TOF-SIMS analysis of lithium air battery discharge products utilizing gas cluster ion beam sputtering for surface stabilization
TOF‐SIMS investigation on various lithium reference materials has been carried out for the characterization of reaction products on electrodes of lithium air batteries (LAB). In conjunction with argon gas cluster ion beam (GCIB) sputtering which can stabilize the surface of lithium compounds effecti...
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| Veröffentlicht in: | Surface and interface analysis 2014-11, Vol.46 (S1), p.344-347 |
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| creator | Karen, Akiya Ito, Kimihiko Kubo, Yoshimi |
| description | TOF‐SIMS investigation on various lithium reference materials has been carried out for the characterization of reaction products on electrodes of lithium air batteries (LAB). In conjunction with argon gas cluster ion beam (GCIB) sputtering which can stabilize the surface of lithium compounds effectively, characteristic secondary ion species have been found for identification and differentiation among them. On the surface of real discharged carbon cathodes of LAB, lithium peroxide and related products were recognized under coexistence of electrolyte components and confirmed by the experiment using 18O2 as reaction gas in the discharging process. Copyright © 2014 John Wiley & Sons, Ltd. |
| doi_str_mv | 10.1002/sia.5508 |
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Copyright © 2014 John Wiley & Sons, Ltd.</description><subject>Air batteries</subject><subject>Carbon</subject><subject>Clusters</subject><subject>Discharge</subject><subject>Electrodes</subject><subject>gas cluster ion beam (GCIB)</subject><subject>Ion beam sputtering</subject><subject>Lithium</subject><subject>lithium battery</subject><subject>Stabilization</subject><subject>TOF-SIMS</subject><issn>0142-2421</issn><issn>1096-9918</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp10cFuEzEQBmALFalpqcQjWOLCZYvttXftY1VIG6nQQ0orcbFmHTt12WSDZ60SLrw6XrUCgcTJh_lmNJ6fkNecnXLGxDuMcKoU0y_IjDPTVMZwfUBmjEtRCSn4ITlCfGCM6Vo3M_Lz5npeLRcflxS20O8xIh0C7eN4H_OGQky0g3H0aU9XEd09pLWnuzSsshuR5jH28UfcrukakLo-Y5E0DlvaedhQ3OWpdaqHIVHMKYDzFEfopj4Yi3xFXgbo0Z88v8fk8_zDzflldXV9sTg_u6qcklxXAZjuWm28axhvHW-1hmBAGWmkEFAbpVdgRM2M0UK7VsiOC8-VCC7othP1MXn7NLcs_y17HO2m_Mf3PWz9kNHyRnHJaqaaQt_8Qx-GnMp1JiXappZS6D8DXRoQkw92l-IG0t5yZqckbEnCTkkUWj3Rx9j7_X-dXS7O_vax3PP7bw_pq23aulX27tOFlbfN-y-Xd9yy-hdt4Jlq</recordid><startdate>201411</startdate><enddate>201411</enddate><creator>Karen, Akiya</creator><creator>Ito, Kimihiko</creator><creator>Kubo, Yoshimi</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7TB</scope><scope>FR3</scope></search><sort><creationdate>201411</creationdate><title>TOF-SIMS analysis of lithium air battery discharge products utilizing gas cluster ion beam sputtering for surface stabilization</title><author>Karen, Akiya ; Ito, Kimihiko ; Kubo, Yoshimi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5418-fa08b789ec6017c1788af9a5949422a3958da923099828c724b12e152fcf87b23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Air batteries</topic><topic>Carbon</topic><topic>Clusters</topic><topic>Discharge</topic><topic>Electrodes</topic><topic>gas cluster ion beam (GCIB)</topic><topic>Ion beam sputtering</topic><topic>Lithium</topic><topic>lithium battery</topic><topic>Stabilization</topic><topic>TOF-SIMS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Karen, Akiya</creatorcontrib><creatorcontrib>Ito, Kimihiko</creatorcontrib><creatorcontrib>Kubo, Yoshimi</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Engineering Research Database</collection><jtitle>Surface and interface analysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Karen, Akiya</au><au>Ito, Kimihiko</au><au>Kubo, Yoshimi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>TOF-SIMS analysis of lithium air battery discharge products utilizing gas cluster ion beam sputtering for surface stabilization</atitle><jtitle>Surface and interface analysis</jtitle><addtitle>Surf. Interface Anal</addtitle><date>2014-11</date><risdate>2014</risdate><volume>46</volume><issue>S1</issue><spage>344</spage><epage>347</epage><pages>344-347</pages><issn>0142-2421</issn><eissn>1096-9918</eissn><coden>SIANDQ</coden><abstract>TOF‐SIMS investigation on various lithium reference materials has been carried out for the characterization of reaction products on electrodes of lithium air batteries (LAB). In conjunction with argon gas cluster ion beam (GCIB) sputtering which can stabilize the surface of lithium compounds effectively, characteristic secondary ion species have been found for identification and differentiation among them. On the surface of real discharged carbon cathodes of LAB, lithium peroxide and related products were recognized under coexistence of electrolyte components and confirmed by the experiment using 18O2 as reaction gas in the discharging process. 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| ispartof | Surface and interface analysis, 2014-11, Vol.46 (S1), p.344-347 |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Air batteries Carbon Clusters Discharge Electrodes gas cluster ion beam (GCIB) Ion beam sputtering Lithium lithium battery Stabilization TOF-SIMS |
| title | TOF-SIMS analysis of lithium air battery discharge products utilizing gas cluster ion beam sputtering for surface stabilization |
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