Martensite decomposition in Cu–Al–Mn–Ag alloys

•Martensite decomposition in Cu–Al–Mn–Ag alloys is mainly influenced by Mn.•Interaction between Cu–Mn atomic pairs increases activation energy.•Cu diffusion is disturbed by the interaction between Cu–Mn atomic pairs. The influence of Mn and Ag additions on the isothermal kinetics of martensite decom...

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Veröffentlicht in:Journal of alloys and compounds 2014-12, Vol.615, p.S156-S159
Hauptverfasser: Santos, Camila Maria Andrade dos, Adorno, Antonio Tallarico, da Silva, Ricardo Alexandre Galdino, Carvalho, Thaisa Mary
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container_end_page S159
container_issue
container_start_page S156
container_title Journal of alloys and compounds
container_volume 615
creator Santos, Camila Maria Andrade dos
Adorno, Antonio Tallarico
da Silva, Ricardo Alexandre Galdino
Carvalho, Thaisa Mary
description •Martensite decomposition in Cu–Al–Mn–Ag alloys is mainly influenced by Mn.•Interaction between Cu–Mn atomic pairs increases activation energy.•Cu diffusion is disturbed by the interaction between Cu–Mn atomic pairs. The influence of Mn and Ag additions on the isothermal kinetics of martensite decomposition in the Cu–9wt.%Al alloy was studied using X-ray diffractometry (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDXS) and microhardness changes measurements with temperature and time. The results indicated that the reaction is disturbed by the increase of Mn, an effect associated with the increase in the Al–Mn and Cu–Mn atomic pairs, which disturbs Cu diffusion and increases the activation energy for the martensite decomposition reaction.
doi_str_mv 10.1016/j.jallcom.2013.11.135
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The influence of Mn and Ag additions on the isothermal kinetics of martensite decomposition in the Cu–9wt.%Al alloy was studied using X-ray diffractometry (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDXS) and microhardness changes measurements with temperature and time. 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source Elsevier ScienceDirect Journals
subjects Alloys
Copper
COPPER ALLOYS (40 TO 99.3 CU)
COPPER ALUMINUM ALLOYS
Copper base alloys
Cross-disciplinary physics: materials science
rheology
Decomposition
DIFFUSION
Exact sciences and technology
Kinetics
Manganese
MARTENSITE
Martensitic transformations
Materials science
Metals and alloys
Phase diagrams and microstructures developed by solidification and solid-solid phase transformations
Physics
Scanning electron microscopy
Solid state reactions
X RAYS
title Martensite decomposition in Cu–Al–Mn–Ag alloys
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