Polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and pentachlorophenol (PCP) in bottom sediments of the Port of Gdansk
Combustion processes are considered to be the main source of the dioxin emission in the Baltic region. Pentachlorophenol (PCP) and its derivatives, pentachlorophenyl laurate (PCPL) and sodium pentachlorophenate (NaPCP) are known as precursors of dioxins. The research was conducted to obtain the firs...
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description | Combustion processes are considered to be the main source of the dioxin emission in the Baltic region. Pentachlorophenol (PCP) and its derivatives, pentachlorophenyl laurate (PCPL) and sodium pentachlorophenate (NaPCP) are known as precursors of dioxins. The research was conducted to obtain the first data on the concentration of PCDD/Fs and PCP in the bottom sediments of the Port of Gdansk. Toxicity (the Microtox® test) as well as several sediment parameters have been examined.
In the surface layer of bottom sediments from the Port of Gdansk, all congeners of PCDD/Fs have been detected using GC-MS/MS. The highest concentration was obtained for OCDD (224.0–271.0 pg g
−1
d.w.) and HpCDD (51.0–36.0 pg g
−1
d.w.). The content of ΣPCDDs prevailed over ΣPCDFs. This may indicate that anthropogenic pollution from the land-based thermal sources has the strongest impact on the concentration of dioxins in the port sediments. The concentration of 17 dioxin congeners (WHO-TEQ) did not exceed the probable effect level (PEL) of 21.5 pg TEQ g
−1
d.w. The concentration of PCP ranged from bellow the LOD (< 0.85 ng g
−1
d.w.) to 12.4 ng g
−1
d.w.
The positive correlation between toxicity and physico-chemical properties of the analyzed bottom sediments confirms that these parameters are important in terms of environment contamination. |
doi_str_mv | 10.2478/s13545-014-0146-7 |
format | Article |
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In the surface layer of bottom sediments from the Port of Gdansk, all congeners of PCDD/Fs have been detected using GC-MS/MS. The highest concentration was obtained for OCDD (224.0–271.0 pg g
−1
d.w.) and HpCDD (51.0–36.0 pg g
−1
d.w.). The content of ΣPCDDs prevailed over ΣPCDFs. This may indicate that anthropogenic pollution from the land-based thermal sources has the strongest impact on the concentration of dioxins in the port sediments. The concentration of 17 dioxin congeners (WHO-TEQ) did not exceed the probable effect level (PEL) of 21.5 pg TEQ g
−1
d.w. The concentration of PCP ranged from bellow the LOD (< 0.85 ng g
−1
d.w.) to 12.4 ng g
−1
d.w.
The positive correlation between toxicity and physico-chemical properties of the analyzed bottom sediments confirms that these parameters are important in terms of environment contamination.</description><identifier>ISSN: 1730-413X</identifier><identifier>ISSN: 1897-3191</identifier><identifier>EISSN: 1897-3191</identifier><identifier>DOI: 10.2478/s13545-014-0146-7</identifier><language>eng</language><publisher>Heidelberg: Versita</publisher><subject>Anthropogenic factors ; Bottom sediments ; Chemical properties ; Chemicophysical properties ; Chlorinated hydrocarbons ; Congeners ; Contamination ; Dioxins ; Earth and Environmental Science ; Earth Sciences ; Flow velocity ; Hazardous materials ; Human influences ; Land pollution ; Marine ; Marine & Freshwater Sciences ; Microtox ; Oceanography ; organochlorine contaminants ; Original Research Paper ; Parameters ; PCB ; Pentachlorophenol ; Physicochemical processes ; Physicochemical properties ; Polychlorinated biphenyls ; Polychlorinated dibenzodioxins ; Polychlorinated dibenzofurans ; Port of Gdansk ; Ports ; profile of the dioxin congeners ; Sediment ; Sediments ; Sodium ; Surface layers ; Toxicity ; Toxicity testing</subject><ispartof>Oceanological and