Enantiospecific cis–trans Isomerization in Chiral Fulleropyrrolidines: Hydrogen-Bonding Assistance in the Carbanion Stabilization in H2O@C60

The stereochemical outcome of cis–trans isomerization of optically pure [60], [70], and endohedral H2O@C60 fulleropyrrolidines reveals that the electronic nature of substituents, fullerene size, and surprisingly the incarcerated water molecule plays a crucial role in this rearrangement process. Theo...

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Veröffentlicht in:	Journal of the American Chemical Society 2015-01, Vol.137 (3), p.1190-1197
Hauptverfasser:	Maroto, Enrique E, Mateos, Jaime, Garcia-Borràs, Marc, Osuna, Sílvia, Filippone, Salvatore, Herranz, María Ángeles, Murata, Yasujiro, Solà, Miquel, Martín, Nazario
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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