Reaction-induced swelling of ionic gels
A chemomechanical theory is proposed to describe the dynamic behavior and response time of ionic gels. The large deformation of these gels accompanied by the migration of mobile ions is driven by a common non-equilibrium chemical reaction. The theoretical model was validated using existing experimen...
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| Veröffentlicht in: | Soft matter 2015-01, Vol.11 (3), p.449-455 |
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| container_title | Soft matter |
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| creator | Liu, ShaoBao Wang, PengFei Huang, GuoYou Wang, Lin Zhou, JinXiong Lu, Tian Jian Xu, Feng Lin, Min |
| description | A chemomechanical theory is proposed to describe the dynamic behavior and response time of ionic gels. The large deformation of these gels accompanied by the migration of mobile ions is driven by a common non-equilibrium chemical reaction. The theoretical model was validated using existing experimental data. Further investigations showed that the dynamic deformation and response time of an ionic gel are dependent on the concentration of reactive and non-reactive ions, the time of exposure to external stimuli, the initial state and the density of ionizable groups on the polymer chains. |
| doi_str_mv | 10.1039/c4sm02252a |
| format | Article |
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The large deformation of these gels accompanied by the migration of mobile ions is driven by a common non-equilibrium chemical reaction. The theoretical model was validated using existing experimental data. Further investigations showed that the dynamic deformation and response time of an ionic gel are dependent on the concentration of reactive and non-reactive ions, the time of exposure to external stimuli, the initial state and the density of ionizable groups on the polymer chains.</description><identifier>ISSN: 1744-683X</identifier><identifier>EISSN: 1744-6848</identifier><identifier>DOI: 10.1039/c4sm02252a</identifier><identifier>PMID: 25409653</identifier><language>eng</language><publisher>England</publisher><subject>Deformation ; Density ; Dynamics ; Gels ; Mathematical models ; Migration ; Response time ; Swelling</subject><ispartof>Soft matter, 2015-01, Vol.11 (3), p.449-455</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-b092ca030f152d4003c7d437e042a738dabe1b4bfb0763ac970bbe0c7f32696b3</citedby><cites>FETCH-LOGICAL-c386t-b092ca030f152d4003c7d437e042a738dabe1b4bfb0763ac970bbe0c7f32696b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25409653$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, ShaoBao</creatorcontrib><creatorcontrib>Wang, PengFei</creatorcontrib><creatorcontrib>Huang, GuoYou</creatorcontrib><creatorcontrib>Wang, Lin</creatorcontrib><creatorcontrib>Zhou, JinXiong</creatorcontrib><creatorcontrib>Lu, Tian Jian</creatorcontrib><creatorcontrib>Xu, Feng</creatorcontrib><creatorcontrib>Lin, Min</creatorcontrib><title>Reaction-induced swelling of ionic gels</title><title>Soft matter</title><addtitle>Soft Matter</addtitle><description>A chemomechanical theory is proposed to describe the dynamic behavior and response time of ionic gels. The large deformation of these gels accompanied by the migration of mobile ions is driven by a common non-equilibrium chemical reaction. The theoretical model was validated using existing experimental data. Further investigations showed that the dynamic deformation and response time of an ionic gel are dependent on the concentration of reactive and non-reactive ions, the time of exposure to external stimuli, the initial state and the density of ionizable groups on the polymer chains.</description><subject>Deformation</subject><subject>Density</subject><subject>Dynamics</subject><subject>Gels</subject><subject>Mathematical models</subject><subject>Migration</subject><subject>Response time</subject><subject>Swelling</subject><issn>1744-683X</issn><issn>1744-6848</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqNkNtKw0AQhhdRbK3e-ACSO0WIzu7sIXtZQj1ARfAA3oXdzaZEcqjZBPHtjbb22qv5GT7-GT5CTilcUUB97XiogTHBzB6ZUsV5LBOe7O8yvk3IUQjvAJhwKg_JhAkOWgqckvMnb1xftk1cNvngfB6FT19VZbOK2iIa96WLVr4Kx-SgMFXwJ9s5I683i5f0Ll4-3t6n82XsMJF9bEEzZwChoILlfLzoVM5ReeDMKExyYz213BYWlETjtAJrPThVIJNaWpyRi03vums_Bh_6rC6DGz8yjW-HkFEpKMexl_0DRaW1oJiM6OUGdV0bQueLbN2Vtem-MgrZj8Ms5c8Pvw7nI3y27R1s7fMd-icNvwEEdmod</recordid><startdate>20150121</startdate><enddate>20150121</enddate><creator>Liu, ShaoBao</creator><creator>Wang, PengFei</creator><creator>Huang, GuoYou</creator><creator>Wang, Lin</creator><creator>Zhou, JinXiong</creator><creator>Lu, Tian Jian</creator><creator>Xu, Feng</creator><creator>Lin, Min</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20150121</creationdate><title>Reaction-induced swelling of ionic gels</title><author>Liu, ShaoBao ; Wang, PengFei ; Huang, GuoYou ; Wang, Lin ; Zhou, JinXiong ; Lu, Tian Jian ; Xu, Feng ; Lin, Min</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-b092ca030f152d4003c7d437e042a738dabe1b4bfb0763ac970bbe0c7f32696b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Deformation</topic><topic>Density</topic><topic>Dynamics</topic><topic>Gels</topic><topic>Mathematical models</topic><topic>Migration</topic><topic>Response time</topic><topic>Swelling</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, ShaoBao</creatorcontrib><creatorcontrib>Wang, PengFei</creatorcontrib><creatorcontrib>Huang, GuoYou</creatorcontrib><creatorcontrib>Wang, Lin</creatorcontrib><creatorcontrib>Zhou, JinXiong</creatorcontrib><creatorcontrib>Lu, Tian Jian</creatorcontrib><creatorcontrib>Xu, Feng</creatorcontrib><creatorcontrib>Lin, Min</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Soft matter</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, ShaoBao</au><au>Wang, PengFei</au><au>Huang, GuoYou</au><au>Wang, Lin</au><au>Zhou, JinXiong</au><au>Lu, Tian Jian</au><au>Xu, Feng</au><au>Lin, Min</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reaction-induced swelling of ionic gels</atitle><jtitle>Soft matter</jtitle><addtitle>Soft Matter</addtitle><date>2015-01-21</date><risdate>2015</risdate><volume>11</volume><issue>3</issue><spage>449</spage><epage>455</epage><pages>449-455</pages><issn>1744-683X</issn><eissn>1744-6848</eissn><abstract>A chemomechanical theory is proposed to describe the dynamic behavior and response time of ionic gels. The large deformation of these gels accompanied by the migration of mobile ions is driven by a common non-equilibrium chemical reaction. The theoretical model was validated using existing experimental data. Further investigations showed that the dynamic deformation and response time of an ionic gel are dependent on the concentration of reactive and non-reactive ions, the time of exposure to external stimuli, the initial state and the density of ionizable groups on the polymer chains.</abstract><cop>England</cop><pmid>25409653</pmid><doi>10.1039/c4sm02252a</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1744-683X |
| ispartof | Soft matter, 2015-01, Vol.11 (3), p.449-455 |
| issn | 1744-683X 1744-6848 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1651430032 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Deformation Density Dynamics Gels Mathematical models Migration Response time Swelling |
| title | Reaction-induced swelling of ionic gels |
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