High-performance planar heterojunction perovskite solar cells: Preserving long charge carrier diffusion lengths and interfacial engineering
We demonstrate that charge carrier diffusion lengths of two classes of perovskites, CH 3 NH 3 PbI 3− x Cl x and CH 3 NH 3 PbI 3 , are both highly sensitive to film processing conditions and optimal processing procedures are critical to preserving the long carrier diffusion lengths of the perovskite...
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| Veröffentlicht in: | Nano research 2014-12, Vol.7 (12), p.1749-1758 |
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| container_title | Nano research |
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| creator | Bai, Sai Wu, Zhongwei Wu, Xiaojing Jin, Yizheng Zhao, Ni Chen, Zhihui Mei, Qingqing Wang, Xin Ye, Zhizhen Song, Tao Liu, Ruiyuan Lee, Shuit-tong Sun, Baoquan |
| description | We demonstrate that charge carrier diffusion lengths of two classes of perovskites, CH
3
NH
3
PbI
3−
x
Cl
x
and CH
3
NH
3
PbI
3
, are both highly sensitive to film processing conditions and optimal processing procedures are critical to preserving the long carrier diffusion lengths of the perovskite films. This understanding, together with the improved cathode interface using bilayer-structured electron transporting interlayers of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM)/ZnO, leads to the successful fabrication of highly efficient, stable and reproducible planar heterojunction CH
3
NH
3
PbI
3−
x
Cl
x
solar cells with impressive power-conversion efficiencies (PCEs) up to 15.9%. A 1-square-centimeter device yielding a PCE of 12.3% has been realized, demonstrating that this simple planar structure is promising for large-area devices. |
| doi_str_mv | 10.1007/s12274-014-0534-8 |
| format | Article |
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3
NH
3
PbI
3−
x
Cl
x
and CH
3
NH
3
PbI
3
, are both highly sensitive to film processing conditions and optimal processing procedures are critical to preserving the long carrier diffusion lengths of the perovskite films. This understanding, together with the improved cathode interface using bilayer-structured electron transporting interlayers of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM)/ZnO, leads to the successful fabrication of highly efficient, stable and reproducible planar heterojunction CH
3
NH
3
PbI
3−
x
Cl
x
solar cells with impressive power-conversion efficiencies (PCEs) up to 15.9%. A 1-square-centimeter device yielding a PCE of 12.3% has been realized, demonstrating that this simple planar structure is promising for large-area devices.</description><identifier>ISSN: 1998-0124</identifier><identifier>EISSN: 1998-0000</identifier><identifier>DOI: 10.1007/s12274-014-0534-8</identifier><language>eng</language><publisher>Heidelberg: Tsinghua University Press</publisher><subject>Annealing ; Atomic/Molecular Structure and Spectra ; Biomedicine ; Biotechnology ; Charge carriers ; Chemistry and Materials Science ; Condensed Matter Physics ; Devices ; Diffusion length ; Engineering ; Fabrication ; Glass substrates ; Heterojunctions ; Materials Science ; Nanocrystals ; Nanotechnology ; Perovskites ; Photovoltaic cells ; Preserving ; Quantum dots ; Research Article ; Solar cells ; Temperature effects</subject><ispartof>Nano research, 2014-12, Vol.7 (12), p.1749-1758</ispartof><rights>Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c555t-146671bf671bf84065569f04e82e0e1142c86623fca6d906c6458f2e8569e86c3</citedby><cites>FETCH-LOGICAL-c555t-146671bf671bf84065569f04e82e0e1142c86623fca6d906c6458f2e8569e86c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12274-014-0534-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12274-014-0534-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Bai, Sai</creatorcontrib><creatorcontrib>Wu, Zhongwei</creatorcontrib><creatorcontrib>Wu, Xiaojing</creatorcontrib><creatorcontrib>Jin, Yizheng</creatorcontrib><creatorcontrib>Zhao, Ni</creatorcontrib><creatorcontrib>Chen, Zhihui</creatorcontrib><creatorcontrib>Mei, Qingqing</creatorcontrib><creatorcontrib>Wang, Xin</creatorcontrib><creatorcontrib>Ye, Zhizhen</creatorcontrib><creatorcontrib>Song, Tao</creatorcontrib><creatorcontrib>Liu, Ruiyuan</creatorcontrib><creatorcontrib>Lee, Shuit-tong</creatorcontrib><creatorcontrib>Sun, Baoquan</creatorcontrib><title>High-performance planar heterojunction perovskite solar cells: Preserving long charge carrier diffusion lengths and interfacial engineering</title><title>Nano research</title><addtitle>Nano Res</addtitle><description>We demonstrate that charge carrier diffusion lengths of two classes of perovskites, CH
