How Does Tunneling Contribute to Counterintuitive H-Abstraction Reactivity of Nonheme Fe(IV)O Oxidants with Alkanes?

This article addresses the intriguing hydrogen-abstraction (H-abstraction) and oxygen-transfer (O-transfer) reactivity of a series of nonheme [FeIV(O)(TMC)(Lax)]z+ complexes, with a tetramethyl cyclam ligand and a variable axial ligand (Lax), toward three substrates: 1,4-cyclohexadiene, 9,10-dihydro...

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Veröffentlicht in:	Journal of the American Chemical Society 2015-01, Vol.137 (2), p.722-733
Hauptverfasser:	Mandal, Debasish, Ramanan, Rajeev, Usharani, Dandamudi, Janardanan, Deepa, Wang, Binju, Shaik, Sason
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkanes - chemistry Hydrogen - chemistry Iron - chemistry Kinetics Models, Molecular Molecular Conformation Oxidants Oxygen - chemistry Quantum Theory
Online-Zugang:	Volltext
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