X-ray irradiation induces local rearrangement of silica particles in swollen rubber

X‐ray photon correlation spectroscopy (XPCS) of swollen rubber containing spherical silica nanoparticles is reported. It is shown that irradiation by intense X‐rays leads to the breakdown of cross‐links, thereby inducing the local rearrangement of silica nanoparticles. This rearrangement process dep...

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Veröffentlicht in:Journal of synchrotron radiation 2015-01, Vol.22 (1), p.119-123
Hauptverfasser: Shinohara, Yuya, Yamamoto, Naoko, Kishimoto, Hiroyuki, Amemiya, Yoshiyuki
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creator Shinohara, Yuya
Yamamoto, Naoko
Kishimoto, Hiroyuki
Amemiya, Yoshiyuki
description X‐ray photon correlation spectroscopy (XPCS) of swollen rubber containing spherical silica nanoparticles is reported. It is shown that irradiation by intense X‐rays leads to the breakdown of cross‐links, thereby inducing the local rearrangement of silica nanoparticles. This rearrangement process depends on the cross‐link density and is characterized by a compressed exponential relaxation with aging behaviour, which resembles a common feature of complex fluids observed with XPCS.
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source Wiley-Blackwell Open Access Titles
subjects Atoms & subatomic particles
Crosslinking
Density
filled rubber
Irradiation
Nanoparticles
Rubber
Silicon dioxide
Synchrotron radiation
X-ray photon correlation spectroscopy
X-rays
title X-ray irradiation induces local rearrangement of silica particles in swollen rubber
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