Tuning the phase transition of ZnO thin films through lithography: an integrated bottom-up and top-down processing
An innovative approach towards the physico‐chemical tailoring of zinc oxide thin films is reported. The films have been deposited by liquid phase using the sol–gel method and then exposed to hard X‐rays, provided by a synchrotron storage ring, for lithography. The use of surfactant and chelating age...
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Veröffentlicht in: | Journal of synchrotron radiation 2015-01, Vol.22 (1), p.165-171 |
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creator | Malfatti, Luca Pinna, Alessandra Enzo, Stefano Falcaro, Paolo Marmiroli, Benedetta Innocenzi, Plinio |
description | An innovative approach towards the physico‐chemical tailoring of zinc oxide thin films is reported. The films have been deposited by liquid phase using the sol–gel method and then exposed to hard X‐rays, provided by a synchrotron storage ring, for lithography. The use of surfactant and chelating agents in the sol allows easy‐to‐pattern films made by an organic–inorganic matrix to be deposited. The exposure to hard X‐rays strongly affects the nucleation and growth of crystalline ZnO, triggering the formation of two intermediate phases before obtaining a wurtzite‐like structure. At the same time, X‐ray lithography allows for a fast patterning of the coatings enabling microfabrication for sensing and arrays technology. |
doi_str_mv | 10.1107/S1600577514024047 |
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subjects | Arrays bottom-up/top-down Deposition Exposure Lithography sol-gel thin film Thin films Tuning X-rays Zinc oxide Zinc oxides |
title | Tuning the phase transition of ZnO thin films through lithography: an integrated bottom-up and top-down processing |
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