Experimental evidence of light soaking effect in Cd-free Cu2ZnSn(S,Se)4-based solar cells
The use of a Zn-based buffer layer for kesterite solar cells presents the double advantage of avoiding cadmium and reducing the amount of light absorbed in this layer. Cu2ZnSn(S,Se)4 solar cells with a ZnS(O,OH) buffer layer have been fabricated and power conversion efficiencies up to 5.8% after lig...
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Veröffentlicht in: | Thin solid films 2014-08, Vol.564, p.375-378 |
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creator | Grenet, Louis Grondin, Pauline Coumert, Karol Karst, Nicolas Emieux, Fabrice Roux, Frédéric Fillon, Raphaël Altamura, Giovanni Fournier, Hélène Faucherand, Pascal Perraud, Simon |
description | The use of a Zn-based buffer layer for kesterite solar cells presents the double advantage of avoiding cadmium and reducing the amount of light absorbed in this layer. Cu2ZnSn(S,Se)4 solar cells with a ZnS(O,OH) buffer layer have been fabricated and power conversion efficiencies up to 5.8% after light soaking treatment have been measured. Cu2ZnSn(Se,S)4 solar cells with a CdS buffer layer have also been realized, leading to a power conversion efficiency up to 7.0%. The dynamics of the light soaking effect in the case of the ZnS(O,OH) buffer layer has been studied as well, and compared to the same effect on a cell with a Cu(In,Ga)Se2 absorber layer.
•5.8% of efficiency for a Cu2ZnSn(S,Se)4 solar cell with a ZnS(O,OH) buffer layer•7.0% of efficiency for a reference Cu2ZnSn(S,Se)4 solar cell with a CdS buffer layer•ZnS(O,OH) buffer layer required at least 1000min of light soaking treatment.•Required light soaking treatment is longer for Cu2ZnSn(S,Se)4 than for Cu(In,Ga)Se2. |
doi_str_mv | 10.1016/j.tsf.2014.05.033 |
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•5.8% of efficiency for a Cu2ZnSn(S,Se)4 solar cell with a ZnS(O,OH) buffer layer•7.0% of efficiency for a reference Cu2ZnSn(S,Se)4 solar cell with a CdS buffer layer•ZnS(O,OH) buffer layer required at least 1000min of light soaking treatment.•Required light soaking treatment is longer for Cu2ZnSn(S,Se)4 than for Cu(In,Ga)Se2.</description><identifier>ISSN: 0040-6090</identifier><identifier>EISSN: 1879-2731</identifier><identifier>DOI: 10.1016/j.tsf.2014.05.033</identifier><identifier>CODEN: THSFAP</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Buffer layer ; Buffer layers ; Cadmium ; Copper zinc tin sulfur selenide ; Cross-disciplinary physics: materials science; rheology ; Dynamic tests ; Energy ; Energy conversion efficiency ; Exact sciences and technology ; Kesterite ; Light soaking ; Materials science ; Metastability ; Natural energy ; Other semiconductors ; Photovoltaic cells ; Photovoltaic conversion ; Physics ; Soaking ; Solar cells ; Solar cells. Photoelectrochemical cells ; Solar energy ; Specific materials ; Thin films ; Zinc sulfide ; ZnS(O,OH)</subject><ispartof>Thin solid films, 2014-08, Vol.564, p.375-378</ispartof><rights>2014 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c275t-f0a2d540dd7361c512ccb1e332060e65753041d5ba564d0351a4ba78c2a19e183</citedby><cites>FETCH-LOGICAL-c275t-f0a2d540dd7361c512ccb1e332060e65753041d5ba564d0351a4ba78c2a19e183</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.tsf.2014.05.033$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28601551$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Grenet, Louis</creatorcontrib><creatorcontrib>Grondin, Pauline</creatorcontrib><creatorcontrib>Coumert, Karol</creatorcontrib><creatorcontrib>Karst, Nicolas</creatorcontrib><creatorcontrib>Emieux, Fabrice</creatorcontrib><creatorcontrib>Roux, Frédéric</creatorcontrib><creatorcontrib>Fillon, Raphaël</creatorcontrib><creatorcontrib>Altamura, Giovanni</creatorcontrib><creatorcontrib>Fournier, Hélène</creatorcontrib><creatorcontrib>Faucherand, Pascal</creatorcontrib><creatorcontrib>Perraud, Simon</creatorcontrib><title>Experimental evidence of light soaking effect in Cd-free Cu2ZnSn(S,Se)4-based solar cells</title><title>Thin solid films</title><description>The use of a Zn-based buffer layer for kesterite solar cells presents the double advantage of avoiding cadmium and reducing the amount of light absorbed in this layer. Cu2ZnSn(S,Se)4 solar cells with a ZnS(O,OH) buffer layer have been fabricated and power conversion efficiencies up to 5.8% after light soaking treatment have been measured. Cu2ZnSn(Se,S)4 solar cells with a CdS buffer layer have also been realized, leading to a power conversion efficiency up to 7.0%. The dynamics of the light soaking effect in the case of the ZnS(O,OH) buffer layer has been studied as well, and compared to the same effect on a cell with a Cu(In,Ga)Se2 absorber layer.
