Enhanced charge collection with ultrathin AlOx electron blocking layer for hole-transporting material-free perovskite solar cell

An ultrathin AlOx layer has been deposited onto a CH3NH3PbI3 film using atomic layer deposition technology, to construct a metal-insulator-semiconductor (MIS) back contact for the hole-transporting material-free perovskite solar cell. By optimization of the ALD deposition cycles, the average power c...

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Veröffentlicht in:Physical chemistry chemical physics : PCCP 2015-02, Vol.17 (7), p.4937-4944
Hauptverfasser: Wei, Huiyun, Shi, Jiangjian, Xu, Xin, Xiao, Junyan, Luo, Jianheng, Dong, Juan, Lv, Songtao, Zhu, Lifeng, Wu, Huijue, Li, Dongmei, Luo, Yanhong, Meng, Qingbo, Chen, Qiang
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container_issue 7
container_start_page 4937
container_title Physical chemistry chemical physics : PCCP
container_volume 17
creator Wei, Huiyun
Shi, Jiangjian
Xu, Xin
Xiao, Junyan
Luo, Jianheng
Dong, Juan
Lv, Songtao
Zhu, Lifeng
Wu, Huijue
Li, Dongmei
Luo, Yanhong
Meng, Qingbo
Chen, Qiang
description An ultrathin AlOx layer has been deposited onto a CH3NH3PbI3 film using atomic layer deposition technology, to construct a metal-insulator-semiconductor (MIS) back contact for the hole-transporting material-free perovskite solar cell. By optimization of the ALD deposition cycles, the average power conversion efficiency (PCE) of the cell has been enhanced from 8.61% to 10.07% with a highest PCE of 11.10%. It is revealed that the improvement in cell performance with this MIS back contact is mainly attributed to the enhancement in charge collection resulting from the electron blocking effect of the AlOx layer.
doi_str_mv 10.1039/c4cp04902k
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title Enhanced charge collection with ultrathin AlOx electron blocking layer for hole-transporting material-free perovskite solar cell
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