Hydroxyl radical-induced degradation of fenuron in pulse and gamma radiolysis: kinetics and product analysis
Radiolytic reactions of phenylureas were studied in detail with fenuron model compound in dilute aqueous solutions using pulse radiolysis for detection of the intermediates, gamma radiolysis with UV–Vis and HPLC-MS techniques for analysis of the final products. The kinetics of oxidation was followed...
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| Veröffentlicht in: | Environmental science and pollution research international 2014-11, Vol.21 (22), p.12693-12700 |
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| creator | Kovács, Krisztina Mile, Viktoria Csay, Tamás Takács, Erzsébet Wojnárovits, László |
| description | Radiolytic reactions of phenylureas were studied in detail with fenuron model compound in dilute aqueous solutions using pulse radiolysis for detection of the intermediates, gamma radiolysis with UV–Vis and HPLC-MS techniques for analysis of the final products. The kinetics of oxidation was followed by COD, TOC and toxicity measurements. During radiolysis of aerated solutions hydroxyl radical (
•
OH), e
aq
−
, H
•
and O
2
•−
/HO
2
•
reactive intermediates are produced, the degradation of solute takes place practically entirely through
•
OH reactions. Therefore, the product distribution is similar to the distributions reported in other advanced oxidation processes with
•
OH as main reactant.
•
OH mainly reacts with the aromatic ring, forming cyclohexadienyl radical as an intermediate. This radical in pulse radiolysis has a wide absorption band in the 310–390 nm wavelength range with a maximum at 350 nm. Cyclohexadienyl radical reacts with dissolved O
2
with a rate coefficient of ∼4 × 10
8
mol
−1
dm
3
s
−1
forming peroxy radical. The latter may eliminate HO
2
•
giving phenols or undergoes fragmentation. The one-electron oxidant
•
OH on average induces more than two-electron oxidations. The toxicity first increases with absorbed dose, then decreases. This increase is partly due to phenols formed during the first degradation period. |
| doi_str_mv | 10.1007/s11356-014-3197-9 |
| format | Article |
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•
OH), e
aq
−
, H
•
and O
2
•−
/HO
2
•
reactive intermediates are produced, the degradation of solute takes place practically entirely through
•
OH reactions. Therefore, the product distribution is similar to the distributions reported in other advanced oxidation processes with
•
OH as main reactant.
•
OH mainly reacts with the aromatic ring, forming cyclohexadienyl radical as an intermediate. This radical in pulse radiolysis has a wide absorption band in the 310–390 nm wavelength range with a maximum at 350 nm. Cyclohexadienyl radical reacts with dissolved O
2
with a rate coefficient of ∼4 × 10
8
mol
−1
dm
3
s
−1
forming peroxy radical. The latter may eliminate HO
2
•
giving phenols or undergoes fragmentation. The one-electron oxidant
•
OH on average induces more than two-electron oxidations. The toxicity first increases with absorbed dose, then decreases. This increase is partly due to phenols formed during the first degradation period.</description><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-014-3197-9</identifier><identifier>PMID: 24965004</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aquatic Pollution ; Atmospheric Protection/Air Quality Control/Air Pollution ; Chemical oxygen demand ; Degradation ; Dissolved oxygen ; Earth and Environmental Science ; Ecotoxicology ; Environment ; Environmental Chemistry ; Environmental Health ; Experiments ; Forming ; Gamma Rays ; Herbicides - chemistry ; Hydroxyl Radical - chemistry ; Hydroxyl radicals ; Intermediates ; Investigations ; Kinetics ; Laboratories ; Liquid chromatography ; Mass Spectrometry ; Oxidants ; Oxidation ; Oxidation-Reduction ; Oxidizing agents ; Phenols ; Phenols - chemistry ; Phenylurea Compounds - chemistry ; Pulse Radiolysis ; Radiation ; Radicals ; Radiolysis ; Reaction kinetics ; Research Article ; Toxicity ; Waste Water Technology ; Water Management ; Water Pollutants, Chemical - chemistry ; Water Pollution Control ; Water Purification - methods</subject><ispartof>Environmental science and pollution research international, 2014-11, Vol.21 (22), p.12693-12700</ispartof><rights>Springer-Verlag Berlin Heidelberg 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c545t-4ec25041b8d6d48120555930a47a3d1d59ae40bc6f9d760eac063d6813709d833</citedby><cites>FETCH-LOGICAL-c545t-4ec25041b8d6d48120555930a47a3d1d59ae40bc6f9d760eac063d6813709d833</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11356-014-3197-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11356-014-3197-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24965004$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kovács, Krisztina</creatorcontrib><creatorcontrib>Mile, Viktoria</creatorcontrib><creatorcontrib>Csay, Tamás</creatorcontrib><creatorcontrib>Takács, Erzsébet</creatorcontrib><creatorcontrib>Wojnárovits, László</creatorcontrib><title>Hydroxyl radical-induced degradation of fenuron in pulse and gamma radiolysis: kinetics and product analysis</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><addtitle>Environ Sci Pollut Res Int</addtitle><description>Radiolytic reactions of phenylureas were studied in detail with fenuron model compound in dilute aqueous solutions using pulse radiolysis for detection of the intermediates, gamma radiolysis with UV–Vis and HPLC-MS techniques for analysis of the final products. The kinetics of oxidation was followed by COD, TOC and toxicity measurements. During radiolysis of aerated solutions hydroxyl radical (
•
OH), e
aq
−
, H
•
and O
2
•−
/HO
2
•
reactive intermediates are produced, the degradation of solute takes place practically entirely through
•
OH reactions. Therefore, the product distribution is similar to the distributions reported in other advanced oxidation processes with
•
OH as main reactant.
