Quest for Anionic MOF Membranes: Continuous sod-ZMOF Membrane with CO2 Adsorption-Driven Selectivity
We report the fabrication of the first continuous zeolite-like metal–organic framework (ZMOF) thin-film membrane. A pure phase sod-ZMOF, sodalite topology, membrane was grown and supported on a porous alumina substrate using a solvothermal crystallization method. The absence of pinhole defects in th...
Gespeichert in:
| Veröffentlicht in: | Journal of the American Chemical Society 2015-02, Vol.137 (5), p.1754-1757 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1757 |
|---|---|
| container_issue | 5 |
| container_start_page | 1754 |
| container_title | Journal of the American Chemical Society |
| container_volume | 137 |
| creator | Al-Maythalony, Bassem A Shekhah, Osama Swaidan, Raja Belmabkhout, Youssef Pinnau, Ingo Eddaoudi, Mohamed |
| description | We report the fabrication of the first continuous zeolite-like metal–organic framework (ZMOF) thin-film membrane. A pure phase sod-ZMOF, sodalite topology, membrane was grown and supported on a porous alumina substrate using a solvothermal crystallization method. The absence of pinhole defects in the film was confirmed and supported by the occurrence of quantifiable time-lags, for all studied gases, during constant volume/variable pressure permeation tests. For both pure and mixed gas feeds, the sod-ZMOF-1 membrane exhibits favorable permeation selectivity toward carbon dioxide over relevant industrial gases such as H2, N2, and CH4, and it is mainly governed by favorable CO2 adsorption. |
| doi_str_mv | 10.1021/ja511495j |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_proquest_miscellaneous_1654701213</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1654701213</sourcerecordid><originalsourceid>FETCH-LOGICAL-a241t-b9f9bad435bb128b6bf3dc9c059754f0ef3107e49b6d58a4440a5333087f149d3</originalsourceid><addsrcrecordid>eNpNkF1LwzAYhYMobn5c-AckN4I31Xy2qXejOhU2hqg33pSkSTGla2bSTvbvzdgUr14O78PhnAPABUY3GBF820iOMct5cwDGmBOUcEzSQzBGCJEkEykdgZMQmigZEfgYjAjnAgksxkC_DCb0sHYeTjrrOlvB-WIK52apvOxMuIOF63rbDW4IMDidfPx_w2_bf8JiQeBEB-dXfXRI7r1dmw6-mtZUvV3bfnMGjmrZBnO-v6fgffrwVjwls8XjczGZJZIw3Ccqr3MlNaNcKUyESlVNdZVXiOcZZzUyNcUoMyxXqeZCMsaQ5JRSJLI61tf0FFzvfFfefW17lUsbKtO2MWrMX-KUswxhgmlEL_fooJZGlytvl9Jvyt9lInC1A2QVysYNvovJS4zK7eLl3-L0B7Gab0M</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1654701213</pqid></control><display><type>article</type><title>Quest for Anionic MOF Membranes: Continuous sod-ZMOF Membrane with CO2 Adsorption-Driven Selectivity</title><source>ACS Publications</source><creator>Al-Maythalony, Bassem A ; Shekhah, Osama ; Swaidan, Raja ; Belmabkhout, Youssef ; Pinnau, Ingo ; Eddaoudi, Mohamed</creator><creatorcontrib>Al-Maythalony, Bassem A ; Shekhah, Osama ; Swaidan, Raja ; Belmabkhout, Youssef ; Pinnau, Ingo ; Eddaoudi, Mohamed</creatorcontrib><description>We report the fabrication of the first continuous zeolite-like metal–organic framework (ZMOF) thin-film membrane. A pure phase sod-ZMOF, sodalite topology, membrane was grown and supported on a porous alumina substrate using a solvothermal crystallization method. The absence of pinhole defects in the film was confirmed and supported by the occurrence of quantifiable time-lags, for all studied gases, during constant volume/variable pressure permeation tests. For both pure and mixed gas feeds, the sod-ZMOF-1 membrane exhibits favorable permeation selectivity toward carbon dioxide over relevant industrial gases such as H2, N2, and CH4, and it is mainly governed by favorable CO2 adsorption.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja511495j</identifier><identifier>PMID: 25580818</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>Journal of the American Chemical Society, 2015-02, Vol.137 (5), p.1754-1757</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ja511495j$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ja511495j$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,27055,27903,27904,56716,56766</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25580818$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Al-Maythalony, Bassem A</creatorcontrib><creatorcontrib>Shekhah, Osama</creatorcontrib><creatorcontrib>Swaidan, Raja</creatorcontrib><creatorcontrib>Belmabkhout, Youssef</creatorcontrib><creatorcontrib>Pinnau, Ingo</creatorcontrib><creatorcontrib>Eddaoudi, Mohamed</creatorcontrib><title>Quest for Anionic MOF Membranes: Continuous sod-ZMOF Membrane with CO2 Adsorption-Driven Selectivity</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>We report the fabrication of the first continuous zeolite-like metal–organic framework (ZMOF) thin-film membrane. A pure phase sod-ZMOF, sodalite topology, membrane was grown and supported on a porous alumina substrate using a solvothermal crystallization method. The absence of pinhole defects in the film was confirmed and supported by the occurrence of quantifiable time-lags, for all studied gases, during constant volume/variable pressure permeation tests. For both pure and mixed gas feeds, the sod-ZMOF-1 membrane exhibits favorable permeation selectivity toward carbon dioxide over relevant industrial gases such as H2, N2, and CH4, and it is mainly governed by favorable CO2 adsorption.