Effect of electrode geometry on photovoltaic performance of polymer solar cells

This paper investigates the impact of electrode geometry on the performance of polymer solar cells (PSCs). The negative electrodes with equal area (0.09 cm super(2)) but different shape (round, oval, square and triangular) are evaluated with respect to short-circuit current density, open-circuit vol...

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Veröffentlicht in:Journal of physics. D, Applied physics Applied physics, 2014-10, Vol.47 (43), p.1-6
Hauptverfasser: Li, Meng, Ma, Heng, Liu, Hairui, Wu, Dongge, Niu, Heying, Cai, Wenjun
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container_issue 43
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container_title Journal of physics. D, Applied physics
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creator Li, Meng
Ma, Heng
Liu, Hairui
Wu, Dongge
Niu, Heying
Cai, Wenjun
description This paper investigates the impact of electrode geometry on the performance of polymer solar cells (PSCs). The negative electrodes with equal area (0.09 cm super(2)) but different shape (round, oval, square and triangular) are evaluated with respect to short-circuit current density, open-circuit voltage, fill factor and power conversion efficiency of PSCs. The results show that the device with round electrodes gives the best photovoltaic performance; in contrast, the device with triangular electrodes reveals the worst properties. A maximum of almost a 19% increase in power conversion efficiency with a round electrode is obtained in the devices compared with that of the triangular electrode. To conclude, the electrode boundary curvature has a significant impact on the performance of PSCs. The larger curvature, i.e. sharper electrodes edges, perhaps has a negative effect on exciton separation and carrier transport in photoelectric conversion processes.
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source IOP Publishing Journals; Institute of Physics (IOP) Journals - HEAL-Link
subjects Boundaries
Curvature
Devices
Electrodes
Energy conversion efficiency
Mathematical analysis
Photovoltaic cells
Solar cells
title Effect of electrode geometry on photovoltaic performance of polymer solar cells
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