The effect of temperature on the exciton absorption of copper chloride and copper bromide nanocrystals in potassium-aluminum-borate glass

The absorption spectra of nanosized crystals of copper (I) halides distributed in the potassium-aluminum borate glass system were investigated in the region of the exciton absorption band in the temperature range from 20 to 300°C. The temperature dependences of the exciton absorption band of CuHal (...

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Veröffentlicht in:Glass physics and chemistry 2015, Vol.41 (1), p.81-88
Hauptverfasser: Babkina, A. N., Nikonorov, N. V., Tsekhomskii, V. A., Shirshnev, P. S.
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creator Babkina, A. N.
Nikonorov, N. V.
Tsekhomskii, V. A.
Shirshnev, P. S.
description The absorption spectra of nanosized crystals of copper (I) halides distributed in the potassium-aluminum borate glass system were investigated in the region of the exciton absorption band in the temperature range from 20 to 300°C. The temperature dependences of the exciton absorption band of CuHal (Hal = Cl, Br) nanocrystals, which were obtained upon the heating and cooling of the sample, have a form of hysteresis. The melting (140–240°C) and crystallization (35–105°C) temperatures of copper (I) halide nanocrystals contained in the potassium-aluminum borate glass were determined by the optical spectroscopy method.
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subjects ABSORPTION
Absorption spectra
Borates
BROMIDES
Ceramics
Characterization and Evaluation of Materials
Chemistry and Materials Science
Composites
Copper
COPPER BROMIDE
CRYSTAL STRUCTURE
Excitation
Glass
GLASSES
Halides
Materials Science
MICROSTRUCTURES
Nanocrystals
Nanostructure
Natural Materials
Physical Chemistry
SPECTRA
title The effect of temperature on the exciton absorption of copper chloride and copper bromide nanocrystals in potassium-aluminum-borate glass
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