Urea–nitrate combustion synthesis of ZrO2 and CeO2 doped CuO/Al2O3 nanocatalyst used in steam reforming of biomethanol for hydrogen production

The CuO/ZrO2/Al2O3 and CuO/CeO2/Al2O3 nanocatalysts for production of hydrogen via methanol steam reforming were prepared by the solution combustion method using urea as fuel. The effect of ceria and zirconia on physicochemical properties of nanocatalysts was investigated by XRD, FESEM, EDX, BET and...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Ceramics international 2014, Vol.40 (9), p.14177-14184
Hauptverfasser: Baneshi, Javad, Haghighi, Mohammad, Jodeiri, Naeimeh, Abdollahifar, Mozaffar, Ajamein, Hossein
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 14184
container_issue 9
container_start_page 14177
container_title Ceramics international
container_volume 40
creator Baneshi, Javad
Haghighi, Mohammad
Jodeiri, Naeimeh
Abdollahifar, Mozaffar
Ajamein, Hossein
description The CuO/ZrO2/Al2O3 and CuO/CeO2/Al2O3 nanocatalysts for production of hydrogen via methanol steam reforming were prepared by the solution combustion method using urea as fuel. The effect of ceria and zirconia on physicochemical properties of nanocatalysts was investigated by XRD, FESEM, EDX, BET and FTIR techniques. XRD analysis showed that addition of zirconia to nanocatalysts made copper crystallites smaller. EDX results demonstrated high dispersion and uniform morphology of particles. The FESEM results proved that the powder prepared through the urea–nitrate combustion method had nanometric particles. Catalytic performance tests indicated the good practicability and high stability of synthesized catalysts via the solution combustion method for the steam reforming of methanol. Consequently, it was found out that the ceria containing catalyst was the best among other samples. The stability test represented that the CuO/CeO2/Al2O3 catalyst was quite stable for the methanol steam reforming.
doi_str_mv 10.1016/j.ceramint.2014.06.005
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1660069807</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0272884214008773</els_id><sourcerecordid>1660069807</sourcerecordid><originalsourceid>FETCH-LOGICAL-c452t-aedf6e061577ad49fb1691063f99590f6e475f873b8ac036714816ee2148ba513</originalsourceid><addsrcrecordid>eNqFUbtu3DAQJIIYyMXOLwQs00he6kFJXYxDYhswcI3dpCEoauXjQSLPJGXgunxCAP-hv8R7OKd2tQvuzOwOh7HvAnIBQl7ucoNBz9alvABR5SBzgPoTW4m2KbOyq-VntoKiKbK2rYov7GuMOyBiV8GK_XsIqF__vjibgk7IjZ_7JSbrHY8Hl7YYbeR-5H_CpuDaDXyN1Ax-j9Qum8urqdiU3GnnjU56OsTEl0gzS_yEeuYBRx_ouMejSm_9jGlL6InTM98ehuAf0fF98MNijmsv2Nmop4jf3us5e_j96359k91trm_XV3eZqeoiZRqHUSJIUTeNHqpu7MmQAFmOXVd3QLOqqUf6gL7VBkrZiKoVErGg2utalOfsx0mXVj8tGJOabTQ4TdqhX6ISUgLIroWGoPIENcHHSIbUPthZh4MSoI4RqJ36H4E6RqBAKoqAiD9PRCQjzxaDisaiMzjYgCapwduPJN4Aq26VrQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1660069807</pqid></control><display><type>article</type><title>Urea–nitrate combustion synthesis of ZrO2 and CeO2 doped CuO/Al2O3 nanocatalyst used in steam reforming of biomethanol for hydrogen production</title><source>Elsevier ScienceDirect Journals Complete</source><creator>Baneshi, Javad ; Haghighi, Mohammad ; Jodeiri, Naeimeh ; Abdollahifar, Mozaffar ; Ajamein, Hossein</creator><creatorcontrib>Baneshi, Javad ; Haghighi, Mohammad ; Jodeiri, Naeimeh ; Abdollahifar, Mozaffar ; Ajamein, Hossein</creatorcontrib><description>The CuO/ZrO2/Al2O3 and CuO/CeO2/Al2O3 nanocatalysts for production of hydrogen via methanol steam reforming were prepared by the solution combustion method using urea as fuel. The effect of ceria and zirconia on physicochemical properties of nanocatalysts was investigated by XRD, FESEM, EDX, BET and FTIR techniques. XRD analysis showed that addition of zirconia to nanocatalysts made copper crystallites smaller. EDX results demonstrated high dispersion and uniform morphology of particles. The FESEM results proved that the powder prepared through the urea–nitrate combustion method had nanometric particles. Catalytic performance tests indicated the good practicability and high stability of synthesized catalysts via the solution combustion method for the steam reforming of methanol. Consequently, it was found out that the ceria containing catalyst was the best among other samples. The stability test represented that the CuO/CeO2/Al2O3 catalyst was quite stable for the methanol steam reforming.