Straightforward Access to the [3.2.2]Nonatriene Structural Framework via Intramolecular Cyclopropenation/Buchner Reaction/Cope Rearrangement Cascade

A one-pot cascade process of benzyl enoldiazoacatates, initiated by dirhodium(II)-catalyzed intramolecular cyclopropene formation, occurs via a subsequent Buchner reaction and Cope rearrangement to provide straightforward access to bicyclo[3.2.2]nonatriene derivatives in high yields and selectivitie...

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Veröffentlicht in:	Organic letters 2015-02, Vol.17 (4), p.790-793
Hauptverfasser:	Xu, Xinfang, Wang, Xiangbo, Zavalij, Peter Y, Doyle, Michael P
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzyl Compounds - chemical synthesis Benzyl Compounds - chemistry Bridged Bicyclo Compounds - chemistry Catalysis Cycloparaffins - chemistry Cyclopropanes - chemistry Molecular Structure Rhodium - chemistry
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description	A one-pot cascade process of benzyl enoldiazoacatates, initiated by dirhodium(II)-catalyzed intramolecular cyclopropene formation, occurs via a subsequent Buchner reaction and Cope rearrangement to provide straightforward access to bicyclo[3.2.2]nonatriene derivatives in high yields and selectivities.
doi_str_mv	10.1021/ol503498n
format	Article
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subjects	Benzyl Compounds - chemical synthesis Benzyl Compounds - chemistry Bridged Bicyclo Compounds - chemistry Catalysis Cycloparaffins - chemistry Cyclopropanes - chemistry Molecular Structure Rhodium - chemistry
title	Straightforward Access to the [3.2.2]Nonatriene Structural Framework via Intramolecular Cyclopropenation/Buchner Reaction/Cope Rearrangement Cascade
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