Growth and characterization of L-prolinium phosphite
•New L-prolinium phosphite crystal was grown.•Crystal structure was determined.•The crystal is characterized by vibrational spectral, thermal, NLO properties. Single crystal of L-prolinium phosphite was grown by evaporation method from aqueous solution. It crystallizes in the orthorhombic system (sp...
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| Veröffentlicht in: | Journal of molecular structure 2015-01, Vol.1079, p.460-464 |
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| container_title | Journal of molecular structure |
| container_volume | 1079 |
| creator | Fleck, M. Ghazaryan, V.V. Petrosyan, A.M. |
| description | •New L-prolinium phosphite crystal was grown.•Crystal structure was determined.•The crystal is characterized by vibrational spectral, thermal, NLO properties.
Single crystal of L-prolinium phosphite was grown by evaporation method from aqueous solution. It crystallizes in the orthorhombic system (space group P212121, Z=4). The asymmetric unit contains one L-prolinium cation and one phosphite (HPO2(OH))− anion. The phosphite anions form a chain by hydrogen bond OH…O with O…O distance 2.5601(15)Å parallel [010]. The L-prolinium cations bridge two chains of anions by OH…O and NH…O hydrogen bonds with O…O and N…O distances 2.505(2)Å and 2.718(2)Å respectively. The infrared and Raman spectra are registered and discussed. Thermal behavior was studied. Phase-matched SHG was observed. |
| doi_str_mv | 10.1016/j.molstruc.2014.09.051 |
| format | Article |
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Single crystal of L-prolinium phosphite was grown by evaporation method from aqueous solution. It crystallizes in the orthorhombic system (space group P212121, Z=4). The asymmetric unit contains one L-prolinium cation and one phosphite (HPO2(OH))− anion. The phosphite anions form a chain by hydrogen bond OH…O with O…O distance 2.5601(15)Å parallel [010]. The L-prolinium cations bridge two chains of anions by OH…O and NH…O hydrogen bonds with O…O and N…O distances 2.505(2)Å and 2.718(2)Å respectively. The infrared and Raman spectra are registered and discussed. Thermal behavior was studied. Phase-matched SHG was observed.</description><identifier>ISSN: 0022-2860</identifier><identifier>EISSN: 1872-8014</identifier><identifier>DOI: 10.1016/j.molstruc.2014.09.051</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Anions ; Asymmetry ; Cations ; Chains ; Crystal structure ; Evaporation ; Growth from solution ; Hydrogen bonds ; Infrared ; Inorganic salts ; L-prolinium phosphite ; NLO crystals ; Vibrational spectra</subject><ispartof>Journal of molecular structure, 2015-01, Vol.1079, p.460-464</ispartof><rights>2014 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c345t-3b9b00b9acce3b787149bfe20bbc5d04aeb2120d678539d63fff1a391286646b3</citedby><cites>FETCH-LOGICAL-c345t-3b9b00b9acce3b787149bfe20bbc5d04aeb2120d678539d63fff1a391286646b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0022286014009533$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Fleck, M.</creatorcontrib><creatorcontrib>Ghazaryan, V.V.</creatorcontrib><creatorcontrib>Petrosyan, A.M.</creatorcontrib><title>Growth and characterization of L-prolinium phosphite</title><title>Journal of molecular structure</title><description>•New L-prolinium phosphite crystal was grown.•Crystal structure was determined.•The crystal is characterized by vibrational spectral, thermal, NLO properties.
