Role of water in metal catalyst performance for ketone hydrogenation: a joint experimental and theoretical study on levulinic acid conversion into gamma-valerolactone
While Ru is a poor hydrogenation catalyst compared to Pt or Pd in the gas phase, it is efficient under aqueous phase conditions in the hydrogenation of ketones such as the conversion of levulinic acid into gamma-valerolactone. Combining DFT calculations and experiments, we demonstrate that water is...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2014-10, Vol.50 (83), p.12450-12453 |
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| container_end_page | 12453 |
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| container_issue | 83 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 50 |
| creator | Michel, Carine Zaffran, Jérémie Ruppert, Agnieszka M Matras-Michalska, Joanna Jędrzejczyk, Marcin Grams, Jacek Sautet, Philippe |
| description | While Ru is a poor hydrogenation catalyst compared to Pt or Pd in the gas phase, it is efficient under aqueous phase conditions in the hydrogenation of ketones such as the conversion of levulinic acid into gamma-valerolactone. Combining DFT calculations and experiments, we demonstrate that water is responsible for the enhanced reactivity of Ru under those conditions. |
| doi_str_mv | 10.1039/c4cc04401k |
| format | Article |
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Combining DFT calculations and experiments, we demonstrate that water is responsible for the enhanced reactivity of Ru under those conditions.</abstract><cop>England</cop><pmid>24980805</pmid><doi>10.1039/c4cc04401k</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2014-10, Vol.50 (83), p.12450-12453 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1660037955 |
| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Catalysis Catalysts Conversion Gas phases Hydrogenation Ketones Ketones - chemistry Lactones - chemistry Levulinic Acids - chemistry Mathematical analysis Models, Molecular Palladium Platinum Water - chemistry |
| title | Role of water in metal catalyst performance for ketone hydrogenation: a joint experimental and theoretical study on levulinic acid conversion into gamma-valerolactone |
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