3
NH
3
PbI
3−
x
Cl
x
and CH
3
NH
3
PbI
3
, are both highly sensitive to film processing conditions and optimal processing procedures are critical to preserving the long carrier diffusion lengths of the perovskite films. This understanding, together with the improved cathode interface using bilayer-structured electron transporting interlayers of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM)/ZnO, leads to the successful fabrication of highly efficient, stable and reproducible planar heterojunction CH
3
NH
3
PbI
3−
x
Cl
x
solar cells with impressive power-conversion efficiencies (PCEs) up to 15.9%. A 1-square-centimeter device yielding a PCE of 12.3% has been realized, demonstrating that this simple planar structure is promising for large-area devices.</description><subject>Annealing</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Biomedicine</subject><subject>Biotechnology</subject><subject>Charge carriers</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Devices</subject><subject>Diffusion length</subject><subject>Engineering</subject><subject>Fabrication</subject><subject>Glass substrates</subject><subject>Heterojunctions</subject><subject>Materials Science</subject><subject>Nanocrystals</subject><subject>Nanotechnology</subject><subject>Perovskites</subject><subject>Photovoltaic cells</subject><subject>Preserving</subject><subject>Quantum dots</subject><subject>Research Article</subject><subject>Solar cells</subject><subject>Temperature effects</subject><issn>1998-0124</issn><issn>1998-0000</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kdFqHCEUhiU0kHTbB8idkJvcTKquOk7uQmiyhUB7kVyLdY-7bmZ1cpwJ9Bny0nWyDZRCBc8R_f4fDz8hZ5xdcsbaL4UL0cqG8brVUjbmiJzyrjMNq-vD-5kLeUI-lrJjTAsuzSl5XcXNthkAQ8a9Sx7o0LvkkG5hBMy7Kfkx5kQrkV_KUxyBltzXdw99X67oD4QC-BLThva5Fr91uAHqHWIEpOsYwlRmgx7SZtwW6tKaxlS9g_PR9bRexwSA1eETOQ6uL_D5T1-Qx9uvDzer5v773beb6_vGK6XGhkutW_4zvBUjmVZKd4FJMAIYcC6FN1qLZfBOrzumvZbKBAGmYmC0Xy7IxcF3wPw8QRntPpZ5HpcgT8VyrbhkgrWqouf_oLs8Yaq_q9SyNR3val8QfqA85lIQgh0w7h3-spzZOR57iMfWeOwcjzVVIw6aMsyzA_7l_F_Rb_cvlJI</recordid><startdate>20141201</startdate><enddate>20141201</enddate><creator>Bai, Sai</creator><creator>Wu, Zhongwei</creator><creator>Wu, Xiaojing</creator><creator>Jin, Yizheng</creator><creator>Zhao, Ni</creator><creator>Chen, Zhihui</creator><creator>Mei, Qingqing</creator><creator>Wang, Xin</creator><creator>Ye, Zhizhen</creator><creator>Song, Tao</creator><creator>Liu, Ruiyuan</creator><creator>Lee, Shuit-tong</creator><creator>Sun, Baoquan</creator><general>Tsinghua University Press</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>7X7</scope><scope>7XB</scope><scope>8AO</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>FR3</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>H8G</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>K9.</scope><scope>KB.</scope><scope>L7M</scope><scope>LK8</scope><scope>M0S</scope><scope>M7P</scope><scope>P64</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>7SP</scope></search><sort><creationdate>20141201</creationdate><title>High-performance planar heterojunction perovskite solar cells: Preserving long charge carrier diffusion lengths and interfacial engineering</title><author>Bai, Sai ; Wu, Zhongwei ; Wu, Xiaojing ; Jin, Yizheng ; Zhao, Ni ; Chen, Zhihui ; Mei, Qingqing ; Wang, Xin ; Ye, Zhizhen ; Song, Tao ; Liu, Ruiyuan ; Lee, Shuit-tong ; Sun, Baoquan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c555t-146671bf671bf84065569f04e82e0e1142c86623fca6d906c6458f2e8569e86c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Annealing</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Biomedicine</topic><topic>Biotechnology</topic><topic>Charge