Fabrication of Fe3O4/SiO2 core–shell nanoparticle monolayer as catalyst for carbon nanotube growth using Langmuir–Blodgett technique

In this work, an approach of controllable distance of catalytic nanoparticles (NPs) shrouded in shell layer for carbon nanotube (CNT) growth has been developed with the aid of the Langmuir–Blodgett (LB) technique. Coagulation of core–shell NPs was controlled by the surface pressure of the LB techniq...

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Veröffentlicht in:Thin solid films 2013-06, Vol.537, p.252-255
Hauptverfasser: Kushida, Masahito, Koide, Tetsuya, Osada, Ippei, Imaizumi, Yoshiaki, Kawasaki, Kouhei, Sugawara, Takehiro
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container_end_page 255
container_issue
container_start_page 252
container_title Thin solid films
container_volume 537
creator Kushida, Masahito
Koide, Tetsuya
Osada, Ippei
Imaizumi, Yoshiaki
Kawasaki, Kouhei
Sugawara, Takehiro
description In this work, an approach of controllable distance of catalytic nanoparticles (NPs) shrouded in shell layer for carbon nanotube (CNT) growth has been developed with the aid of the Langmuir–Blodgett (LB) technique. Coagulation of core–shell NPs was controlled by the surface pressure of the LB technique. Scanning electron microscope images show that core–shell NP LB film without coagulation and vacancies was observed. The approach of core–shell NP LB film revealed in this work could potentially be applied in catalytic NP monolayer formation and high activity of catalytic NPs for CNT growth. •Fe3O4 nanoparticles (NPs) and Fe3O4/SiO2 core–shell NPs were synthesized.•Fe3O4 NP as catalyst was almost retained at the center of SiO2 shell structure.•Core–shell NP monolayer without coagulation and vacancies was deposited on substrate.•Core–shell NP monolayer was closely packed by using Langmuir–Blodgett technique.
doi_str_mv 10.1016/j.tsf.2013.04.031
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The approach of core–shell NP LB film revealed in this work could potentially be applied in catalytic NP monolayer formation and high activity of catalytic NPs for CNT growth. •Fe3O4 nanoparticles (NPs) and Fe3O4/SiO2 core–shell NPs were synthesized.•Fe3O4 NP as catalyst was almost retained at the center of SiO2 shell structure.•Core–shell NP monolayer without coagulation and vacancies was deposited on substrate.•Core–shell NP monolayer was closely packed by using Langmuir–Blodgett technique.</description><identifier>ISSN: 0040-6090</identifier><identifier>EISSN: 1879-2731</identifier><identifier>DOI: 10.1016/j.tsf.2013.04.031</identifier><identifier>CODEN: THSFAP</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Carbon nanotube growth ; Carbon nanotubes ; Catalysis ; Catalysts ; Catalysts: preparations and properties ; Catalytic nanoparticles ; Chemistry ; Coagulation ; Core–shell ; Cross-disciplinary physics: materials science; rheology ; Exact sciences and technology ; General and physical chemistry ; Langmuir-Blodgett films ; Materials science ; Methods of nanofabrication ; Molecular electronic devices ; Monolayers ; Nanoscale materials and structures: fabrication and characterization ; Nanotubes ; Other topics in nanoscale materials and structures ; Physics ; Scanning electron microscopy ; Shells ; Theory of reactions, general kinetics. 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subjects Carbon nanotube growth
Carbon nanotubes
Catalysis
Catalysts
Catalysts: preparations and properties
Catalytic nanoparticles
Chemistry
Coagulation
Core–shell
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
General and physical chemistry
Langmuir-Blodgett films
Materials science
Methods of nanofabrication
Molecular electronic devices
Monolayers
Nanoscale materials and structures: fabrication and characterization
Nanotubes
Other topics in nanoscale materials and structures
Physics
Scanning electron microscopy
Shells
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
title Fabrication of Fe3O4/SiO2 core–shell nanoparticle monolayer as catalyst for carbon nanotube growth using Langmuir–Blodgett technique
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