Polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and pentachlorophenol (PCP) in bottom sediments of the Port of Gdansk

Combustion processes are considered to be the main source of the dioxin emission in the Baltic region. Pentachlorophenol (PCP) and its derivatives, pentachlorophenyl laurate (PCPL) and sodium pentachlorophenate (NaPCP) are known as precursors of dioxins. The research was conducted to obtain the firs...

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Veröffentlicht in:Oceanological and hydrobiological studies 2014-09, Vol.43 (3), p.312-323
Hauptverfasser: Lewandowski, Krzysztof, Witt, Maria, Kobusińska, Marta, Niemirycz, Elżbieta
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creator Lewandowski, Krzysztof
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Kobusińska, Marta
Niemirycz, Elżbieta
description Combustion processes are considered to be the main source of the dioxin emission in the Baltic region. Pentachlorophenol (PCP) and its derivatives, pentachlorophenyl laurate (PCPL) and sodium pentachlorophenate (NaPCP) are known as precursors of dioxins. The research was conducted to obtain the first data on the concentration of PCDD/Fs and PCP in the bottom sediments of the Port of Gdansk. Toxicity (the Microtox® test) as well as several sediment parameters have been examined. In the surface layer of bottom sediments from the Port of Gdansk, all congeners of PCDD/Fs have been detected using GC-MS/MS. The highest concentration was obtained for OCDD (224.0–271.0 pg g −1 d.w.) and HpCDD (51.0–36.0 pg g −1 d.w.). The content of ΣPCDDs prevailed over ΣPCDFs. This may indicate that anthropogenic pollution from the land-based thermal sources has the strongest impact on the concentration of dioxins in the port sediments. The concentration of 17 dioxin congeners (WHO-TEQ) did not exceed the probable effect level (PEL) of 21.5 pg TEQ g −1 d.w. The concentration of PCP ranged from bellow the LOD (< 0.85 ng g −1 d.w.) to 12.4 ng g −1 d.w. The positive correlation between toxicity and physico-chemical properties of the analyzed bottom sediments confirms that these parameters are important in terms of environment contamination.
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Pentachlorophenol (PCP) and its derivatives, pentachlorophenyl laurate (PCPL) and sodium pentachlorophenate (NaPCP) are known as precursors of dioxins. The research was conducted to obtain the first data on the concentration of PCDD/Fs and PCP in the bottom sediments of the Port of Gdansk. Toxicity (the Microtox® test) as well as several sediment parameters have been examined. In the surface layer of bottom sediments from the Port of Gdansk, all congeners of PCDD/Fs have been detected using GC-MS/MS. The highest concentration was obtained for OCDD (224.0–271.0 pg g −1 d.w.) and HpCDD (51.0–36.0 pg g −1 d.w.). The content of ΣPCDDs prevailed over ΣPCDFs. This may indicate that anthropogenic pollution from the land-based thermal sources has the strongest impact on the concentration of dioxins in the port sediments. The concentration of 17 dioxin congeners (WHO-TEQ) did not exceed the probable effect level (PEL) of 21.5 pg TEQ g −1 d.w. The concentration of PCP ranged from bellow the LOD (&lt; 0.85 ng g −1 d.w.) to 12.4 ng g −1 d.w. 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subjects Anthropogenic factors
Bottom sediments
Chemical properties
Chemicophysical properties
Chlorinated hydrocarbons
Congeners
Contamination
Dioxins
Earth and Environmental Science
Earth Sciences
Flow velocity
Hazardous materials
Human influences
Land pollution
Marine
Marine & Freshwater Sciences
Microtox
Oceanography
organochlorine contaminants
Original Research Paper
Parameters
PCB
Pentachlorophenol
Physicochemical processes
Physicochemical properties
Polychlorinated biphenyls
Polychlorinated dibenzodioxins
Polychlorinated dibenzofurans
Port of Gdansk
Ports
profile of the dioxin congeners
Sediment
Sediments
Sodium
Surface layers
Toxicity
Toxicity testing
title Polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and pentachlorophenol (PCP) in bottom sediments of the Port of Gdansk
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