Greener synthesis and optimization of highly photoluminescence Mn super(2+)-doped ZnS quantum dots

In this study, ZnS quantum dots (QDs) and strong yellow light-emitting Mn super(2+)-doped ZnS QDs are synthesized using 3-mercaptopropionic acid (MPA) as a stabilizer by a promising preparation method in an aqueous solution. Further, the photoluminescence (PL) properties of the ZnS QDs under differe...

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Veröffentlicht in:Journal of luminescence 2015-02, Vol.158, p.176-180
Hauptverfasser: Zhou, Chunyan, Song, Jiahui, Zhou, Liya, Zhong, Liping, Liu, Jiaxian, Qi, Yaya
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container_title Journal of luminescence
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creator Zhou, Chunyan
Song, Jiahui
Zhou, Liya
Zhong, Liping
Liu, Jiaxian
Qi, Yaya
description In this study, ZnS quantum dots (QDs) and strong yellow light-emitting Mn super(2+)-doped ZnS QDs are synthesized using 3-mercaptopropionic acid (MPA) as a stabilizer by a promising preparation method in an aqueous solution. Further, the photoluminescence (PL) properties of the ZnS QDs under different conditions are thoroughly investigated. Under optimized experimental conditions, the structure of the obtained ZnS:Mn super(2+) nanocrystals is consistent with that of the cubic zinc blende crystal, with a nearly spherical shape of approximately 5 nm average diameter. The emission peak varies from 450 nm to 575 nm with Mn super(2+) doping, which suggests effective energy transfer from the host ZnS QDs to the dopant Mn super(2+) ions. The results indicate that ZnS:Mn super(2+) QDs can potentially be used in light-emitting diodes (LEDs).
doi_str_mv 10.1016/j.jlumin.2014.09.053
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subjects Crystal structure
Energy transfer
Luminescence
Optimization
Photoluminescence
Quantum dots
Zinc
Zinc sulfides
title Greener synthesis and optimization of highly photoluminescence Mn super(2+)-doped ZnS quantum dots
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