Novel conducting nanocomposite based on polypyrrole and modified poly(styrene-alt-maleic anhydride) via emulsion polymerization: Synthesis, Characterization, Antioxidant, and heavy metal sorbent activity
Novel polypyrrole/modified poly(styrene‐alt‐maleic anhydride) conducting nanocomposites were prepared via emulsion polymerization using sodium dodecyl sulfate as an emulsifier and ammonium persulfate as an oxidant. Modified poly(styrene‐alt‐maleic anhydride) was used as an external dopant for conduc...
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Veröffentlicht in: | Polymer composites 2015-01, Vol.36 (1), p.138-144 |
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creator | Nazarzadeh Zare, Ehsan Mansour Lakouraj, Moslem Najafi Moghadam, Peyman Hasanzadeh, Reza |
description | Novel polypyrrole/modified poly(styrene‐alt‐maleic anhydride) conducting nanocomposites were prepared via emulsion polymerization using sodium dodecyl sulfate as an emulsifier and ammonium persulfate as an oxidant. Modified poly(styrene‐alt‐maleic anhydride) was used as an external dopant for conductivity enhancement of polypyrrole. The conductivity of nanocomposites was measured with a four‐probe method. The maximum electrical conductivity of the nanocomposite was 1.40 S/cm. The data from this research showed that the novel nanocomposite presents good tendency for the removal of heavy metal ions from aqueous solutions. Also the prepared nanocomposites were analyzed for their antioxidant activity using 2,2‐diphenyl‐1‐picrylhydrazyl assay. The results showed that the antioxidant activity of the nanocomposite was 60%. The nanocomposites were characterized by Fourier transform infrared, ultraviolet–visible, X‐ray diffraction, field emission scanning electron microscopy, and differential scanning calorimetry measurements. POLYM. COMPOS., 36:138–144, 2015. © 2014 Society of Plastics Engineers |
doi_str_mv | 10.1002/pc.22922 |
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Modified poly(styrene‐alt‐maleic anhydride) was used as an external dopant for conductivity enhancement of polypyrrole. The conductivity of nanocomposites was measured with a four‐probe method. The maximum electrical conductivity of the nanocomposite was 1.40 S/cm. The data from this research showed that the novel nanocomposite presents good tendency for the removal of heavy metal ions from aqueous solutions. Also the prepared nanocomposites were analyzed for their antioxidant activity using 2,2‐diphenyl‐1‐picrylhydrazyl assay. The results showed that the antioxidant activity of the nanocomposite was 60%. The nanocomposites were characterized by Fourier transform infrared, ultraviolet–visible, X‐ray diffraction, field emission scanning electron microscopy, and differential scanning calorimetry measurements. POLYM. 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Compos</addtitle><description>Novel polypyrrole/modified poly(styrene‐alt‐maleic anhydride) conducting nanocomposites were prepared via emulsion polymerization using sodium dodecyl sulfate as an emulsifier and ammonium persulfate as an oxidant. Modified poly(styrene‐alt‐maleic anhydride) was used as an external dopant for conductivity enhancement of polypyrrole. The conductivity of nanocomposites was measured with a four‐probe method. The maximum electrical conductivity of the nanocomposite was 1.40 S/cm. The data from this research showed that the novel nanocomposite presents good tendency for the removal of heavy metal ions from aqueous solutions. Also the prepared nanocomposites were analyzed for their antioxidant activity using 2,2‐diphenyl‐1‐picrylhydrazyl assay. The results showed that the antioxidant activity of the nanocomposite was 60%. The nanocomposites were characterized by Fourier transform infrared, ultraviolet–visible, X‐ray diffraction, field emission scanning electron microscopy, and differential scanning calorimetry measurements. POLYM. COMPOS., 36:138–144, 2015. © 2014 Society of Plastics Engineers</description><subject>Anhydrides</subject><subject>Antioxidants</subject><subject>Conducting polymers</subject><subject>Emulsion polymerization</subject><subject>Nanostructure</subject><subject>Polypyrroles</subject><subject>Polystyrene