Revealing the specific solute–solvent interactions via the measurements of the NMR spin–spin coupling constants

[Display omitted] •Solvents are divided onto subsets by changes of 1JCH induced by solvent polarity.•Subset I contains solvents inducing changes linearly dependent on solvent polarity.•Subset II contains solvents with various specific solute–solvents interactions.•Deviations of 1JCH from fitting lin...

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Veröffentlicht in:	Journal of molecular structure 2015-03, Vol.1083, p.175-178
Hauptverfasser:	Shahkhatuni, Astghik A., Shahkhatuni, Aleksan G., Minasyan, Nune S., Panosyan, Henry A., Sahakyan, Aleksandr B.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic hydrocarbons Conjugation Constants Derivatives Dielectric constant Dielectric permittivity Hydrogen bonding Methane NMR spectroscopy Solvent effects Solvent polarity Solvent sensitivity Solvents Spin-spin coupling Spin–spin coupling constants
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