HRGC-ECD and HRGC-ECNI-SIM-HRMS quantification of toxaphene residues by six environmentally relevant chlorobornanes as standard
The HRGC determination of toxaphene residues in environmental samples is often difficult because of different degradation rates and accumulation behavior of individual toxaphene components. Therefore, isolated environmentally relevant chlorinated bornanes are used as standards. During the last years...
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Veröffentlicht in: | Chemosphere (Oxford) 1998-08, Vol.37 (3), p.549-558 |
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creator | Kimmel, Lenka Angerhöfer, Daniela Gill, Udai Coelhan, Mehmet Parlar, Harun |
description | The HRGC determination of toxaphene residues in environmental samples is often difficult because of different degradation rates and accumulation behavior of individual toxaphene components. Therefore, isolated environmentally relevant chlorinated bornanes are used as standards. During the last years, single components as well as different combinations of them have been tested for their suitability for HRGC-HRMS-ECNI quantification. In this study, Parlar #26, Parlar #40, Parlar #41, Parlar #44, Parlar #50, and Parlar #62 have been used. The results show the sum of these six components to be at least 80–85% of toxaphene in fish oils. |
doi_str_mv | 10.1016/S0045-6535(98)00070-8 |
format | Article |
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subjects | Agnatha. Pisces Analysis methods Analytical chemistry Animal, plant and microbial ecology Applied ecology Applied sciences Biological and medical sciences Chemistry Chromatographic methods and physical methods associated with chromatography Ecotoxicology, biological effects of pollution Effects of pollution and side effects of pesticides on vertebrates Exact sciences and technology Fundamental and applied biological sciences. Psychology Gas chromatographic methods Natural water pollution Pollution Water treatment and pollution |
title | HRGC-ECD and HRGC-ECNI-SIM-HRMS quantification of toxaphene residues by six environmentally relevant chlorobornanes as standard |
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