resins</subject><subject>Resistivity</subject><issn>0272-8397</issn><issn>1548-0569</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp10d9qFDEUBvBBFFyr4CMEvKmwU5PMJpl41y66FcsqWBG8CZnMGTc1k0yTzNrxFX0pp3-oUPDqEL5fvgROUbwk-IhgTN8M5ohSSemjYkHYqi4x4_JxscBU0LKupHhaPEvpYpaE82pR_NmGPThkgm9Hk63_gbz2wYR-CMlmQI1O0KLg0RDcNEwxBgdI-xb1obWdnbPr4DDlKYKHUrtc9tqBNTPaTW20LbxGe6sR9KNL9q6oh2h_6zwf36Ivk887SDYt0Xqnozb5PlyiYz_PK9tqn5c3z-5A7yfUQ9YOpRAb8BnNV-ze5ul58aTTLsGLu3lQfH3_7nx9Wp592nxYH5-VZiUILQXpoBOiY4xKKRpMuJGUE94RzIDirpNa1KyptW7lqqJacMm0pKSRom5qjquD4vC2d4jhcoSUVW-TAee0hzAmRTgjK0aY5DN99YBehDH6-XezqljFMK2rf4UmhpQidGqIttdxUgSr662qwaibrc60vKW_rIPpv059Xj_wNmW4uvc6_lRcVIKpb9uN-riVJ6ffz0_UpvoLKFq2ng</recordid><startdate>201501</startdate><enddate>201501</enddate><creator>Nazarzadeh Zare, Ehsan</creator><creator>Mansour Lakouraj, Moslem</creator><creator>Najafi Moghadam, Peyman</creator><creator>Hasanzadeh, Reza</creator><general>Blackwell Publishing Ltd</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>7SP</scope><scope>7U5</scope><scope>L7M</scope></search><sort><creationdate>201501</creationdate><title>Novel conducting nanocomposite based on polypyrrole and modified poly(styrene-alt-maleic anhydride) via emulsion polymerization: Synthesis, Characterization, Antioxidant, and heavy metal sorbent activity</title><author>Nazarzadeh Zare, Ehsan ; Mansour Lakouraj, Moslem ; Najafi Moghadam, Peyman ; Hasanzadeh, Reza</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4712-71fef77f552997b016c92616f105e20ff9a785b8aad9432a7695a921b978b8603</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Anhydrides</topic><topic>Antioxidants</topic><topic>Conducting polymers</topic><topic>Emulsion polymerization</topic><topic>Nanostructure</topic><topic>Polypyrroles</topic><topic>Polystyrene resins</topic><topic>Resistivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nazarzadeh Zare, Ehsan</creatorcontrib><creatorcontrib>Mansour Lakouraj, Moslem</creatorcontrib><creatorcontrib>Najafi Moghadam, Peyman</creatorcontrib><creatorcontrib>Hasanzadeh, Reza</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Polymer composites</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nazarzadeh Zare, Ehsan</au><au>Mansour Lakouraj, Moslem</au><au>Najafi Moghadam, Peyman</au><au>Hasanzadeh, Reza</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel conducting nanocomposite based on polypyrrole and modified poly(styrene-alt-maleic anhydride) via emulsion polymerization: Synthesis, Characterization, Antioxidant, and heavy metal sorbent activity</atitle><jtitle>Polymer composites</jtitle><addtitle>Polym. Compos</addtitle><date>2015-01</date><risdate>2015</risdate><volume>36</volume><issue>1</issue><spage>138</spage><epage>144</epage><pages>138-144</pages><issn>0272-8397</issn><eissn>1548-0569</eissn><coden>PCOMDI</coden><abstract>Novel polypyrrole/modified poly(styrene‐alt‐maleic anhydride) conducting nanocomposites were prepared via emulsion polymerization using sodium dodecyl sulfate as an emulsifier and ammonium persulfate as an oxidant. Modified poly(styrene‐alt‐maleic anhydride) was used as an external dopant for conductivity enhancement of polypyrrole. The conductivity of nanocomposites was measured with a four‐probe method. The maximum electrical conductivity of the nanocomposite was 1.40 S/cm. The data from this research showed that the novel nanocomposite presents good tendency for the removal of heavy metal ions from aqueous solutions. Also the prepared nanocomposites were analyzed for their antioxidant activity using 2,2‐diphenyl‐1‐picrylhydrazyl assay. The results showed that the antioxidant activity of the nanocomposite was 60%. The nanocomposites were characterized by Fourier transform infrared, ultraviolet–visible, X‐ray diffraction, field emission scanning electron microscopy, and differential scanning calorimetry measurements. POLYM. COMPOS., 36:138–144, 2015. © 2014 Society of Plastics Engineers</abstract><cop>Newtown</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/pc.22922</doi><tpages>7</tpages></addata></record> |
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subjects | Anhydrides Antioxidants Conducting polymers Emulsion polymerization Nanostructure Polypyrroles Polystyrene resins Resistivity |
title | Novel conducting nanocomposite based on polypyrrole and modified poly(styrene-alt-maleic anhydride) via emulsion polymerization: Synthesis, Characterization, Antioxidant, and heavy metal sorbent activity |
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