X-ray irradiation induces local rearrangement of silica particles in swollen rubber
X‐ray photon correlation spectroscopy (XPCS) of swollen rubber containing spherical silica nanoparticles is reported. It is shown that irradiation by intense X‐rays leads to the breakdown of cross‐links, thereby inducing the local rearrangement of silica nanoparticles. This rearrangement process dep...
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Veröffentlicht in: | Journal of synchrotron radiation 2015-01, Vol.22 (1), p.119-123 |
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creator | Shinohara, Yuya Yamamoto, Naoko Kishimoto, Hiroyuki Amemiya, Yoshiyuki |
description | X‐ray photon correlation spectroscopy (XPCS) of swollen rubber containing spherical silica nanoparticles is reported. It is shown that irradiation by intense X‐rays leads to the breakdown of cross‐links, thereby inducing the local rearrangement of silica nanoparticles. This rearrangement process depends on the cross‐link density and is characterized by a compressed exponential relaxation with aging behaviour, which resembles a common feature of complex fluids observed with XPCS. |
doi_str_mv | 10.1107/S1600577514022954 |
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It is shown that irradiation by intense X‐rays leads to the breakdown of cross‐links, thereby inducing the local rearrangement of silica nanoparticles. 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This rearrangement process depends on the cross‐link density and is characterized by a compressed exponential relaxation with aging behaviour, which resembles a common feature of complex fluids observed with XPCS.</description><subject>Atoms & subatomic particles</subject><subject>Crosslinking</subject><subject>Density</subject><subject>filled rubber</subject><subject>Irradiation</subject><subject>Nanoparticles</subject><subject>Rubber</subject><subject>Silicon dioxide</subject><subject>Synchrotron radiation</subject><subject>X-ray photon correlation spectroscopy</subject><subject>X-rays</subject><issn>1600-5775</issn><issn>0909-0495</issn><issn>1600-5775</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqNkctO3DAUhi0E4tY-AJsqEhs2Kb7E8XgJIxhACESHXlhZdnJcmXqSwU4E8zY8S58MTwMIlUW7snX8_Z9l_wjtEPyZECz2p6TEmAvBSYEplbxYQZvLUb6crb7Zb6CtGG8xJqWgbB1tUM6Z4FJsousfedCLzIWga6c71zaZa-q-gpj5ttI-C6DTWfMTZtB0WWt_P0bnXaWzuQ6dq3wCXZPF-9Z7aLLQGwPhA1qz2kf4-Lxuo6_HR9fjk_z8cnI6PjjPK85lkYMYSaNLWlhbm1qImuFCcEqsxZxQxqwAY2FEMAUzspUkxDKMDRG0HmkJhm2jvcE7D-1dD7FTMxcr8F430PZRkTL9DBGYl_-BFulyKUqa0N2_0Nu2D016yEAVrPxDkYGqQhtjAKvmwc10WCiC1bId9a6dlPn0bO7NDOrXxEsdCZADcO88LP5tVGfTGzo55Jgu5fmQdbGDh9esDr9UKZJefb-YqDH9IqdXV1x9Y0-tzKlW</recordid><startdate>20150101</startdate><enddate>20150101</enddate><creator>Shinohara, Yuya</creator><creator>Yamamoto, Naoko</creator><creator>Kishimoto, Hiroyuki</creator><creator>Amemiya, Yoshiyuki</creator><general>International Union of Crystallography</general><general>John Wiley & Sons, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>JQ2</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20150101</creationdate><title>X-ray irradiation induces local rearrangement of silica particles in swollen rubber</title><author>Shinohara, Yuya ; Yamamoto, Naoko ; Kishimoto, Hiroyuki ; Amemiya, Yoshiyuki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5594-e789ba624ffdbd77d3047521ff051233f7ebfe8102eb8fc911f300b172d8a9eb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Atoms & subatomic particles</topic><topic>Crosslinking</topic><topic>Density</topic><topic>filled rubber</topic><topic>Irradiation</topic><topic>Nanoparticles</topic><topic>Rubber</topic><topic>Silicon dioxide</topic><topic>Synchrotron radiation</topic><topic>X-ray photon correlation spectroscopy</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shinohara, Yuya</creatorcontrib><creatorcontrib>Yamamoto, Naoko</creatorcontrib><creatorcontrib>Kishimoto, Hiroyuki</creatorcontrib><creatorcontrib>Amemiya, Yoshiyuki</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of synchrotron radiation</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Shinohara, Yuya</au><au>Yamamoto, Naoko</au><au>Kishimoto, Hiroyuki</au><au>Amemiya, Yoshiyuki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>X-ray irradiation induces local rearrangement of silica particles in swollen rubber</atitle><jtitle>Journal of synchrotron radiation</jtitle><addtitle>Jnl of Synchrotron Radiation</addtitle><date>2015-01-01</date><risdate>2015</risdate><volume>22</volume><issue>1</issue><spage>119</spage><epage>123</epage><pages>119-123</pages><issn>1600-5775</issn><issn>0909-0495</issn><eissn>1600-5775</eissn><abstract>X‐ray photon correlation spectroscopy (XPCS) of swollen rubber containing spherical silica nanoparticles is reported. It is shown that irradiation by intense X‐rays leads to the breakdown of cross‐links, thereby inducing the local rearrangement of silica nanoparticles. This rearrangement process depends on the cross‐link density and is characterized by a compressed exponential relaxation with aging behaviour, which resembles a common feature of complex fluids observed with XPCS.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>International Union of Crystallography</pub><pmid>25537597</pmid><doi>10.1107/S1600577514022954</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Atoms & subatomic particles Crosslinking Density filled rubber Irradiation Nanoparticles Rubber Silicon dioxide Synchrotron radiation X-ray photon correlation spectroscopy X-rays |
title | X-ray irradiation induces local rearrangement of silica particles in swollen rubber |
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