Poly(isobutylene) Nanoparticles via Cationic Polymerization in Nonaqueous Emulsions

The preparation of poly(isobutylene) (PIB) nanoparticles via cationic emulsion polymerization is presented. As a requirement, an oil‐in‐perfluoroalkane nonaqueous emulsion is developed, which is inert under the carbocationic polymerization conditions. To stabilize the dichloromethane/hexane droplets...

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Veröffentlicht in:	Macromolecular rapid communications. 2015-01, Vol.36 (2), p.204-210
Hauptverfasser:	Schuster, Thomas, Golling, Florian E., Krumpfer, Joseph W., Wagner, Manfred, Graf, Robert, Alsaygh, Abdulhamid A., Klapper, Markus, Müllen, Klaus
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemistry Block copolymers cationic polymerization Cations - chemistry Droplets Dynamical systems Dynamics Emulsifiers Emulsifying Agents - chemistry Emulsion polymerization Emulsions - chemistry Fluorination Fluorocarbon Polymers - chemistry fluoropolymers Hexanes - chemistry Methylene Chloride - chemistry Microscopy, Electron, Scanning Molecular Weight Nanoparticles Nanoparticles - chemistry Nanoparticles - ultrastructure Polymerization Polymers - chemical synthesis Polymers - chemistry Polystyrenes - chemistry rubber
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