Rapid enzymatic production of acylglycerols from conjugated linoleic acid and glycerol in a solvent-free system

Rates and product distributions have been determined for the consecutive esterification reactions of conjugated linoleic acid (CLA) with glycerol in the presence of an immobilized Candida antarctica lipase from Novo Nordisk (Lipozyme IM). In a solvent-free environment, both rates and product distrib...

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Veröffentlicht in:Biotechnology letters 1998-06, Vol.20 (6), p.617-621
Hauptverfasser: ARCOS, J. A, OTERO, C, HILL, C. G
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description Rates and product distributions have been determined for the consecutive esterification reactions of conjugated linoleic acid (CLA) with glycerol in the presence of an immobilized Candida antarctica lipase from Novo Nordisk (Lipozyme IM). In a solvent-free environment, both rates and product distributions are affected by the ratio of reactants, temperature, and hydration level. For mole ratios of CLA to glycerol ranging from 1/1 to 3/1, incorporation of at least 95% of the original CLA into the product acylglycerols was achieved in less than 7 h of reaction at 50°C. © Rapid Science Ltd. 1998[PUBLICATION ABSTRACT]
doi_str_mv 10.1023/A:1005370232725
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subjects Bioconversions. Hemisynthesis
Biological and medical sciences
Biotechnology
Fatty acids
Fundamental and applied biological sciences. Psychology
Methods. Procedures. Technologies
Solvents
title Rapid enzymatic production of acylglycerols from conjugated linoleic acid and glycerol in a solvent-free system
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