Nitrosation Reaction Without Nitrogen Oxide Waste Gas Emission and Its Engineering Practice

The gas-liquid phase equilibrium is used in controlling the nitrosation reaction process. Decomposition of nitrous acid and oxidation side reaction.are suppressed in a closed reaction system. The system pressure is used as the criterion of the end of reaction, avoiding excessive feeding and reducing...

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Veröffentlicht in:Chinese journal of chemical engineering 2013-04, Vol.21 (4), p.442-446
1. Verfasser: 陈春光 冯亚青 牛伟玮 陈学玺
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Sprache:eng
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Zusammenfassung:The gas-liquid phase equilibrium is used in controlling the nitrosation reaction process. Decomposition of nitrous acid and oxidation side reaction.are suppressed in a closed reaction system. The system pressure is used as the criterion of the end of reaction, avoiding excessive feeding and reducing'the decomposition'of nitrous acid. The head space of the reactor is used as the gas buffer, stabilizing the feeding fluctuations and inhibiting the side reaction, decomposition of nitrous acid. Nitrogen oxide concentration is controlled at the minimum level.Thus the zero release ofnitrogen ox!de waste gas can be achieved without using any absorption process.
ISSN:1004-9541
2210-321X
DOI:10.1016/S1004-9541(13)60490-5