A Facile Synthesis of Monodispersed Carbon-encapsulated Copper Nanoparticles with Excellent Oxidation Resistance from a Refluxing-derived Precursor
Carbon-encapsulated copper nanoparticles (CECNPs) are synthesized from a precursor derived easily through a refluxing method. The as-synthesized CECNPs are monodispersed with a uniform size distribution and obvious core–shell structure. The formation process of the CECNPs is investigated, and the po...
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Veröffentlicht in: | Chemistry letters 2013-06, Vol.42 (6), p.627-629 |
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container_title | Chemistry letters |
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creator | Meng, Xiaopeng Wen, Jiqiu Yao, Yadong Ding, Yi Gong, Yichao Zou, Changwu Yin, Guangfu Liao, Xiaoming Huang, Zhongbing Chen, Xianchun |
description | Carbon-encapsulated copper nanoparticles (CECNPs) are synthesized from a precursor derived easily through a refluxing method. The as-synthesized CECNPs are monodispersed with a uniform size distribution and obvious core–shell structure. The formation process of the CECNPs is investigated, and the possible mechanism is proposed. Furthermore, TG-DSC measurements, in conjunction with the corresponding XRD patterns, reveal that the as-synthesized CECNPs show excellent oxidation resistance to temperatures up to 900 °C. |
doi_str_mv | 10.1246/cl.130064 |
format | Article |
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The as-synthesized CECNPs are monodispersed with a uniform size distribution and obvious core–shell structure. The formation process of the CECNPs is investigated, and the possible mechanism is proposed. Furthermore, TG-DSC measurements, in conjunction with the corresponding XRD patterns, reveal that the as-synthesized CECNPs show excellent oxidation resistance to temperatures up to 900 °C.</description><identifier>ISSN: 0366-7022</identifier><identifier>EISSN: 1348-0715</identifier><identifier>DOI: 10.1246/cl.130064</identifier><language>eng</language><publisher>Tokyo: The Chemical Society of Japan</publisher><subject>Copper ; Core-shell structure ; FABRICATION ; FLUXES ; FLUXING ; Formations ; Nanoparticles ; Oxidation resistance ; PARTICLES ; Precursors ; Refluxing ; Size distribution ; Synthesis</subject><ispartof>Chemistry letters, 2013-06, Vol.42 (6), p.627-629</ispartof><rights>The Chemical Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 2013</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-4d33d368ceee805d6af9c994f8a2406718895f7a28922b881fef4acc03d9bb9b3</citedby><cites>FETCH-LOGICAL-c337t-4d33d368ceee805d6af9c994f8a2406718895f7a28922b881fef4acc03d9bb9b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Meng, Xiaopeng</creatorcontrib><creatorcontrib>Wen, Jiqiu</creatorcontrib><creatorcontrib>Yao, Yadong</creatorcontrib><creatorcontrib>Ding, Yi</creatorcontrib><creatorcontrib>Gong, Yichao</creatorcontrib><creatorcontrib>Zou, Changwu</creatorcontrib><creatorcontrib>Yin, Guangfu</creatorcontrib><creatorcontrib>Liao, Xiaoming</creatorcontrib><creatorcontrib>Huang, Zhongbing</creatorcontrib><creatorcontrib>Chen, Xianchun</creatorcontrib><title>A Facile Synthesis of Monodispersed Carbon-encapsulated Copper Nanoparticles with Excellent Oxidation Resistance from a Refluxing-derived Precursor</title><title>Chemistry letters</title><addtitle>Chemistry Letters</addtitle><description>Carbon-encapsulated copper nanoparticles (CECNPs) are synthesized from a precursor derived easily through a refluxing method. The as-synthesized CECNPs are monodispersed with a uniform size distribution and obvious core–shell structure. The formation process of the CECNPs is investigated, and the possible mechanism is proposed. Furthermore, TG-DSC measurements, in conjunction with the corresponding XRD patterns, reveal that the as-synthesized CECNPs show excellent oxidation resistance to temperatures up to 900 °C.