Polarization and mass transfer during the electrolysis of molten salts with liquid metallic electrodes
Calculations are used to show that the fraction of the overvoltage of the stage of discharge-ionization can be significant in the total overvoltage during the polarization of liquid metallic electrodes in molten chlorides depleted of electrochemically active particles (depending on the type of the d...
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| Veröffentlicht in: | Russian metallurgy Metally 2014-08, Vol.2014 (8), p.599-605 |
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| container_title | Russian metallurgy Metally |
| container_volume | 2014 |
| creator | Mikhalev, Yu. G. |
| description | Calculations are used to show that the fraction of the overvoltage of the stage of discharge-ionization can be significant in the total overvoltage during the polarization of liquid metallic electrodes in molten chlorides depleted of electrochemically active particles (depending on the type of the dissipative structures that appear near the electrode/electrolyte interface). This finding is taken into account to obtain criterion equations to describe the mass-transfer rate as a function of the physicochemical properties of the electrolyte and the metal electrode. |
| doi_str_mv | 10.1134/S0036029514080072 |
| format | Article |
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| ispartof | Russian metallurgy Metally, 2014-08, Vol.2014 (8), p.599-605 |
| issn | 0036-0295 1555-6255 1531-8648 |
| language | eng |
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| source | SpringerLink Journals |
| subjects | Chemistry and Materials Science Electrodes Electrolytes Fused salts Liquids Mass transfer Materials Science Mathematical analysis Metallic Materials Overvoltage Polarization |
| title | Polarization and mass transfer during the electrolysis of molten salts with liquid metallic electrodes |
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