Single crystal of L-prolinium phosphite was grown by evaporation method from aqueous solution. It crystallizes in the orthorhombic system (space group P212121, Z=4). The asymmetric unit contains one L-prolinium cation and one phosphite (HPO2(OH))− anion. The phosphite anions form a chain by hydrogen bond OH…O with O…O distance 2.5601(15)Å parallel [010]. The L-prolinium cations bridge two chains of anions by OH…O and NH…O hydrogen bonds with O…O and N…O distances 2.505(2)Å and 2.718(2)Å respectively. The infrared and Raman spectra are registered and discussed. Thermal behavior was studied. Phase-matched SHG was observed.</description><subject>Anions</subject><subject>Asymmetry</subject><subject>Cations</subject><subject>Chains</subject><subject>Crystal structure</subject><subject>Evaporation</subject><subject>Growth from solution</subject><subject>Hydrogen bonds</subject><subject>Infrared</subject><subject>Inorganic salts</subject><subject>L-prolinium phosphite</subject><subject>NLO crystals</subject><subject>Vibrational spectra</subject><issn>0022-2860</issn><issn>1872-8014</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqFkEFLxDAUhIMouK7-BenRS-tL0qbNTVl0FRa86DkkaUqztE1NUkV_vVlWz54eDDPDvA-hawwFBsxu98XohhD9ogsCuCyAF1DhE7TCTU3yJkmnaAVASE4aBufoIoQ9AOAUXqFy691n7DM5tZnupZc6Gm-_ZbRuylyX7fLZu8FOdhmzuXdh7m00l-isk0MwV793jd4eH143T_nuZfu8ud_lmpZVzKniCkBxqbWhqm5qXHLVGQJK6aqFUhpFMIGW1U1Fecto13VYUo7TTlYyRdfo5tibNrwvJkQx2qDNMMjJuCUIzCpMeV03PFnZ0aq9C8GbTszejtJ_CQzigEnsxR8mccAkgIuEKQXvjkGTHvmwxougrZm0aa03OorW2f8qfgB1-3Sk</recordid><startdate>20150105</startdate><enddate>20150105</enddate><creator>Fleck, M.</creator><creator>Ghazaryan, V.V.</creator><creator>Petrosyan, A.M.</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20150105</creationdate><title>Growth and characterization of L-prolinium phosphite</title><author>Fleck, M. ; Ghazaryan, V.V. ; Petrosyan, A.M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c345t-3b9b00b9acce3b787149bfe20bbc5d04aeb2120d678539d63fff1a391286646b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Anions</topic><topic>Asymmetry</topic><topic>Cations</topic><topic>Chains</topic><topic>Crystal structure</topic><topic>Evaporation</topic><topic>Growth from solution</topic><topic>Hydrogen bonds</topic><topic>Infrared</topic><topic>Inorganic salts</topic><topic>L-prolinium phosphite</topic><topic>NLO crystals</topic><topic>Vibrational spectra</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fleck, M.</creatorcontrib><creatorcontrib>Ghazaryan, V.V.</creatorcontrib><creatorcontrib>Petrosyan, A.M.</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of molecular structure</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fleck, M.</au><au>Ghazaryan, V.V.</au><au>Petrosyan, A.M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Growth and characterization of L-prolinium phosphite</atitle><jtitle>Journal of molecular structure</jtitle><date>2015-01-05</date><risdate>2015</risdate><volume>1079</volume><spage>460</spage><epage>464</epage><pages>460-464</pages><issn>0022-2860</issn><eissn>1872-8014</eissn><abstract>•New L-prolinium phosphite crystal was grown.•Crystal structure was determined.•The crystal is characterized by vibrational spectral, thermal, NLO properties.
Single crystal of L-prolinium phosphite was grown by evaporation method from aqueous solution. It crystallizes in the orthorhombic system (space group P212121, Z=4). The asymmetric unit contains one L-prolinium cation and one phosphite (HPO2(OH))− anion. The phosphite anions form a chain by hydrogen bond OH…O with O…O distance 2.5601(15)Å parallel [010]. The L-prolinium cations bridge two chains of anions by OH…O and NH…O hydrogen bonds with O…O and N…O distances 2.505(2)Å and 2.718(2)Å respectively. The infrared and Raman spectra are registered and discussed. Thermal behavior was studied. Phase-matched SHG was observed.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.molstruc.2014.09.051</doi><tpages>5</tpages></addata></record> |
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| source | Elsevier ScienceDirect Journals |
| subjects | Anions Asymmetry Cations Chains Crystal structure Evaporation Growth from solution Hydrogen bonds Infrared Inorganic salts L-prolinium phosphite NLO crystals Vibrational spectra |
| title | Growth and characterization of L-prolinium phosphite |
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