</description><subject>Copper</subject><subject>Core-shell structure</subject><subject>FABRICATION</subject><subject>FLUXES</subject><subject>FLUXING</subject><subject>Formations</subject><subject>Nanoparticles</subject><subject>Oxidation resistance</subject><subject>PARTICLES</subject><subject>Precursors</subject><subject>Refluxing</subject><subject>Size distribution</subject><subject>Synthesis</subject><issn>0366-7022</issn><issn>1348-0715</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNplkcFu1DAQhi1EJZaWA29giQscUsax13GO1aoFpEKrAufIccasV1472A7dfQ5emETbA4LTSP9882mkn5DXDC5ZLeR74y8ZB5DiGVkxLlQFDVs_JyvgUlYN1PUL8jLnHQColtcr8vuK3mjjPNKvx1C2mF2m0dLPMcTB5RFTxoFudOpjqDAYPebJ67JkcZy39IsOcdSpOOMx00dXtvT6YNB7DIXeHdygi4uBPiziooNBalPcUz0n1k8HF35UAyb3azbeJzRTyjFdkDOrfcZXT_OcfL-5_rb5WN3effi0ubqtDOdNqcTA-cClMoioYD1IbVvTtsIqXQuQDVOqXdtG16qt614pZtEKbQzwoe37tufn5O3JO6b4c8Jcur3Ly-86YJxyx6QEaEBwPqNv_kF3cUph_q5jolEgW5AL9e5EmRRzTmi7Mbm9TseOQbfU0xnfneqZWfnEbnHvzGyKxmE57vSow1_2_w7_ADcVl8A</recordid><startdate>20130605</startdate><enddate>20130605</enddate><creator>Meng, Xiaopeng</creator><creator>Wen, Jiqiu</creator><creator>Yao, Yadong</creator><creator>Ding, Yi</creator><creator>Gong, Yichao</creator><creator>Zou, Changwu</creator><creator>Yin, Guangfu</creator><creator>Liao, Xiaoming</creator><creator>Huang, Zhongbing</creator><creator>Chen, Xianchun</creator><general>The Chemical Society of Japan</general><general>Chemical Society of Japan</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7U5</scope><scope>H8G</scope><scope>L7M</scope></search><sort><creationdate>20130605</creationdate><title>A Facile Synthesis of Monodispersed Carbon-encapsulated Copper Nanoparticles with Excellent Oxidation Resistance from a Refluxing-derived Precursor</title><author>Meng, Xiaopeng ; Wen, Jiqiu ; Yao, Yadong ; Ding, Yi ; Gong, Yichao ; Zou, Changwu ; Yin, Guangfu ; Liao, Xiaoming ; Huang, Zhongbing ; Chen, Xianchun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-4d33d368ceee805d6af9c994f8a2406718895f7a28922b881fef4acc03d9bb9b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Copper</topic><topic>Core-shell structure</topic><topic>FABRICATION</topic><topic>FLUXES</topic><topic>FLUXING</topic><topic>Formations</topic><topic>Nanoparticles</topic><topic>Oxidation resistance</topic><topic>PARTICLES</topic><topic>Precursors</topic><topic>Refluxing</topic><topic>Size distribution</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Meng, Xiaopeng</creatorcontrib><creatorcontrib>Wen, Jiqiu</creatorcontrib><creatorcontrib>Yao, Yadong</creatorcontrib><creatorcontrib>Ding, Yi</creatorcontrib><creatorcontrib>Gong, Yichao</creatorcontrib><creatorcontrib>Zou, Changwu</creatorcontrib><creatorcontrib>Yin, Guangfu</creatorcontrib><creatorcontrib>Liao, Xiaoming</creatorcontrib><creatorcontrib>Huang, Zhongbing</creatorcontrib><creatorcontrib>Chen, Xianchun</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Copper Technical Reference Library</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Meng, Xiaopeng</au><au>Wen, Jiqiu</au><au>Yao, Yadong</au><au>Ding, Yi</au><au>Gong, Yichao</au><au>Zou, Changwu</au><au>Yin, Guangfu</au><au>Liao, Xiaoming</au><au>Huang, Zhongbing</au><au>Chen, Xianchun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Facile Synthesis of Monodispersed Carbon-encapsulated Copper Nanoparticles with Excellent Oxidation Resistance from a Refluxing-derived Precursor</atitle><jtitle>Chemistry letters</jtitle><addtitle>Chemistry Letters</addtitle><date>2013-06-05</date><risdate>2013</risdate><volume>42</volume><issue>6</issue><spage>627</spage><epage>629</epage><pages>627-629</pages><issn>0366-7022</issn><eissn>1348-0715</eissn><abstract>Carbon-encapsulated copper nanoparticles (CECNPs) are synthesized from a precursor derived easily through a refluxing method. The as-synthesized CECNPs are monodispersed with a uniform size distribution and obvious core–shell structure. The formation process of the CECNPs is investigated, and the possible mechanism is proposed. Furthermore, TG-DSC measurements, in conjunction with the corresponding XRD patterns, reveal that the as-synthesized CECNPs show excellent oxidation resistance to temperatures up to 900 °C.</abstract><cop>Tokyo</cop><pub>The Chemical Society of Japan</pub><doi>10.1246/cl.130064</doi><tpages>3</tpages></addata></record> |
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source | Oxford University Press Journals All Titles (1996-Current) |
subjects | Copper Core-shell structure FABRICATION FLUXES FLUXING Formations Nanoparticles Oxidation resistance PARTICLES Precursors Refluxing Size distribution Synthesis |
title | A Facile Synthesis of Monodispersed Carbon-encapsulated Copper Nanoparticles with Excellent Oxidation Resistance from a Refluxing-derived Precursor |
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