Physicochemical properties of selected monoterpenes

Monoterpenes have physical and chemical properties that may make them attractive alternatives to chlorofluorocarbons in many industrial applications. More widespread use of these chemicals will inevitably increase the likelihood of their discharge into the environment. Several physicochemical proper...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Environment international 1998-04, Vol.24 (3), p.353-358
Hauptverfasser: Li, J., Perdue, E.M., Pavlostathis, S.G., Araujo, R.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 358
container_issue 3
container_start_page 353
container_title Environment international
container_volume 24
creator Li, J.
Perdue, E.M.
Pavlostathis, S.G.
Araujo, R.
description Monoterpenes have physical and chemical properties that may make them attractive alternatives to chlorofluorocarbons in many industrial applications. More widespread use of these chemicals will inevitably increase the likelihood of their discharge into the environment. Several physicochemical properties of these compounds are needed to predict their most likely fate in the environment. This paper reports the aqueous solubilities, vapor pressures, and octanol-water partition coefficients of eight monoterpenes (α-pinene, limonene, γ-terpinene, terpinolene, arbanol, α-terpineol, linalool, and plinol). The aqueous solubilities and vapor pressures were measured at two temperatures, and the octanol-water partition coefficients were measured at one temperature. Well-established empirical correlations between these parameters for other organic compounds were used to evaluate the internal consistency of results obtained in this study. In addition, the predictions of two models were compared with the observed results.
doi_str_mv 10.1016/S0160-4120(98)00013-0
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_16465233</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0160412098000130</els_id><sourcerecordid>16465233</sourcerecordid><originalsourceid>FETCH-LOGICAL-c367t-2c151c18bd5c1109e30c8485c60bbf74b1130d8809d4d14248583db640b67c143</originalsourceid><addsrcrecordid>eNqFkE9LxDAQxYMouK5-BKEHET1UZ5o2TU8ii_9gQUE9hzadspG2qUlX2G9v6i579TJz-b158x5j5wg3CChu38OAOMUErgp5DQDIYzhgM5Q5j0WewSGb7ZFjduL9V4CSVGYzxt9WG2-01SvqjC7baHB2IDca8pFtIk8t6ZHqqLO9HckN1JM_ZUdN2Xo62-05-3x8-Fg8x8vXp5fF_TLWXORjnGjMUKOs6kwjQkEctAymWkBVNXlaIXKopYSiTmtMp38kryuRQiVyjSmfs8vt3fDT95r8qDrjNbVt2ZNde4UiFVnCeQCzLaid9d5RowZnutJtFIKaKlJ_Fakpvyqk-qtIQdBd7AxKH7I3ruy18XtxkiDk2XT-botRCPtjyCmvDfWaauNCO6q25h-jX5ANeQM</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>16465233</pqid></control><display><type>article</type><title>Physicochemical properties of selected monoterpenes</title><source>Elsevier ScienceDirect Journals Complete - AutoHoldings</source><creator>Li, J. ; Perdue, E.M. ; Pavlostathis, S.G. ; Araujo, R.</creator><creatorcontrib>Li, J. ; Perdue, E.M. ; Pavlostathis, S.G. ; Araujo, R.</creatorcontrib><description>Monoterpenes have physical and chemical properties that may make them attractive alternatives to chlorofluorocarbons in many industrial applications. More widespread use of these chemicals will inevitably increase the likelihood of their discharge into the environment. Several physicochemical properties of these compounds are needed to predict their most likely fate in the environment. This paper reports the aqueous solubilities, vapor pressures, and octanol-water partition coefficients of eight monoterpenes (α-pinene, limonene, γ-terpinene, terpinolene, arbanol, α-terpineol, linalool, and plinol). The aqueous solubilities and vapor pressures were measured at two temperatures, and the octanol-water partition coefficients were measured at one temperature. Well-established empirical correlations between these parameters for other organic compounds were used to evaluate the internal consistency of results obtained in this study. In addition, the predictions of two models were compared with the observed results.</description><identifier>ISSN: 0160-4120</identifier><identifier>EISSN: 1873-6750</identifier><identifier>DOI: 10.1016/S0160-4120(98)00013-0</identifier><identifier>CODEN: ENVIDV</identifier><language>eng</language><publisher>Amsterdam: Elsevier Ltd</publisher><subject>Applied sciences ; Chemical thermodynamics ; Chemistry ; Elements, mineral and organic compounds ; Exact sciences and technology ; General and physical chemistry ; Global environmental pollution ; Pollution ; Thermodynamic properties</subject><ispartof>Environment international, 1998-04, Vol.24 (3), p.353-358</ispartof><rights>1998</rights><rights>1998 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c367t-2c151c18bd5c1109e30c8485c60bbf74b1130d8809d4d14248583db640b67c143</citedby><cites>FETCH-LOGICAL-c367t-2c151c18bd5c1109e30c8485c60bbf74b1130d8809d4d14248583db640b67c143</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0160-4120(98)00013-0$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,778,782,3539,27911,27912,45982</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=2210753$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, J.</creatorcontrib><creatorcontrib>Perdue, E.M.</creatorcontrib><creatorcontrib>Pavlostathis, S.G.</creatorcontrib><creatorcontrib>Araujo, R.