π-Rich σ(2)P-heterocycles: bent η(1)-P- and μ(2)-P-coordinated 1,3-benzazaphosphole copper(I) halide complexes

The reaction of 1-neopentyl-1,3-benzazaphosphole 1 with CuCl, CuBr, or Cu(SMe2)Br in THF at room temperature provides sparingly soluble [Cu7(μ(2)-L6)(μ(2)-X7)](+)[CuX2](-) cluster complexes 2a,b (L indicates coordinated 1, a X = Cl, b X = Br), with loosely bound THF, in high yields. The conversions...

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Veröffentlicht in:	Inorganic chemistry 2015-03, Vol.54 (5), p.2117-2127
Hauptverfasser:	Ghalib, Mohammed, Jones, Peter G, Schulzke, Carola, Sziebert, Dénes, Nyulászi, László, Heinicke, Joachim W
Format:	Artikel
Sprache:	eng
Schlagworte:	Copper - chemistry Heterocyclic Compounds - chemical synthesis Heterocyclic Compounds - chemistry Hydrocarbons, Halogenated - chemical synthesis Hydrocarbons, Halogenated - chemistry Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry
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