Determination of sulfite with emphasis on biosensing methods: a review
Sulfite is used as a preservative in a variety of food and pharmaceutical industries to inhibit enzymatic and nonenzymatic browning and in brewing industries as an antibacterial and antioxidizing agent. Convenient and reproducible analytical methods employing sulfite oxidase are an attractive altern...
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Veröffentlicht in: | Analytical and bioanalytical chemistry 2013-04, Vol.405 (10), p.3049-3062 |
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description | Sulfite is used as a preservative in a variety of food and pharmaceutical industries to inhibit enzymatic and nonenzymatic browning and in brewing industries as an antibacterial and antioxidizing agent. Convenient and reproducible analytical methods employing sulfite oxidase are an attractive alternative to conventional detection methods. Sulfite biosensors are based on measurement of either O
2
or electrons generated from splitting of H
2
O
2
or heat released during oxidation of sulfite by immobilized sulfite oxidase. Sulfite biosensors can be grouped into 12 classes. They work optimally within 2 to 900 s, between pH 6.5 and 9.0, 25 and 40 °C, and in the range from 0 to 50,000 μM, with detection limit between 0.2 and 200 μM. Sulfite biosensors measure sulfite in food, beverages, and water and can be reused 100–300 times over a period of 1–240 days. The review presents the principles, merits, and demerits of various analytical methods for determination of sulfite, with special emphasis on sulfite biosensors. |
doi_str_mv | 10.1007/s00216-013-6753-0 |
format | Article |
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2
or electrons generated from splitting of H
2
O
2
or heat released during oxidation of sulfite by immobilized sulfite oxidase. Sulfite biosensors can be grouped into 12 classes. They work optimally within 2 to 900 s, between pH 6.5 and 9.0, 25 and 40 °C, and in the range from 0 to 50,000 μM, with detection limit between 0.2 and 200 μM. Sulfite biosensors measure sulfite in food, beverages, and water and can be reused 100–300 times over a period of 1–240 days. The review presents the principles, merits, and demerits of various analytical methods for determination of sulfite, with special emphasis on sulfite biosensors.</description><identifier>ISSN: 1618-2642</identifier><identifier>EISSN: 1618-2650</identifier><identifier>DOI: 10.1007/s00216-013-6753-0</identifier><identifier>PMID: 23392406</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer-Verlag</publisher><subject>Analytical Chemistry ; Analytical methods ; Antiinfectives and antibacterials ; Automation ; Beverages ; Biochemistry ; Biosensing Techniques - methods ; Biosensors ; Browning ; Capillary electrophoresis ; Characterization and Evaluation of Materials ; Chemical properties ; Chemistry ; Chemistry and Materials Science ; Chromatography ; Composition ; Cytochrome ; Food ; Food Analysis ; Food Preservatives - analysis ; Food Science ; Foods ; Fruits ; Hydrogen peroxide ; Identification and classification ; Iodine ; Laboratory Medicine ; Mathematical analysis ; Methods ; Monitoring/Environmental Analysis ; Oxidase ; Oxidation ; Pharmaceutical industry ; Preservatives ; Review ; Sodium ; Sulfites ; Sulfites - analysis ; Sulfur ; Testing ; Water chemistry</subject><ispartof>Analytical and bioanalytical chemistry, 2013-04, Vol.405 (10), p.3049-3062</ispartof><rights>Springer-Verlag Berlin Heidelberg 2013</rights><rights>COPYRIGHT 2013 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c514t-c7c044b36c81dd95cee6a032a7974822db8d9b3dfb58856497eae80c08c454123</citedby><cites>FETCH-LOGICAL-c514t-c7c044b36c81dd95cee6a032a7974822db8d9b3dfb58856497eae80c08c454123</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00216-013-6753-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00216-013-6753-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23392406$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Pundir, Chandra Shekhar</creatorcontrib><creatorcontrib>Rawal, Rachna</creatorcontrib><title>Determination of sulfite with emphasis on biosensing methods: a review</title><title>Analytical and bioanalytical chemistry</title><addtitle>Anal Bioanal Chem</addtitle><addtitle>Anal Bioanal Chem</addtitle><description>Sulfite is used as a preservative in a variety of food and pharmaceutical industries to inhibit enzymatic and nonenzymatic browning and in brewing industries as an antibacterial and antioxidizing agent. Convenient and reproducible analytical methods employing sulfite oxidase are an attractive alternative to conventional detection methods. Sulfite biosensors are based on measurement of either O
2
or electrons generated from splitting of H
2
O
2