</description><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNpNkF1LwzAYhYMobn5c-AckN4I31Xy2qXejOhU2hqg33pSkSTGla2bSTvbvzdgUr14O78PhnAPABUY3GBF820iOMct5cwDGmBOUcEzSQzBGCJEkEykdgZMQmigZEfgYjAjnAgksxkC_DCb0sHYeTjrrOlvB-WIK52apvOxMuIOF63rbDW4IMDidfPx_w2_bf8JiQeBEB-dXfXRI7r1dmw6-mtZUvV3bfnMGjmrZBnO-v6fgffrwVjwls8XjczGZJZIw3Ccqr3MlNaNcKUyESlVNdZVXiOcZZzUyNcUoMyxXqeZCMsaQ5JRSJLI61tf0FFzvfFfefW17lUsbKtO2MWrMX-KUswxhgmlEL_fooJZGlytvl9Jvyt9lInC1A2QVysYNvovJS4zK7eLl3-L0B7Gab0M</recordid><startdate>20150211</startdate><enddate>20150211</enddate><creator>Al-Maythalony, Bassem A</creator><creator>Shekhah, Osama</creator><creator>Swaidan, Raja</creator><creator>Belmabkhout, Youssef</creator><creator>Pinnau, Ingo</creator><creator>Eddaoudi, Mohamed</creator><general>American Chemical Society</general><scope>NPM</scope><scope>7X8</scope></search><sort><creationdate>20150211</creationdate><title>Quest for Anionic MOF Membranes: Continuous sod-ZMOF Membrane with CO2 Adsorption-Driven Selectivity</title><author>Al-Maythalony, Bassem A ; Shekhah, Osama ; Swaidan, Raja ; Belmabkhout, Youssef ; Pinnau, Ingo ; Eddaoudi, Mohamed</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a241t-b9f9bad435bb128b6bf3dc9c059754f0ef3107e49b6d58a4440a5333087f149d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Al-Maythalony, Bassem A</creatorcontrib><creatorcontrib>Shekhah, Osama</creatorcontrib><creatorcontrib>Swaidan, Raja</creatorcontrib><creatorcontrib>Belmabkhout, Youssef</creatorcontrib><creatorcontrib>Pinnau, Ingo</creatorcontrib><creatorcontrib>Eddaoudi, Mohamed</creatorcontrib><collection>PubMed</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Al-Maythalony, Bassem A</au><au>Shekhah, Osama</au><au>Swaidan, Raja</au><au>Belmabkhout, Youssef</au><au>Pinnau, Ingo</au><au>Eddaoudi, Mohamed</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Quest for Anionic MOF Membranes: Continuous sod-ZMOF Membrane with CO2 Adsorption-Driven Selectivity</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2015-02-11</date><risdate>2015</risdate><volume>137</volume><issue>5</issue><spage>1754</spage><epage>1757</epage><pages>1754-1757</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><abstract>We report the fabrication of the first continuous zeolite-like metal–organic framework (ZMOF) thin-film membrane. A pure phase sod-ZMOF, sodalite topology, membrane was grown and supported on a porous alumina substrate using a solvothermal crystallization method. The absence of pinhole defects in the film was confirmed and supported by the occurrence of quantifiable time-lags, for all studied gases, during constant volume/variable pressure permeation tests. For both pure and mixed gas feeds, the sod-ZMOF-1 membrane exhibits favorable permeation selectivity toward carbon dioxide over relevant industrial gases such as H2, N2, and CH4, and it is mainly governed by favorable CO2 adsorption.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>25580818</pmid><doi>10.1021/ja511495j</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0002-7863 |
| ispartof | Journal of the American Chemical Society, 2015-02, Vol.137 (5), p.1754-1757 |
| issn | 0002-7863 1520-5126 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1654701213 |
| source | ACS Publications |
| title | Quest for Anionic MOF Membranes: Continuous sod-ZMOF Membrane with CO2 Adsorption-Driven Selectivity |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-26T02%3A49%3A02IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Quest%20for%20Anionic%20MOF%20Membranes:%20Continuous%20sod-ZMOF%20Membrane%20with%20CO2%20Adsorption-Driven%20Selectivity&rft.jtitle=Journal%20of%20the%20American%20Chemical%20Society&rft.au=Al-Maythalony,%20Bassem%20A&rft.date=2015-02-11&rft.volume=137&rft.issue=5&rft.spage=1754&rft.epage=1757&rft.pages=1754-1757&rft.issn=0002-7863&rft.eissn=1520-5126&rft_id=info:doi/10.1021/ja511495j&rft_dat=%3Cproquest_pubme%3E1654701213%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1654701213&rft_id=info:pmid/25580818&rfr_iscdi=true |