAL STRUCTURE</subject><subject>Excitation</subject><subject>Glass</subject><subject>GLASSES</subject><subject>Halides</subject><subject>Materials Science</subject><subject>MICROSTRUCTURES</subject><subject>Nanocrystals</subject><subject>Nanostructure</subject><subject>Natural Materials</subject><subject>Physical Chemistry</subject><subject>SPECTRA</subject><issn>1087-6596</issn><issn>1608-313X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp1kc9KxDAQxosouK4-gLeAFy_VpGmyyVEW_4HgwT14K2ma7mZpk5qk4D6Cb-2UVRDF03zM9_tmQibLzgm-IoSW1y8EiwVnkhOGCcYlP8hmhGORU0JfD0GDnU_-cXYS4xZjLBeLcpZ9rDYGmbY1OiHfomT6wQSVxmCQdyhN5ru2CbSqow9DsiAB1H4AEOlN54NtDFKu-e7VwfdTyynnddjFpLqIrEODTypGO_a56sbeOhC1h10GrTswTrOjFkhz9lXn2erudrV8yJ-e7x-XN0-5pqVMuaCYcIO50oVQtWrKumVSlJoJsShFAaXA8AOUFYXWrCGaStKKtiGyKJWgdJ5d7scOwb-NJqaqt1GbrlPO-DFWhHMpMSuoBPTiF7r1Y3DwOKAYI5wKzIAie0oHH2MwbTUE26uwqwiupttUf24DmWKficC6tQk_Jv8b-gRG8JH1</recordid><startdate>2015</startdate><enddate>2015</enddate><creator>Babkina, A. 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S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The effect of temperature on the exciton absorption of copper chloride and copper bromide nanocrystals in potassium-aluminum-borate glass</atitle><jtitle>Glass physics and chemistry</jtitle><stitle>Glass Phys Chem</stitle><date>2015</date><risdate>2015</risdate><volume>41</volume><issue>1</issue><spage>81</spage><epage>88</epage><pages>81-88</pages><issn>1087-6596</issn><eissn>1608-313X</eissn><abstract>The absorption spectra of nanosized crystals of copper (I) halides distributed in the potassium-aluminum borate glass system were investigated in the region of the exciton absorption band in the temperature range from 20 to 300°C. The temperature dependences of the exciton absorption band of CuHal (Hal = Cl, Br) nanocrystals, which were obtained upon the heating and cooling of the sample, have a form of hysteresis. The melting (140–240°C) and crystallization (35–105°C) temperatures of copper (I) halide nanocrystals contained in the potassium-aluminum borate glass were determined by the optical spectroscopy method.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1087659615010046</doi><tpages>8</tpages></addata></record> |
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subjects | ABSORPTION Absorption spectra Borates BROMIDES Ceramics Characterization and Evaluation of Materials Chemistry and Materials Science Composites Copper COPPER BROMIDE CRYSTAL STRUCTURE Excitation Glass GLASSES Halides Materials Science MICROSTRUCTURES Nanocrystals Nanostructure Natural Materials Physical Chemistry SPECTRA |
title | The effect of temperature on the exciton absorption of copper chloride and copper bromide nanocrystals in potassium-aluminum-borate glass |
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