•
OH mainly reacts with the aromatic ring, forming cyclohexadienyl radical as an intermediate. This radical in pulse radiolysis has a wide absorption band in the 310–390 nm wavelength range with a maximum at 350 nm. Cyclohexadienyl radical reacts with dissolved O
2
with a rate coefficient of ∼4 × 10
8
mol
−1
dm
3
s
−1
forming peroxy radical. The latter may eliminate HO
2
•
giving phenols or undergoes fragmentation. The one-electron oxidant
•
OH on average induces more than two-electron oxidations. The toxicity first increases with absorbed dose, then decreases. This increase is partly due to phenols formed during the first degradation period.</description><subject>Aquatic Pollution</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Chemical oxygen demand</subject><subject>Degradation</subject><subject>Dissolved oxygen</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Experiments</subject><subject>Forming</subject><subject>Gamma Rays</subject><subject>Herbicides - chemistry</subject><subject>Hydroxyl Radical - chemistry</subject><subject>Hydroxyl radicals</subject><subject>Intermediates</subject><subject>Investigations</subject><subject>Kinetics</subject><subject>Laboratories</subject><subject>Liquid chromatography</subject><subject>Mass Spectrometry</subject><subject>Oxidants</subject><subject>Oxidation</subject><subject>Oxidation-Reduction</subject><subject>Oxidizing agents</subject><subject>Phenols</subject><subject>Phenols - chemistry</subject><subject>Phenylurea Compounds - chemistry</subject><subject>Pulse Radiolysis</subject><subject>Radiation</subject><subject>Radicals</subject><subject>Radiolysis</subject><subject>Reaction kinetics</subject><subject>Research Article</subject><subject>Toxicity</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollutants, Chemical - chemistry</subject><subject>Water Pollution Control</subject><subject>Water Purification - 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radical-induced degradation of fenuron in pulse and gamma radiolysis: kinetics and product analysis</title><author>Kovács, Krisztina ; Mile, Viktoria ; Csay, Tamás ; Takács, Erzsébet ; Wojnárovits, László</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c545t-4ec25041b8d6d48120555930a47a3d1d59ae40bc6f9d760eac063d6813709d833</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Aquatic Pollution</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Chemical oxygen demand</topic><topic>Degradation</topic><topic>Dissolved oxygen</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Experiments</topic><topic>Forming</topic><topic>Gamma Rays</topic><topic>Herbicides - chemistry</topic><topic>Hydroxyl Radical - 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Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kovács, Krisztina</au><au>Mile, Viktoria</au><au>Csay, Tamás</au><au>Takács, Erzsébet</au><au>Wojnárovits, László</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydroxyl radical-induced degradation of fenuron in pulse and gamma radiolysis: kinetics and product analysis</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><addtitle>Environ Sci Pollut Res Int</addtitle><date>2014-11-01</date><risdate>2014</risdate><volume>21</volume><issue>22</issue><spage>12693</spage><epage>12700</epage><pages>12693-12700</pages><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>Radiolytic reactions of phenylureas were studied in detail with fenuron model compound in dilute aqueous solutions using pulse radiolysis for detection of the intermediates, gamma radiolysis with UV–Vis and HPLC-MS techniques for analysis of the final products. The kinetics of oxidation was followed by COD, TOC and toxicity measurements. During radiolysis of aerated solutions hydroxyl radical (
•
OH), e
aq
−
, H
•
and O
2
•−
/HO
2
•
reactive intermediates are produced, the degradation of solute takes place practically entirely through
•
OH reactions. Therefore, the product distribution is similar to the distributions reported in other advanced oxidation processes with
•
OH as main reactant.
•
OH mainly reacts with the aromatic ring, forming cyclohexadienyl radical as an intermediate. This radical in pulse radiolysis has a wide absorption band in the 310–390 nm wavelength range with a maximum at 350 nm. Cyclohexadienyl radical reacts with dissolved O
2
with a rate coefficient of ∼4 × 10
8
mol
−1
dm
3
s
−1
forming peroxy radical. The latter may eliminate HO
2
•
giving phenols or undergoes fragmentation. The one-electron oxidant
•
OH on average induces more than two-electron oxidations. The toxicity first increases with absorbed dose, then decreases. This increase is partly due to phenols formed during the first degradation period.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>24965004</pmid><doi>10.1007/s11356-014-3197-9</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0944-1344 |
| ispartof | Environmental science and pollution research international, 2014-11, Vol.21 (22), p.12693-12700 |
| issn | 0944-1344 1614-7499 |
| language | eng |
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| source | MEDLINE; SpringerLink Journals - AutoHoldings |
| subjects | Aquatic Pollution Atmospheric Protection/Air Quality Control/Air Pollution Chemical oxygen demand Degradation Dissolved oxygen Earth and Environmental Science Ecotoxicology Environment Environmental Chemistry Environmental Health Experiments Forming Gamma Rays Herbicides - chemistry Hydroxyl Radical - chemistry Hydroxyl radicals Intermediates Investigations Kinetics Laboratories Liquid chromatography Mass Spectrometry Oxidants Oxidation Oxidation-Reduction Oxidizing agents Phenols Phenols - chemistry Phenylurea Compounds - chemistry Pulse Radiolysis Radiation Radicals Radiolysis Reaction kinetics Research Article Toxicity Waste Water Technology Water Management Water Pollutants, Chemical - chemistry Water Pollution Control Water Purification - methods |
| title | Hydroxyl radical-induced degradation of fenuron in pulse and gamma radiolysis: kinetics and product analysis |
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