Thermal analysis of magnesium reactions with nitrogen/oxygen gas mixtures

•Total oxidation and nitridation heat decreases linearly from 79% to 95% N2 in O2/N2 mixture.•Preference of oxidation was weakened by nitridation in higher N2/O2 ratio mixture than air.•Two growth stages of coating layer are identified in entire Mg oxidation/nitridation process.•Activation energy ca...

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Veröffentlicht in:	Journal of hazardous materials 2013-09, Vol.260, p.707-714
Hauptverfasser:	Chunmiao, Yuan, Lifu, Yu, Chang, Li, Gang, Li, Shengjun, Zhong
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation energy Air Applied sciences Atmosphere Calorimetry, Differential Scanning Chemical engineering Coating Diffusion Exact sciences and technology Gases - chemistry Hazardous materials Hazardous Substances - chemistry Hot Temperature Kinetics Magnesium Magnesium - chemistry Magnesium powder Mathematical analysis Nitridation Nitrogen - chemistry Oxidation Oxygen - chemistry Particle Size Pollution Powders Protective Reactors Temperature Thermal analysis Thermogravimetric analysis Thermogravimetry Time Factors
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