•5.8% of efficiency for a Cu2ZnSn(S,Se)4 solar cell with a ZnS(O,OH) buffer layer•7.0% of efficiency for a reference Cu2ZnSn(S,Se)4 solar cell with a CdS buffer layer•ZnS(O,OH) buffer layer required at least 1000min of light soaking treatment.•Required light soaking treatment is longer for Cu2ZnSn(S,Se)4 than for Cu(In,Ga)Se2.</description><subject>Applied sciences</subject><subject>Buffer layer</subject><subject>Buffer layers</subject><subject>Cadmium</subject><subject>Copper zinc tin sulfur selenide</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Dynamic tests</subject><subject>Energy</subject><subject>Energy conversion efficiency</subject><subject>Exact sciences and technology</subject><subject>Kesterite</subject><subject>Light soaking</subject><subject>Materials science</subject><subject>Metastability</subject><subject>Natural energy</subject><subject>Other semiconductors</subject><subject>Photovoltaic cells</subject><subject>Photovoltaic conversion</subject><subject>Physics</subject><subject>Soaking</subject><subject>Solar cells</subject><subject>Solar cells. Photoelectrochemical cells</subject><subject>Solar energy</subject><subject>Specific materials</subject><subject>Thin films</subject><subject>Zinc sulfide</subject><subject>ZnS(O,OH)</subject><issn>0040-6090</issn><issn>1879-2731</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp9kMFOGzEQhq2qSKS0D8DNF6RUYrcz9tqbqKcqCi0SEofAob1Yjj1OHZbd1N4g-vY4CuLIaS7f_8_Mx9g5Qo2A-tu2HnOoBWBTg6pByg9sgrN2XolW4kc2AWig0jCHU_Yp5y0AoBBywn4vn3eU4iP1o-04PUVPvSM-BN7Fzd-R58E-xH7DKQRyI489X_gqJCK-2Is__aqfri5X9LWp1jaTL3hnE3fUdfkzOwm2y_TldZ6x-6vl3eJXdXP783rx46ZyolVjFcAKrxrwvpUanULh3BpJSgEaSKtWSWjQq7VVuvEgFdpmbduZExbnhDN5xqbH3l0a_u0pj-Yx5sMFtqdhnw1qDaBKX1NQPKIuDTknCmZXXrfpv0EwB41ma4pGc9BoQJmisWQuXuttdrYLyfYu5regmGlApbBw348clV-fIiWTXTy49DEVc8YP8Z0tLxvghYU</recordid><startdate>20140801</startdate><enddate>20140801</enddate><creator>Grenet, Louis</creator><creator>Grondin, Pauline</creator><creator>Coumert, Karol</creator><creator>Karst, Nicolas</creator><creator>Emieux, Fabrice</creator><creator>Roux, Frédéric</creator><creator>Fillon, Raphaël</creator><creator>Altamura, Giovanni</creator><creator>Fournier, Hélène</creator><creator>Faucherand, Pascal</creator><creator>Perraud, Simon</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20140801</creationdate><title>Experimental evidence of light soaking effect in Cd-free Cu2ZnSn(S,Se)4-based solar cells</title><author>Grenet, Louis ; Grondin, Pauline ; Coumert, Karol ; Karst, Nicolas ; Emieux, Fabrice ; Roux, Frédéric ; Fillon, Raphaël ; Altamura, Giovanni ; Fournier, Hélène ; Faucherand, Pascal ; Perraud, Simon</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c275t-f0a2d540dd7361c512ccb1e332060e65753041d5ba564d0351a4ba78c2a19e183</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Applied sciences</topic><topic>Buffer layer</topic><topic>Buffer layers</topic><topic>Cadmium</topic><topic>Copper zinc tin sulfur selenide</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Dynamic tests</topic><topic>Energy</topic><topic>Energy conversion efficiency</topic><topic>Exact sciences and technology</topic><topic>Kesterite</topic><topic>Light soaking</topic><topic>Materials science</topic><topic>Metastability</topic><topic>Natural energy</topic><topic>Other semiconductors</topic><topic>Photovoltaic cells</topic><topic>Photovoltaic