Cu(II)-Promoted Methanolysis of N,N‑Bis(2-picolyl)carbamates: Rate-Limiting Metal Ion Delivery of Coordinated Alcoholate Nucleophile Followed by Fast Partitioning of a Tetrahedral Intermediate

Five O-aryl/alkyl N,N-bis(2-picolyl)carbamates were prepared with the O-aryl/alkyl portions being p-nitrophenoxy, m-nitrophenoxy, trifluoroethoxy, methoxy, and isopropoxy (4a,b,c,d,e, respectively) and the kinetics and reaction products of their methanolysis reactions in the presence of Cu(O3SCF3)2...

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Veröffentlicht in:	Journal of organic chemistry 2015-02, Vol.80 (3), p.1357-1364
Hauptverfasser:	Neverov, Alexei A, Cimpean, Luana, Chiykowski, Valerie, Vance, Tyler, Brown, R. Stan
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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