</description><identifier>ISSN: 0272-8842</identifier><identifier>EISSN: 1873-3956</identifier><identifier>DOI: 10.1016/j.ceramint.2014.06.005</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Aluminum oxide ; Biomethanol ; Catalysis ; Catalysts ; Combustion ; Combustion synthesis ; CuO/CeO2/Al2O3 ; CuO/ZrO2/Al2O3 ; Hydrogen ; Methyl alcohol ; Nanostructure ; Reforming ; Urea–nitrate combustion ; Zirconium dioxide</subject><ispartof>Ceramics international, 2014, Vol.40 (9), p.14177-14184</ispartof><rights>2014 Elsevier Ltd and Techna Group S.r.l.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c452t-aedf6e061577ad49fb1691063f99590f6e475f873b8ac036714816ee2148ba513</citedby><cites>FETCH-LOGICAL-c452t-aedf6e061577ad49fb1691063f99590f6e475f873b8ac036714816ee2148ba513</cites><orcidid>0000-0001-6683-097X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.ceramint.2014.06.005$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,4024,27923,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Baneshi, Javad</creatorcontrib><creatorcontrib>Haghighi, Mohammad</creatorcontrib><creatorcontrib>Jodeiri, Naeimeh</creatorcontrib><creatorcontrib>Abdollahifar, Mozaffar</creatorcontrib><creatorcontrib>Ajamein, Hossein</creatorcontrib><title>Urea–nitrate combustion synthesis of ZrO2 and CeO2 doped CuO/Al2O3 nanocatalyst used in steam reforming of biomethanol for hydrogen production</title><title>Ceramics international</title><description>The CuO/ZrO2/Al2O3 and CuO/CeO2/Al2O3 nanocatalysts for production of hydrogen via methanol steam reforming were prepared by the solution combustion method using urea as fuel. The effect of ceria and zirconia on physicochemical properties of nanocatalysts was investigated by XRD, FESEM, EDX, BET and FTIR techniques. XRD analysis showed that addition of zirconia to nanocatalysts made copper crystallites smaller. EDX results demonstrated high dispersion and uniform morphology of particles. The FESEM results proved that the powder prepared through the urea–nitrate combustion method had nanometric particles. Catalytic performance tests indicated the good practicability and high stability of synthesized catalysts via the solution combustion method for the steam reforming of methanol. Consequently, it was found out that the ceria containing catalyst was the best among other samples. The stability test represented that the CuO/CeO2/Al2O3 catalyst was quite stable for the methanol steam reforming.</description><subject>Aluminum oxide</subject><subject>Biomethanol</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Combustion</subject><subject>Combustion synthesis</subject><subject>CuO/CeO2/Al2O3</subject><subject>CuO/ZrO2/Al2O3</subject><subject>Hydrogen</subject><subject>Methyl alcohol</subject><subject>Nanostructure</subject><subject>Reforming</subject><subject>Urea–nitrate combustion</subject><subject>Zirconium dioxide</subject><issn>0272-8842</issn><issn>1873-3956</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqFUbtu3DAQJIIYyMXOLwQs00he6kFJXYxDYhswcI3dpCEoauXjQSLPJGXgunxCAP-hv8R7OKd2tQvuzOwOh7HvAnIBQl7ucoNBz9alvABR5SBzgPoTW4m2KbOyq-VntoKiKbK2rYov7GuMOyBiV8GK_XsIqF__vjibgk7IjZ_7JSbrHY8Hl7YYbeR-5H_CpuDaDXyN1Ax-j9Qum8urqdiU3GnnjU56OsTEl0gzS_yEeuYBRx_ouMejSm_9jGlL6InTM98ehuAf0fF98MNijmsv2Nmop4jf3us5e_j96359k91trm_XV3eZqeoiZRqHUSJIUTeNHqpu7MmQAFmOXVd3QLOqqUf6gL7VBkrZiKoVErGg2utalOfsx0mXVj8tGJOabTQ4TdqhX6ISUgLIroWGoPIENcHHSIbUPthZh4MSoI4RqJ36H4E6RqBAKoqAiD9PRCQjzxaDisaiMzjYgCapwduPJN4Aq26VrQ</recordid><startdate>2014</startdate><enddate>2014</enddate><creator>Baneshi, Javad</creator><creator>Haghighi, Mohammad</creator><creator>Jodeiri, Naeimeh</creator><creator>Abdollahifar, Mozaffar</creator><creator>Ajamein, Hossein</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QQ</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-6683-097X</orcidid></search><sort><creationdate>2014</creationdate><title>Urea–nitrate combustion synthesis of ZrO2 and CeO2 doped CuO/Al2O3 