Epoxidized linolenic acid salts as multifunctional additives for the thermal stability of plasticized PVC
ABSTRACT Calcium and zinc salts of epoxidized linolenic acid were synthesized and used as multifunctional additives, to minimize or prevent the reaction of epoxidized soybean oil (ESO) with liberated hydrochloric acid (HCl) during the thermal degradation of poly(vinyl chloride) (PVC) in particular....
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| Veröffentlicht in: | Journal of applied polymer science 2015-04, Vol.132 (13), p.np-n/a |
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| container_title | Journal of applied polymer science |
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| creator | Mohammed, Fiaz S. Conley, Mark Saunders, Steven R. Switzer, Jackson Jha, Rani Cogen, Jeffrey M. Chaudhary, Bharat I. Pollet, Pamela Eckert, Charles A. Liotta, Charles L. |
| description | ABSTRACT
Calcium and zinc salts of epoxidized linolenic acid were synthesized and used as multifunctional additives, to minimize or prevent the reaction of epoxidized soybean oil (ESO) with liberated hydrochloric acid (HCl) during the thermal degradation of poly(vinyl chloride) (PVC) in particular. These metal epoxy salts were incorporated as thermal stabilizers for both diisodecyl phthalate and ESO–plasticized PVC blends that underwent thermal degradation studies at 170°C. The overall performance of these metal epoxy salts was examined by thermal gravimetric analysis and visual color retention of the PVC blends. The weight loss profiles of the metal salt stabilized PVC were comparable to those of blends containing metal stearates. There were, however, vast improvements in color retention of the plasticized PVC using these novel additives. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41736. |
| doi_str_mv | 10.1002/app.41736 |
| format | Article |
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Calcium and zinc salts of epoxidized linolenic acid were synthesized and used as multifunctional additives, to minimize or prevent the reaction of epoxidized soybean oil (ESO) with liberated hydrochloric acid (HCl) during the thermal degradation of poly(vinyl chloride) (PVC) in particular. These metal epoxy salts were incorporated as thermal stabilizers for both diisodecyl phthalate and ESO–plasticized PVC blends that underwent thermal degradation studies at 170°C. The overall performance of these metal epoxy salts was examined by thermal gravimetric analysis and visual color retention of the PVC blends. The weight loss profiles of the metal salt stabilized PVC were comparable to those of blends containing metal stearates. There were, however, vast improvements in color retention of the plasticized PVC using these novel additives. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41736.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.41736</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Blackwell Publishing Ltd</publisher><subject>Additives ; Blends ; Chlorides ; Color ; degradation ; Linolenic acid ; Materials science ; plasticizer ; poly(vinyl) chloride ; Polymer blends ; Polymers ; Polyvinyl chlorides ; Thermal degradation ; thermal properties</subject><ispartof>Journal of applied polymer science, 2015-04, Vol.132 (13), p.np-n/a</ispartof><rights>2014 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4736-295734512dc04636ed4928dbb3c8cd796dac383b6221ce928bae6fd1bb80f72c3</citedby><cites>FETCH-LOGICAL-c4736-295734512dc04636ed4928dbb3c8cd796dac383b6221ce928bae6fd1bb80f72c3</cites><orcidid>0000-0002-3961-3360</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.41736$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.41736$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Mohammed, Fiaz S.</creatorcontrib><creatorcontrib>Conley, Mark</creatorcontrib><creatorcontrib>Saunders, Steven R.</creatorcontrib><creatorcontrib>Switzer, Jackson</creatorcontrib><creatorcontrib>Jha, Rani</creatorcontrib><creatorcontrib>Cogen, Jeffrey M.</creatorcontrib><creatorcontrib>Chaudhary, Bharat I.</creatorcontrib><creatorcontrib>Pollet, Pamela</creatorcontrib><creatorcontrib>Eckert, Charles A.</creatorcontrib><creatorcontrib>Liotta, Charles L.</creatorcontrib><title>Epoxidized linolenic acid salts as multifunctional additives for the thermal stability of plasticized PVC</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>ABSTRACT
Calcium and zinc salts of epoxidized linolenic acid were synthesized and used as multifunctional additives, to minimize or prevent the reaction of epoxidized soybean oil (ESO) with liberated hydrochloric acid (HCl) during the thermal degradation of poly(vinyl chloride) (PVC) in particular. These metal epoxy salts were incorporated as thermal stabilizers for both diisodecyl phthalate and ESO–plasticized PVC blends that underwent thermal degradation studies at 170°C. The overall performance of these metal epoxy salts was examined by thermal gravimetric analysis and visual color retention of the PVC blends. The weight loss profiles of the metal salt stabilized PVC were comparable to those of blends containing metal stearates. There were, however, vast improvements in color retention of the plasticized PVC using these novel additives. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41736.</description><subject>Additives</subject><subject>Blends</subject><subject>Chlorides</subject><subject>Color</subject><subject>degradation</subject><subject>Linolenic acid</subject><subject>Materials science</subject><subject>plasticizer</subject><subject>poly(vinyl) chloride</subject><subject>Polymer blends</subject><subject>Polymers</subject><subject>Polyvinyl chlorides</subject><subject>Thermal degradation</subject><subject>thermal properties</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp1kE9PFTEUxRujiU9g4TdowkYXA_03bWeJL4AkgG8B6q7ptJ1Q7JuObQd5fnr6eOLCxMXNXZzfObn3APAeoyOMEDnW03TEsKD8FVhg1ImGcSJfg0XVcCO7rn0L3uV8jxDGLeIL4E-n-Oit_-0sDH6MwY3eQG28hVmHkqHOcD2H4od5NMXHUQeorfXFP7gMh5hguXPbSeuq5KJ7H3zZwDjAKehcvHmOXn1d7oM3gw7ZHfzZe-D27PRm-bm5_HJ-sTy5bAyrZzekawVlLSbWIMYpd5Z1RNq-p0YaKzputaGS9pwQbFyVeu34YHHfSzQIYuge-LDLnVL8Obtc1Npn40LQo4tzVpi3mEoipajo4T_ofZxTfXFLMYIRIwhV6uOOMinmnNygpuTXOm0URmpbuqqlq-fSK3u8Y3_54Db_B9XJavXiaHYOn4t7_OvQ6YfigopWfbs-V6z7fiXEpzN1Q58AuHmTHA</recordid><startdate>20150405</startdate><enddate>20150405</enddate><creator>Mohammed, Fiaz S.</creator><creator>Conley, Mark</creator><creator>Saunders, Steven R.</creator><creator>Switzer, Jackson</creator><creator>Jha, Rani</creator><creator>Cogen, Jeffrey M.</creator><creator>Chaudhary, Bharat I.</creator><creator>Pollet, Pamela</creator><creator>Eckert, Charles A.</creator><creator>Liotta, Charles L.</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-3961-3360</orcidid></search><sort><creationdate>20150405</creationdate><title>Epoxidized linolenic acid salts as multifunctional additives for the thermal stability of plasticized PVC</title><author>Mohammed, Fiaz S. ; Conley, Mark ; Saunders, Steven R. ; Switzer, Jackson ; Jha, Rani ; Cogen, Jeffrey M. ; Chaudhary, Bharat I. ; Pollet, Pamela ; Eckert, Charles A. ; Liotta, Charles L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4736-295734512dc04636ed4928dbb3c8cd796dac383b6221ce928bae6fd1bb80f72c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Additives</topic><topic>Blends</topic><topic>Chlorides</topic><topic>Color</topic><topic>degradation</topic><topic>Linolenic acid</topic><topic>Materials science</topic><topic>plasticizer</topic><topic>poly(vinyl) chloride</topic><topic>Polymer blends</topic><topic>Polymers</topic><topic>Polyvinyl chlorides</topic><topic>Thermal degradation</topic><topic>thermal properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mohammed, Fiaz S.</creatorcontrib><creatorcontrib>Conley, Mark</creatorcontrib><creatorcontrib>Saunders, Steven R.</creatorcontrib><creatorcontrib>Switzer, Jackson</creatorcontrib><creatorcontrib>Jha, Rani</creatorcontrib><creatorcontrib>Cogen, Jeffrey M.</creatorcontrib><creatorcontrib>Chaudhary, Bharat I.</creatorcontrib><creatorcontrib>Pollet, Pamela</creatorcontrib><creatorcontrib>Eckert, Charles A.</creatorcontrib><creatorcontrib>Liotta, Charles L.</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mohammed, Fiaz S.</au><au>Conley, Mark</au><au>Saunders, Steven R.</au><au>Switzer, Jackson</au><au>Jha, Rani</au><au>Cogen, Jeffrey M.</au><au>Chaudhary, Bharat I.</au><au>Pollet, Pamela</au><au>Eckert, Charles A.</au><au>Liotta, Charles L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Epoxidized linolenic acid salts as multifunctional additives for the thermal stability of plasticized PVC</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2015-04-05</date><risdate>2015</risdate><volume>132</volume><issue>13</issue><spage>np</spage><epage>n/a</epage><pages>np-n/a</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>ABSTRACT
Calcium and zinc salts of epoxidized linolenic acid were synthesized and used as multifunctional additives, to minimize or prevent the reaction of epoxidized soybean oil (ESO) with liberated hydrochloric acid (HCl) during the thermal degradation of poly(vinyl chloride) (PVC) in particular. These metal epoxy salts were incorporated as thermal stabilizers for both diisodecyl phthalate and ESO–plasticized PVC blends that underwent thermal degradation studies at 170°C. The overall performance of these metal epoxy salts was examined by thermal gravimetric analysis and visual color retention of the PVC blends. The weight loss profiles of the metal salt stabilized PVC were comparable to those of blends containing metal stearates. There were, however, vast improvements in color retention of the plasticized PVC using these novel additives. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41736.</abstract><cop>Hoboken</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/app.41736</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-3961-3360</orcidid><oa>free_for_read</oa></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Additives Blends Chlorides Color degradation Linolenic acid Materials science plasticizer poly(vinyl) chloride Polymer blends Polymers Polyvinyl chlorides Thermal degradation thermal properties |
| title | Epoxidized linolenic acid salts as multifunctional additives for the thermal stability of plasticized PVC |
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