hydrobiological studies, 2014-09, Vol.43 (3), p.312-323</ispartof><rights>Versita Warsaw and Springer-Verlag Wien 2014</rights><rights>2014. This work is published under http://creativecommons.org/licenses/by-nc-nd/3.0 (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c509t-44a25a8505d8c1041332a5b7ff97b866f1614ef61f791912d9b265131986b69f3</citedby><cites>FETCH-LOGICAL-c509t-44a25a8505d8c1041332a5b7ff97b866f1614ef61f791912d9b265131986b69f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,864,27924,27925</link.rule.ids></links><search><creatorcontrib>Lewandowski, Krzysztof</creatorcontrib><creatorcontrib>Witt, Maria</creatorcontrib><creatorcontrib>Kobusińska, Marta</creatorcontrib><creatorcontrib>Niemirycz, Elżbieta</creatorcontrib><title>Polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and pentachlorophenol (PCP) in bottom sediments of the Port of Gdansk</title><title>Oceanological and hydrobiological studies</title><addtitle>Ocean and Hydro</addtitle><description>Combustion processes are considered to be the main source of the dioxin emission in the Baltic region. Pentachlorophenol (PCP) and its derivatives, pentachlorophenyl laurate (PCPL) and sodium pentachlorophenate (NaPCP) are known as precursors of dioxins. The research was conducted to obtain the first data on the concentration of PCDD/Fs and PCP in the bottom sediments of the Port of Gdansk. Toxicity (the Microtox® test) as well as several sediment parameters have been examined.
In the surface layer of bottom sediments from the Port of Gdansk, all congeners of PCDD/Fs have been detected using GC-MS/MS. The highest concentration was obtained for OCDD (224.0–271.0 pg g
−1
d.w.) and HpCDD (51.0–36.0 pg g
−1
d.w.). The content of ΣPCDDs prevailed over ΣPCDFs. This may indicate that anthropogenic pollution from the land-based thermal sources has the strongest impact on the concentration of dioxins in the port sediments. The concentration of 17 dioxin congeners (WHO-TEQ) did not exceed the probable effect level (PEL) of 21.5 pg TEQ g
−1
d.w. The concentration of PCP ranged from bellow the LOD (< 0.85 ng g
−1
d.w.) to 12.4 ng g
−1
d.w.
The positive correlation between toxicity and physico-chemical properties of the analyzed bottom sediments confirms that these parameters are important in terms of environment contamination.</description><subject>Anthropogenic factors</subject><subject>Bottom sediments</subject><subject>Chemical properties</subject><subject>Chemicophysical properties</subject><subject>Chlorinated hydrocarbons</subject><subject>Congeners</subject><subject>Contamination</subject><subject>Dioxins</subject><subject>Earth and Environmental Science</subject><subject>Earth Sciences</subject><subject>Flow velocity</subject><subject>Hazardous materials</subject><subject>Human influences</subject><subject>Land pollution</subject><subject>Marine</subject><subject>Marine & Freshwater Sciences</subject><subject>Microtox</subject><subject>Oceanography</subject><subject>organochlorine contaminants</subject><subject>Original Research Paper</subject><subject>Parameters</subject><subject>PCB</subject><subject>Pentachlorophenol</subject><subject>Physicochemical processes</subject><subject>Physicochemical properties</subject><subject>Polychlorinated biphenyls</subject><subject>Polychlorinated dibenzodioxins</subject><subject>Polychlorinated dibenzofurans</subject><subject>Port of Gdansk</subject><subject>Ports</subject><subject>profile of the dioxin congeners</subject><subject>Sediment</subject><subject>Sediments</subject><subject>Sodium</subject><subject>Surface layers</subject><subject>Toxicity</subject><subject>Toxicity