nanocatalyst used in steam reforming of biomethanol for hydrogen production</title><author>Baneshi, Javad ; Haghighi, Mohammad ; Jodeiri, Naeimeh ; Abdollahifar, Mozaffar ; Ajamein, Hossein</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c452t-aedf6e061577ad49fb1691063f99590f6e475f873b8ac036714816ee2148ba513</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Aluminum oxide</topic><topic>Biomethanol</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Combustion</topic><topic>Combustion synthesis</topic><topic>CuO/CeO2/Al2O3</topic><topic>CuO/ZrO2/Al2O3</topic><topic>Hydrogen</topic><topic>Methyl alcohol</topic><topic>Nanostructure</topic><topic>Reforming</topic><topic>Urea–nitrate combustion</topic><topic>Zirconium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Baneshi, Javad</creatorcontrib><creatorcontrib>Haghighi, Mohammad</creatorcontrib><creatorcontrib>Jodeiri, Naeimeh</creatorcontrib><creatorcontrib>Abdollahifar, Mozaffar</creatorcontrib><creatorcontrib>Ajamein, Hossein</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Ceramics international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Baneshi, Javad</au><au>Haghighi, Mohammad</au><au>Jodeiri, Naeimeh</au><au>Abdollahifar, Mozaffar</au><au>Ajamein, Hossein</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Urea–nitrate combustion synthesis of ZrO2 and CeO2 doped CuO/Al2O3 nanocatalyst used in steam reforming of biomethanol for hydrogen production</atitle><jtitle>Ceramics international</jtitle><date>2014</date><risdate>2014</risdate><volume>40</volume><issue>9</issue><spage>14177</spage><epage>14184</epage><pages>14177-14184</pages><issn>0272-8842</issn><eissn>1873-3956</eissn><abstract>The CuO/ZrO2/Al2O3 and CuO/CeO2/Al2O3 nanocatalysts for production of hydrogen via methanol steam reforming were prepared by the solution combustion method using urea as fuel. The effect of ceria and zirconia on physicochemical properties of nanocatalysts was investigated by XRD, FESEM, EDX, BET and FTIR techniques. XRD analysis showed that addition of zirconia to nanocatalysts made copper crystallites smaller. EDX results demonstrated high dispersion and uniform morphology of particles. The FESEM results proved that the powder prepared through the urea–nitrate combustion method had nanometric particles. Catalytic performance tests indicated the good practicability and high stability of synthesized catalysts via the solution combustion method for the steam reforming of methanol. Consequently, it was found out that the ceria containing catalyst was the best among other samples. The stability test represented that the CuO/CeO2/Al2O3 catalyst was quite stable for the methanol steam reforming.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.ceramint.2014.06.005</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0001-6683-097X</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0272-8842
ispartof Ceramics international, 2014, Vol.40 (9), p.14177-14184
issn 0272-8842
1873-3956
language eng
recordid cdi_proquest_miscellaneous_1660069807
source Elsevier ScienceDirect Journals Complete
subjects Aluminum oxide
Biomethanol
Catalysis
Catalysts
Combustion
Combustion synthesis
CuO/CeO2/Al2O3
CuO/ZrO2/Al2O3
Hydrogen
Methyl alcohol
Nanostructure
Reforming
Urea–nitrate combustion
Zirconium dioxide
title Urea–nitrate combustion synthesis of ZrO2 and CeO2 doped CuO/Al2O3 nanocatalyst used in steam reforming of biomethanol for hydrogen production
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T02%3A02%3A58IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Urea%E2%80%93nitrate%20combustion%20synthesis%20of%20ZrO2%20and%20CeO2%20doped%20CuO/Al2O3%20nanocatalyst%20used%20in%20steam%20reforming%20of%20biomethanol%20for%20hydrogen%20production&rft.jtitle=Ceramics%20international&rft.au=Baneshi,%20Javad&rft.date=2014&rft.volume=40&rft.issue=9&rft.spage=14177&rft.epage=14184&rft.pages=14177-14184&rft.issn=0272-8842&rft.eissn=1873-3956&rft_id=info:doi/10.1016/j.ceramint.2014.06.005&rft_dat=%3Cproquest_cross%3E1660069807%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1660069807&rft_id=info:pmid/&rft_els_id=S0272884214008773&rfr_iscdi=true