or heat released during oxidation of sulfite by immobilized sulfite oxidase. Sulfite biosensors can be grouped into 12 classes. They work optimally within 2 to 900 s, between pH 6.5 and 9.0, 25 and 40 °C, and in the range from 0 to 50,000 μM, with detection limit between 0.2 and 200 μM. Sulfite biosensors measure sulfite in food, beverages, and water and can be reused 100–300 times over a period of 1–240 days. The review presents the principles, merits, and demerits of various analytical methods for determination of sulfite, with special emphasis on sulfite biosensors.</description><subject>Analytical Chemistry</subject><subject>Analytical methods</subject><subject>Antiinfectives and antibacterials</subject><subject>Automation</subject><subject>Beverages</subject><subject>Biochemistry</subject><subject>Biosensing Techniques - methods</subject><subject>Biosensors</subject><subject>Browning</subject><subject>Capillary electrophoresis</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical properties</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chromatography</subject><subject>Composition</subject><subject>Cytochrome</subject><subject>Food</subject><subject>Food Analysis</subject><subject>Food Preservatives - analysis</subject><subject>Food Science</subject><subject>Foods</subject><subject>Fruits</subject><subject>Hydrogen peroxide</subject><subject>Identification and classification</subject><subject>Iodine</subject><subject>Laboratory Medicine</subject><subject>Mathematical analysis</subject><subject>Methods</subject><subject>Monitoring/Environmental Analysis</subject><subject>Oxidase</subject><subject>Oxidation</subject><subject>Pharmaceutical industry</subject><subject>Preservatives</subject><subject>Review</subject><subject>Sodium</subject><subject>Sulfites</subject><subject>Sulfites - 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methods</topic><topic>Biosensors</topic><topic>Browning</topic><topic>Capillary electrophoresis</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical properties</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chromatography</topic><topic>Composition</topic><topic>Cytochrome</topic><topic>Food</topic><topic>Food Analysis</topic><topic>Food Preservatives - analysis</topic><topic>Food Science</topic><topic>Foods</topic><topic>Fruits</topic><topic>Hydrogen peroxide</topic><topic>Identification and classification</topic><topic>Iodine</topic><topic>Laboratory Medicine</topic><topic>Mathematical analysis</topic><topic>Methods</topic><topic>Monitoring/Environmental Analysis</topic><topic>Oxidase</topic><topic>Oxidation</topic><topic>Pharmaceutical industry</topic><topic>Preservatives</topic><topic>Review</topic><topic>Sodium</topic><topic>Sulfites</topic><topic>Sulfites - analysis</topic><topic>Sulfur</topic><topic>Testing</topic><topic>Water chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pundir, Chandra Shekhar</creatorcontrib><creatorcontrib>Rawal, Rachna</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>Biological Science Collection</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Materials Science Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>ProQuest Biological Science Collection</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Biological Science Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>MEDLINE - Academic</collection><collection>Aqualine</collection><collection>Water Resources Abstracts</collection><jtitle>Analytical and bioanalytical chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pundir, Chandra Shekhar</au><au>Rawal, Rachna</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determination of sulfite with emphasis on biosensing methods: a review</atitle><jtitle>Analytical and bioanalytical chemistry</jtitle><stitle>Anal Bioanal Chem</stitle><addtitle>Anal Bioanal Chem</addtitle><date>2013-04-01</date><risdate>2013</risdate><volume>405</volume><issue>10</issue><spage>3049</spage><epage>3062</epage><pages>3049-3062</pages><issn>1618-2642</issn><eissn>1618-2650</eissn><abstract>Sulfite is used as a preservative in a variety of food and pharmaceutical industries to inhibit enzymatic and nonenzymatic browning and in brewing industries as an antibacterial and antioxidizing agent. Convenient and reproducible analytical methods employing sulfite oxidase are an attractive alternative to conventional detection methods. Sulfite biosensors are based on measurement of either O
2
or electrons generated from splitting of H
2
O
2
or heat released during oxidation of sulfite by immobilized sulfite oxidase. Sulfite biosensors can be grouped into 12 classes. They work optimally within 2 to 900 s, between pH 6.5 and 9.0, 25 and 40 °C, and in the range from 0 to 50,000 μM, with detection limit between 0.2 and 200 μM. Sulfite biosensors measure sulfite in food, beverages, and water and can be reused 100–300 times over a period of 1–240 days. The review presents the principles, merits, and demerits of various analytical methods for determination of sulfite, with special emphasis on sulfite biosensors.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><pmid>23392406</pmid><doi>10.1007/s00216-013-6753-0</doi><tpages>14</tpages></addata></record> |
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subjects | Analytical Chemistry Analytical methods Antiinfectives and antibacterials Automation Beverages Biochemistry Biosensing Techniques - methods Biosensors Browning Capillary electrophoresis Characterization and Evaluation of Materials Chemical properties Chemistry Chemistry and Materials Science Chromatography Composition Cytochrome Food Food Analysis Food Preservatives - analysis Food Science Foods Fruits Hydrogen peroxide Identification and classification Iodine Laboratory Medicine Mathematical analysis Methods Monitoring/Environmental Analysis Oxidase Oxidation Pharmaceutical industry Preservatives Review Sodium Sulfites Sulfites - analysis Sulfur Testing Water chemistry |
title | Determination of sulfite with emphasis on biosensing methods: a review |
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