testing</subject><issn>1730-413X</issn><issn>1897-3191</issn><issn>1897-3191</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNqNkU2L1TAUhosoOI7-AHcBN3PBaE4-25XIHWcUBrwLBXchbZO5HXuTmqTo9Yf4e03tLERUZnHIgTzve76q6imQF5Sr-mUCJrjABPgSEqt71QnUjcIMGrhfcsUI5sA-PawepXRDiBCi5ifVj10Yj91-DHHwJtse9UNr_feAJ9wP4dvgEzrbbc_P0-Y5mv6OujmaW-wibZDxPZqsz-YXGqa99WFcfncbNHjUhpzDASXbD4dCJRQcynuLdiHmJb_si9nnx9UDZ8Zkn9y-p9XHizcftm_x1fvLd9vXV7gTpMmYc0OFqQURfd0BKfMxakSrnGtUW0vpQAK3ToJTTdkD7ZuWSgFlJ7VsZePYaXW2-k4xfJltyvowpM6Oo_E2zEmDFFwWI4A7oJRK0pSlF_TZH-hNmKMvg2haAyhQXLH_UaVtpUAQulCwUl0MKUXr9BSHg4lHDUQvp9fr6XU5-xJSq6J5tWq-mjHb2NvrOB9L8luBf2k5YwxocaCrQyrV_PWdpOwnzTTDDA</recordid><startdate>20140901</startdate><enddate>20140901</enddate><creator>Lewandowski, Krzysztof</creator><creator>Witt, Maria</creator><creator>Kobusińska, Marta</creator><creator>Niemirycz, Elżbieta</creator><general>Versita</general><general>Walter de Gruyter GmbH</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7TN</scope><scope>7UA</scope><scope>8FD</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>F1W</scope><scope>FR3</scope><scope>H95</scope><scope>H96</scope><scope>H97</scope><scope>H99</scope><scope>HCIFZ</scope><scope>L.F</scope><scope>L.G</scope><scope>P64</scope><scope>PCBAR</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>7SN</scope><scope>7TV</scope></search><sort><creationdate>20140901</creationdate><title>Polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and pentachlorophenol (PCP) in bottom sediments of the Port of Gdansk</title><author>Lewandowski, Krzysztof ; 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Pentachlorophenol (PCP) and its derivatives, pentachlorophenyl laurate (PCPL) and sodium pentachlorophenate (NaPCP) are known as precursors of dioxins. The research was conducted to obtain the first data on the concentration of PCDD/Fs and PCP in the bottom sediments of the Port of Gdansk. Toxicity (the Microtox® test) as well as several sediment parameters have been examined.
In the surface layer of bottom sediments from the Port of Gdansk, all congeners of PCDD/Fs have been detected using GC-MS/MS. The highest concentration was obtained for OCDD (224.0–271.0 pg g
−1
d.w.) and HpCDD (51.0–36.0 pg g
−1
d.w.). The content of ΣPCDDs prevailed over ΣPCDFs. This may indicate that anthropogenic pollution from the land-based thermal sources has the strongest impact on the concentration of dioxins in the port sediments. The concentration of 17 dioxin congeners (WHO-TEQ) did not exceed the probable effect level (PEL) of 21.5 pg TEQ g
−1
d.w. The concentration of PCP ranged from bellow the LOD (< 0.85 ng g
−1
d.w.) to 12.4 ng g
−1
d.w.
The positive correlation between toxicity and physico-chemical properties of the analyzed bottom sediments confirms that these parameters are important in terms of environment contamination.</abstract><cop>Heidelberg</cop><pub>Versita</pub><doi>10.2478/s13545-014-0146-7</doi><tpages>12</tpages><oa>free_for_read</oa></addata></record> |
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source | DOAJ Directory of Open Access Journals; EZB-FREE-00999 freely available EZB journals; Alma/SFX Local Collection |
subjects | Anthropogenic factors Bottom sediments Chemical properties Chemicophysical properties Chlorinated hydrocarbons Congeners Contamination Dioxins Earth and Environmental Science Earth Sciences Flow velocity Hazardous materials Human influences Land pollution Marine Marine & Freshwater Sciences Microtox Oceanography organochlorine contaminants Original Research Paper Parameters PCB Pentachlorophenol Physicochemical processes Physicochemical properties Polychlorinated biphenyls Polychlorinated dibenzodioxins Polychlorinated dibenzofurans Port of Gdansk Ports profile of the dioxin congeners Sediment Sediments Sodium Surface layers Toxicity Toxicity testing |
title | Polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and pentachlorophenol (PCP) in bottom sediments of the Port of Gdansk |
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