</creatorcontrib><title>Physicochemical properties of selected monoterpenes</title><title>Environment international</title><description>Monoterpenes have physical and chemical properties that may make them attractive alternatives to chlorofluorocarbons in many industrial applications. More widespread use of these chemicals will inevitably increase the likelihood of their discharge into the environment. Several physicochemical properties of these compounds are needed to predict their most likely fate in the environment. This paper reports the aqueous solubilities, vapor pressures, and octanol-water partition coefficients of eight monoterpenes (α-pinene, limonene, γ-terpinene, terpinolene, arbanol, α-terpineol, linalool, and plinol). The aqueous solubilities and vapor pressures were measured at two temperatures, and the octanol-water partition coefficients were measured at one temperature. Well-established empirical correlations between these parameters for other organic compounds were used to evaluate the internal consistency of results obtained in this study. In addition, the predictions of two models were compared with the observed results.</description><subject>Applied sciences</subject><subject>Chemical thermodynamics</subject><subject>Chemistry</subject><subject>Elements, mineral and organic compounds</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Global environmental pollution</subject><subject>Pollution</subject><subject>Thermodynamic properties</subject><issn>0160-4120</issn><issn>1873-6750</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNqFkE9LxDAQxYMouK5-BKEHET1UZ5o2TU8ii_9gQUE9hzadspG2qUlX2G9v6i579TJz-b158x5j5wg3CChu38OAOMUErgp5DQDIYzhgM5Q5j0WewSGb7ZFjduL9V4CSVGYzxt9WG2-01SvqjC7baHB2IDca8pFtIk8t6ZHqqLO9HckN1JM_ZUdN2Xo62-05-3x8-Fg8x8vXp5fF_TLWXORjnGjMUKOs6kwjQkEctAymWkBVNXlaIXKopYSiTmtMp38kryuRQiVyjSmfs8vt3fDT95r8qDrjNbVt2ZNde4UiFVnCeQCzLaid9d5RowZnutJtFIKaKlJ_Fakpvyqk-qtIQdBd7AxKH7I3ruy18XtxkiDk2XT-botRCPtjyCmvDfWaauNCO6q25h-jX5ANeQM</recordid><startdate>19980401</startdate><enddate>19980401</enddate><creator>Li, J.</creator><creator>Perdue, E.M.</creator><creator>Pavlostathis, S.G.</creator><creator>Araujo, R.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TV</scope><scope>C1K</scope></search><sort><creationdate>19980401</creationdate><title>Physicochemical properties of selected monoterpenes</title><author>Li, J. ; Perdue, E.M. ; Pavlostathis, S.G. ; Araujo, R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-2c151c18bd5c1109e30c8485c60bbf74b1130d8809d4d14248583db640b67c143</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Applied sciences</topic><topic>Chemical thermodynamics</topic><topic>Chemistry</topic><topic>Elements, mineral and organic compounds</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Global environmental pollution</topic><topic>Pollution</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, J.</creatorcontrib><creatorcontrib>Perdue, E.M.</creatorcontrib><creatorcontrib>Pavlostathis, S.G.</creatorcontrib><creatorcontrib>Araujo, R.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Pollution Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><jtitle>Environment international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, J.</au><au>Perdue, E.M.</au><au>Pavlostathis, S.G.</au><au>Araujo, R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Physicochemical properties of selected monoterpenes</atitle><jtitle>Environment international</jtitle><date>1998-04-01</date><risdate>1998</risdate><volume>24</volume><issue>3</issue><spage>353</spage><epage>358</epage><pages>353-358</pages><issn>0160-4120</issn><eissn>1873-6750</eissn><coden>ENVIDV</coden><abstract>Monoterpenes have physical and chemical properties that may make them attractive alternatives to chlorofluorocarbons in many industrial applications. More widespread use of these chemicals will inevitably increase the likelihood of their discharge into the environment. Several physicochemical properties of these compounds are needed to predict their most likely fate in the environment. This paper reports the aqueous solubilities, vapor pressures, and octanol-water partition coefficients of eight monoterpenes (α-pinene, limonene, γ-terpinene, terpinolene, arbanol, α-terpineol, linalool, and plinol). The aqueous solubilities and vapor pressures were measured at two temperatures, and the octanol-water partition coefficients were measured at one temperature. Well-established empirical correlations between these parameters for other organic compounds were used to evaluate the internal consistency of results obtained in this study. In addition, the predictions of two models were compared with the observed results.</abstract><cop>Amsterdam</cop><pub>Elsevier Ltd</pub><doi>10.1016/S0160-4120(98)00013-0</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0160-4120
ispartof Environment international, 1998-04, Vol.24 (3), p.353-358
issn 0160-4120
1873-6750
language eng
recordid cdi_proquest_miscellaneous_16465233
source Elsevier ScienceDirect Journals Complete - AutoHoldings
subjects Applied sciences
Chemical thermodynamics
Chemistry
Elements, mineral and organic compounds
Exact sciences and technology
General and physical chemistry
Global environmental pollution
Pollution
Thermodynamic properties
title Physicochemical properties of selected monoterpenes
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T03%3A44%3A33IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Physicochemical%20properties%20of%20selected%20monoterpenes&rft.jtitle=Environment%20international&rft.au=Li,%20J.&rft.date=1998-04-01&rft.volume=24&rft.issue=3&rft.spage=353&rft.epage=358&rft.pages=353-358&rft.issn=0160-4120&rft.eissn=1873-6750&rft.coden=ENVIDV&rft_id=info:doi/10.1016/S0160-4120(98)00013-0&rft_dat=%3Cproquest_cross%3E16465233%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=16465233&rft_id=info:pmid/&rft_els_id=S0160412098000130&rfr_iscdi=true