conversion</topic><topic>Physics</topic><topic>Soaking</topic><topic>Solar cells</topic><topic>Solar cells. Photoelectrochemical cells</topic><topic>Solar energy</topic><topic>Specific materials</topic><topic>Thin films</topic><topic>Zinc sulfide</topic><topic>ZnS(O,OH)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Grenet, Louis</creatorcontrib><creatorcontrib>Grondin, Pauline</creatorcontrib><creatorcontrib>Coumert, Karol</creatorcontrib><creatorcontrib>Karst, Nicolas</creatorcontrib><creatorcontrib>Emieux, Fabrice</creatorcontrib><creatorcontrib>Roux, Frédéric</creatorcontrib><creatorcontrib>Fillon, Raphaël</creatorcontrib><creatorcontrib>Altamura, Giovanni</creatorcontrib><creatorcontrib>Fournier, Hélène</creatorcontrib><creatorcontrib>Faucherand, Pascal</creatorcontrib><creatorcontrib>Perraud, Simon</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Thin solid films</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Grenet, Louis</au><au>Grondin, Pauline</au><au>Coumert, Karol</au><au>Karst, Nicolas</au><au>Emieux, Fabrice</au><au>Roux, Frédéric</au><au>Fillon, Raphaël</au><au>Altamura, Giovanni</au><au>Fournier, Hélène</au><au>Faucherand, Pascal</au><au>Perraud, Simon</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Experimental evidence of light soaking effect in Cd-free Cu2ZnSn(S,Se)4-based solar cells</atitle><jtitle>Thin solid films</jtitle><date>2014-08-01</date><risdate>2014</risdate><volume>564</volume><spage>375</spage><epage>378</epage><pages>375-378</pages><issn>0040-6090</issn><eissn>1879-2731</eissn><coden>THSFAP</coden><abstract>The use of a Zn-based buffer layer for kesterite solar cells presents the double advantage of avoiding cadmium and reducing the amount of light absorbed in this layer. Cu2ZnSn(S,Se)4 solar cells with a ZnS(O,OH) buffer layer have been fabricated and power conversion efficiencies up to 5.8% after light soaking treatment have been measured. Cu2ZnSn(Se,S)4 solar cells with a CdS buffer layer have also been realized, leading to a power conversion efficiency up to 7.0%. The dynamics of the light soaking effect in the case of the ZnS(O,OH) buffer layer has been studied as well, and compared to the same effect on a cell with a Cu(In,Ga)Se2 absorber layer.
•5.8% of efficiency for a Cu2ZnSn(S,Se)4 solar cell with a ZnS(O,OH) buffer layer•7.0% of efficiency for a reference Cu2ZnSn(S,Se)4 solar cell with a CdS buffer layer•ZnS(O,OH) buffer layer required at least 1000min of light soaking treatment.•Required light soaking treatment is longer for Cu2ZnSn(S,Se)4 than for Cu(In,Ga)Se2.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.tsf.2014.05.033</doi><tpages>4</tpages></addata></record> |
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subjects | Applied sciences Buffer layer Buffer layers Cadmium Copper zinc tin sulfur selenide Cross-disciplinary physics: materials science rheology Dynamic tests Energy Energy conversion efficiency Exact sciences and technology Kesterite Light soaking Materials science Metastability Natural energy Other semiconductors Photovoltaic cells Photovoltaic conversion Physics Soaking Solar cells Solar cells. Photoelectrochemical cells Solar energy Specific materials Thin films Zinc sulfide ZnS(O,OH) |
title | Experimental evidence of light soaking effect in Cd-free Cu2ZnSn(S,Se)4-based solar cells |
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