carriers</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Devices</topic><topic>Diffusion length</topic><topic>Engineering</topic><topic>Fabrication</topic><topic>Glass substrates</topic><topic>Heterojunctions</topic><topic>Materials Science</topic><topic>Nanocrystals</topic><topic>Nanotechnology</topic><topic>Perovskites</topic><topic>Photovoltaic cells</topic><topic>Preserving</topic><topic>Quantum dots</topic><topic>Research Article</topic><topic>Solar cells</topic><topic>Temperature effects</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bai, Sai</creatorcontrib><creatorcontrib>Wu, Zhongwei</creatorcontrib><creatorcontrib>Wu, Xiaojing</creatorcontrib><creatorcontrib>Jin, Yizheng</creatorcontrib><creatorcontrib>Zhao, Ni</creatorcontrib><creatorcontrib>Chen, Zhihui</creatorcontrib><creatorcontrib>Mei, Qingqing</creatorcontrib><creatorcontrib>Wang, Xin</creatorcontrib><creatorcontrib>Ye, Zhizhen</creatorcontrib><creatorcontrib>Song, Tao</creatorcontrib><creatorcontrib>Liu, Ruiyuan</creatorcontrib><creatorcontrib>Lee, Shuit-tong</creatorcontrib><creatorcontrib>Sun, 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Collection</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Materials Science Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>ProQuest Biological Science Collection</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Biological Science Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Electronics & Communications Abstracts</collection><jtitle>Nano research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bai, Sai</au><au>Wu, Zhongwei</au><au>Wu, Xiaojing</au><au>Jin, Yizheng</au><au>Zhao, Ni</au><au>Chen, Zhihui</au><au>Mei, Qingqing</au><au>Wang, Xin</au><au>Ye, Zhizhen</au><au>Song, Tao</au><au>Liu, Ruiyuan</au><au>Lee, Shuit-tong</au><au>Sun, Baoquan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High-performance planar heterojunction perovskite solar cells: Preserving long charge carrier diffusion lengths and interfacial engineering</atitle><jtitle>Nano research</jtitle><stitle>Nano Res</stitle><date>2014-12-01</date><risdate>2014</risdate><volume>7</volume><issue>12</issue><spage>1749</spage><epage>1758</epage><pages>1749-1758</pages><issn>1998-0124</issn><eissn>1998-0000</eissn><abstract>We demonstrate that charge carrier diffusion lengths of two classes of perovskites, CH
3
NH
3
PbI
3−
x
Cl
x
and CH
3
NH
3
PbI
3
, are both highly sensitive to film processing conditions and optimal processing procedures are critical to preserving the long carrier diffusion lengths of the perovskite films. This understanding, together with the improved cathode interface using bilayer-structured electron transporting interlayers of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM)/ZnO, leads to the successful fabrication of highly efficient, stable and reproducible planar heterojunction CH
3
NH
3
PbI
3−
x
Cl
x
solar cells with impressive power-conversion efficiencies (PCEs) up to 15.9%. A 1-square-centimeter device yielding a PCE of 12.3% has been realized, demonstrating that this simple planar structure is promising for large-area devices.</abstract><cop>Heidelberg</cop><pub>Tsinghua University Press</pub><doi>10.1007/s12274-014-0534-8</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1998-0124 |
| ispartof | Nano research, 2014-12, Vol.7 (12), p.1749-1758 |
| issn | 1998-0124 1998-0000 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1651402075 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Annealing Atomic/Molecular Structure and Spectra Biomedicine Biotechnology Charge carriers Chemistry and Materials Science Condensed Matter Physics Devices Diffusion length Engineering Fabrication Glass substrates Heterojunctions Materials Science Nanocrystals Nanotechnology Perovskites Photovoltaic cells Preserving Quantum dots Research Article Solar cells Temperature effects |
| title | High-performance planar heterojunction perovskite solar cells: Preserving long charge carrier diffusion lengths and interfacial engineering |
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